3,6-diallylbenzene-1,2-diol | 50916-57-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3,6-diallylbenzene-1,2-diol
• 英文别名: 3,6-Diallyl-1,2-dihydroxy-benzol；3,6-Diallyl-brenzkatechin；3,6-diallylcatechol；3,6-diallyl-pyrocatechol；2.3-Dihydroxy-1.4-diallyl-benzol；3,6-Diallyl-brenzcatechin；3,6-Bis(prop-2-enyl)benzene-1,2-diol
• CAS: 50916-57-9
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: GJSXVNALQMJFBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,6-diallylbenzene-1,2-diol 在 palladium on activated charcoal 盐酸 、 氢气 、 sodium sulfate 、 silver(l) oxide 作用下， 生成 3,6-Dipropyl-ortho-chinon
  参考文献：
  名称：

  Mueller,E. et al., Zeitschrift fur Naturforschung. Teil B: Chemie, Biochemie, Biophysik, Biologie, 1963, vol. 18b, p. 1002 - 1009

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二(烯丙氧基)苯 生成 3,6-diallylbenzene-1,2-diol
  参考文献：
  名称：

  Community perceptions of stalking: What are the fundamental concerns?

  摘要：

  DOI：

  10.1080/13218710009524982

文献信息

• Investigating the microwave-accelerated Claisen rearrangement of allyl aryl ethers: Scope of the catalysts, solvents, temperatures, and substrates
  作者：Zi Hui、Songwei Jiang、Xiang Qi、Xiang-Yang Ye、Tian Xie

  DOI：10.1016/j.tetlet.2020.151995

  日期：2020.6

  The microwave-accelerated Claisen rearrangement of allyl aryl ethers was investigated, in order to gain insight into the scope of the catalysts, solvents, temperatures, and substrates. Among the catalysts examined, phosphomolybdic acid (PMA) was found to greatly accelerate the reaction in NMP, at temperatures ranging from 220 to 300 °C. This method was found to be useful for preparing several intermediates

  对微波加速烯丙基芳基醚的克莱森重排进行了研究，以便深入了解催化剂，溶剂，温度和底物的范围。在所考察的催化剂中，发现磷钼酸（PMA）在220至300°C的温度下可大大促进NMP中的反应。发现该方法对于使用贵金属催化剂例如Au（I），Ag（I）和Pt（II）制备先前在文献中报道的几种中间体是有用的。另外，在芳基部分带有溴和硝基的底物需要仔细调整反应条件，以避免复杂的产物分布。
• Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase
  作者：R. E. Palermo、R. Singh、J. K. Bashkin、R. H. Holm

  DOI：10.1021/ja00321a019

  日期：1984.5

  Resolution des structures cristallines des trois complexes (Et 4 N) 4 [Mo 2 Fe 6 S 8 (S-p-C 6 H 4 Cl) 6 (cat) 2 ], (Et 4 N) 3 [MoFe 3 S 4 (SEt) 3 (Cl 4 cat)(CN)] et (Et 4 N) 3 [MoFe 3 S 4 (S-p-C 6 H 4 Cl) 3 (Cl 4 cat)N 3 ]•MeCN. Spectres RMN

  分辨率 des 结构 cristallines des trois complexes (Et 4 N) 4 [Mo 2 Fe 6 S 8 (SpC 6 H 4 Cl) 6 (cat) 2 ], (Et 4 N) 3 [MoFe 3 S 4 (SEt) 3 ( Cl 4 cat)(CN)] et (Et 4 N) 3 [MoFe 3 S 4 (SpC 6 H 4 Cl) 3 (Cl 4 cat)N 3 ]•MeCN。幽灵RMN
• CROSSLINKABLE COPOLYMERS COMPRISING FLUOROVINYLETHER FUNCTIONALIZED AROMATIC MOIETIES
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20140134388A1

  公开（公告）日：2014-05-15

  Disclosed are copolymers comprising a backbone with olefinic unsaturation and fluorovinylether functionalized aromatic repeat units, and methods to make the copolymers. The copolymers are useful for imparting improved soil, water, and oil resistance to materials including fibers, fabrics, carpets, films, plaques, and shaped articles. The copolymers can be crosslinked and used to form shaped articles with the improved properties.

  本发明涉及一种共聚物，其包括具有烯烃不饱和度的主链和含有氟乙烯醚官能化芳香重复单元的共聚物，并且提供了制备该共聚物的方法。该共聚物可用于赋予包括纤维、织物、地毯、薄膜、板材和成型物等材料改善的土壤、水和油抗性。该共聚物可以交联并用于形成具有改善性能的成型物。
• ARTICLES MADE FROM CROSSLINKED COPOLYMERS COMPRISING FLUOROVINYLETHER FUNCTIONALIZED AROMATIC MOIETIES
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20140135456A1

  公开（公告）日：2014-05-15

  Disclosed are articles made from crosslinked copolymers comprising crosslinks between olefinically unsaturated positions in the backbone of one type of repeat unit and a second repeat unit that is a fluorovinylether functionalized aromatic repeat unit. The articles have enhanced surface fluorine that imparts improved soil, water, and oil resistance to the articles.

  本发明涉及由交联共聚物制成的物品，其中在一种重复单元的骨架中的烯丙基未饱和位置与第二种重复单元相交联，第二种重复单元是一种含氟乙烯基醚官能化芳香重复单元。这些物品具有增强的表面氟，使其具有改善的抗污、抗水和抗油性能。
• CROSSLINKED COPOLYMERS COMPRISING FLUOROVINYLETHER FUNCTIONALIZED AROMATIC MOIETIES
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20140134420A1

  公开（公告）日：2014-05-15

  Disclosed are crosslinked copolymers comprising a copolymer with crosslinks between olefinically unsaturated positions in the backbone of one type of repeat unit and a second repeat unit that is a fluorovinylether functionalized aromatic repeat unit. The crosslinked copolymers are useful for imparting improved soil, water, and oil resistance to materials including fibers, fabrics, carpets, films, plaques, and shaped articles.

  本发明涉及交联共聚物，其中包括一种共聚物，其在一种重复单元的主链中的烯基不饱和位置之间具有交联，并且第二个重复单元是一种含氟乙烯基醚官能化芳香重复单元。这些交联共聚物可用于赋予材料如纤维、织物、地毯、薄膜、板材和成形件更好的抗污、抗水和抗油性能。