2-[2-(2-Hydroxyethoxy)ethoxy]ethyl 4-formylbenzoate | 164030-73-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[2-(2-Hydroxyethoxy)ethoxy]ethyl 4-formylbenzoate
• 英文别名: 2-[2-(2-hydroxyethoxy)ethoxy]ethyl 4-formylbenzoate
• CAS: 164030-73-3
• 化学式: C₁₄H₁₈O₆
• 分子量: 282.293
• InChiKey: CFHJULWGPHNCRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  82.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-[2-(2-Hydroxyethoxy)ethoxy]ethyl 4-formylbenzoate 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 三氟乙酸 作用下， 以 氘代氯仿 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Dynamic Covalent Diblock Copolymers Prepared from RAFT Generated Aldehyde and Alkoxyamine End-Functionalized Polymers

  摘要：

  Aldehyde- or alkoxyamine-containing trithiocarbonate chain transfer agents were prepared and used to mediate the synthesis of a series of polymers end-functionlized with either aldehyde or alkoxyamines functions, utilizing reversible addition-fragmentation polymerization techniques. Aldehyde end-functionalized polymers were shown to link through reversible oxime bond formation with alkoxyamine end-funtionalized polymers forming diblock copolymers. The dynamic nature of the oxime bond linking these polymer blocks together was demonstrated through a simple exchange reaction with a small molecule alkoxyamine. A diblock copolymer prepared from the self-assembly of an aldehyde end-functionalized polyisoprenc with an alkoxyamine end-functionalized polystyrene was shown to undergo further hierarchical self-assembly into micellar aggregates in DMF. It was shown that the addition of an excess of a small molecule alkoxyamine triggered the disassembly of these micelles.

  DOI：

  10.1021/ma902291a
• 作为产物：
  描述：

  对醛基苯甲酸 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 、 苯 为溶剂， 反应 3.0h， 生成 2-[2-(2-Hydroxyethoxy)ethoxy]ethyl 4-formylbenzoate
  参考文献：
  名称：

  Synthesis and Optical-Limiting Behavior of Hybrid Inorganic-Organic Materials from the Sol-Gel Processing of Organofullerenes

  摘要：

  DOI：

  10.1002/(sici)1521-3765(19990903)5:9<2501::aid-chem2501>3.0.co;2-8

文献信息

• Synthesis of a [60]fullerene derivative covalently linked to a ruthenium(<scp>II</scp>) tris(bipyridine) complex
  作者：Michele Maggini、Anna Donò、Gianfranco Scorrano、Maurizio Prato

  DOI：10.1039/c39950000845

  日期：——

  The synthesis of a [60]fullerene derivative containing the transition metal complex Ru(bpy)32+ is described; its UV–VIS spectrum shows absorptions typical of the two independent chromophores.

  本文介绍了一种含有过渡金属复合物 Ru(bpy)32+ 的 [60] 富勒烯衍生物的合成过程；其紫外-可见光谱显示了两种独立发色团的典型吸收。
• Dynamic Covalent Diblock Copolymers Prepared from RAFT Generated Aldehyde and Alkoxyamine End-Functionalized Polymers
  作者：Alexander W. Jackson、David A. Fulton

  DOI：10.1021/ma902291a

  日期：2010.1.26

  Aldehyde- or alkoxyamine-containing trithiocarbonate chain transfer agents were prepared and used to mediate the synthesis of a series of polymers end-functionlized with either aldehyde or alkoxyamines functions, utilizing reversible addition-fragmentation polymerization techniques. Aldehyde end-functionalized polymers were shown to link through reversible oxime bond formation with alkoxyamine end-funtionalized polymers forming diblock copolymers. The dynamic nature of the oxime bond linking these polymer blocks together was demonstrated through a simple exchange reaction with a small molecule alkoxyamine. A diblock copolymer prepared from the self-assembly of an aldehyde end-functionalized polyisoprenc with an alkoxyamine end-functionalized polystyrene was shown to undergo further hierarchical self-assembly into micellar aggregates in DMF. It was shown that the addition of an excess of a small molecule alkoxyamine triggered the disassembly of these micelles.
• Synthesis and Optical-Limiting Behavior of Hybrid Inorganic-Organic Materials from the Sol-Gel Processing of Organofullerenes
  作者：Michele Maggini、Carla De Faveri、Gianfranco Scorrano、Maurizio Prato、Giovanna Brusatin、Massimo Guglielmi、Moreno Meneghetti、Raffaella Signorini、Renato Bozio

  DOI：10.1002/(sici)1521-3765(19990903)5:9<2501::aid-chem2501>3.0.co;2-8

  日期：1999.9.3