N-allyl(diphenylethyl)phosphinoselenoic amide | 1299597-54-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-allyl(diphenylethyl)phosphinoselenoic amide
• 英文别名: N-[bis(2-phenylethyl)phosphinoselenoyl]prop-2-en-1-amine
• CAS: 1299597-54-8
• 化学式: C₁₉H₂₄NPSe
• 分子量: 376.34
• InChiKey: KRZGQCOFDZZHMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.26
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  bis(2-phenylethyl)phosphine selenide 、 丙烯胺 在 三乙胺 作用下， 以 四氯化碳 为溶剂， 反应 1.0h， 以83%的产率得到N-allyl(diphenylethyl)phosphinoselenoic amide
  参考文献：
  名称：

  A simple one-pot synthesis of phosphinoselenoic amides and diamides from secondary phosphine selenides and amines using Et3N-CCl4

  摘要：

  The multi-component reaction between secondary phosphine selenides and amines (primary, secondary, and primary diamines) proceeds using the Et3N-CCl4 system under mild conditions to give phosphinoselenoic amides or diamides in 81-89% isolated yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.02.095

文献信息

• Cross-coupling between secondary phosphine selenides and primary or secondary amines: halogen-free synthesis of phosphinoselenoic amides
  作者：Nina K. Gusarova、Svetlana I. Verkhoturova、Tatyana I. Kazantseva、Svetlana N. Arbuzova、Alexander I. Albanov、Boris A. Trofimov

  DOI：10.1016/j.mencom.2013.09.004

  日期：2013.9

  Secondary phosphine selenides react with primary or secondary amines at 60-65 degrees C in dioxane to give phosphinoselenoic amides.
• A simple one-pot synthesis of phosphinoselenoic amides and diamides from secondary phosphine selenides and amines using Et3N-CCl4
  作者：Nina K. Gusarova、Pavel A. Volkov、Nina I. Ivanova、Ludmila I. Larina、Boris A. Trofimov

  DOI：10.1016/j.tetlet.2011.02.095

  日期：2011.5

  The multi-component reaction between secondary phosphine selenides and amines (primary, secondary, and primary diamines) proceeds using the Et3N-CCl4 system under mild conditions to give phosphinoselenoic amides or diamides in 81-89% isolated yields. (C) 2011 Elsevier Ltd. All rights reserved.