2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate | 65133-69-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate
• 英文别名: 2-hydroxyethyl[2-(2-hydroxyethoxy)ethyl]terephthalate；2-(2-Hydroxyethoxy)ethyl (2-hydroxyethyl) terephthalate；4-O-[2-(2-hydroxyethoxy)ethyl] 1-O-(2-hydroxyethyl) benzene-1,4-dicarboxylate
• CAS: 65133-69-9
• 化学式: C₁₄H₁₈O₇
• 分子量: 298.293
• InChiKey: AYVLVEOLEKBOTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  双(2-羟基乙基)对苯二甲酸酯 、 二乙二醇 在 zinc diacetate 作用下， 反应 6.0h， 生成 2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate
  参考文献：
  名称：

  METHOD OF MANUFACTURING BHCD AND DERIVATIVES THEREOF

  摘要：

  本公开提供了一种制造双(2-羟乙基)环己烷-1,4-二羧酸酯（BHCD）及其衍生物的方法。该方法包括以下步骤。提供包括双羟乙基对苯二甲酸酯（BHET）的第一反应物。将2-(2-羟乙氧基)乙基-2-羟乙基对苯二甲酸酯（BHEET）添加到包括BHET的第一反应物中，形成第二反应物。对第二反应物进行氢化处理。

  公开号：

  US20170342016A1

文献信息

• POLYETHYLENE TEREPHTHALATE FOR MOLDING AND PROCESS FOR PRODUCING THE SAME
  申请人：Aies Co., Ltd.

  公开号：EP1672000A1

  公开（公告）日：2006-06-21

  There is provided a method for producing a polyethylene terephthalate for molding which has a low content of cyclic trimer. The present invention is a method for producing a polyethylene terephthalate for molding which comprises (1) a condensation step of condensing bis(2-hydroxyethyl)terephthalate having an ion content of 10 ppm or less and an acid value of 30 mgKOH/g or less to produce an oligomer having an average polymerization degree of 4 to 10, (2) a melt-polymerization step of melt-polymerizing the oligomer to produce a prepolymer having an intrinsic viscosity of 0.50 to 0.65, and (3) a solid-state polymerization step of crystallizing pellets of the prepolymer and then solid-state polymerizing the prepolymer at a temperature of 190 to 230°C to produce a polyethylene terephthalate having an intrinsic viscosity of not lower than 0.65; and a polyethylene terephthalate for molding which is obtained by the method and has specific properties.

  本发明提供了一种生产模塑用聚对苯二甲酸乙二醇酯的方法，这种聚对苯二甲酸乙二醇酯的环状三聚体含量较低。 本发明是一种生产模塑用聚对苯二甲酸乙二醇酯的方法，该方法包括：(1) 缩合步骤，缩合离子含量为 10 ppm 或以下、酸值为 30 mgKOH/g 或以下的对苯二甲酸二(2-羟乙基)酯，生成平均聚合度为 4 至 10 的低聚物；(2) 熔融聚合步骤，熔融聚合低聚物，生成本征粘度为 0.50至0.65的预聚物，以及(3)固态聚合步骤，将预聚物结晶成颗粒，然后在190至230℃的温度下固态聚合预聚物，生成固有粘度不低于0.65的聚对苯二甲酸乙二醇酯；以及通过该方法获得的具有特定性能的模塑用聚对苯二甲酸乙二醇酯。
• Method of manufacturing BHCD and derivatives thereof
  申请人：Far Eastern New Century Corporation

  公开号：US10017454B2

  公开（公告）日：2018-07-10

  The present disclosure provides a method of manufacturing bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate (BHCD) and derivatives thereof. The method includes the following steps. A first reactant including bis-hydroxyethyl terephthalate (BHET) is provided. 2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate (BHEET) is added to the first reactant including BHET to form a second reactant. The second reactant is hydrogenated.

  本公开提供了一种制造环己烷-1,4-二甲酸双（2-羟乙基）酯（BHCD）及其衍生物的方法。 该方法包括以下步骤。 提供包括对苯二甲酸二羟乙基酯（BHET）在内的第一反应物。 将 2-(2-羟乙氧基)乙基对苯二甲酸乙酯 (BHEET) 加入到包括 BHET 的第一反应物中，形成第二反应物。 第二种反应物经过氢化处理。
• Process for producing a polyester
  申请人：Far Eastern New Century Corporation

  公开号：US10472464B2

  公开（公告）日：2019-11-12

  A method for producing a polyester includes: a) preparing a first monomer represented by Formula (1) for example—bis(β-hydroxyethyl) terephthalate (BHET); and b) preparing a second monomer represented by Formula (2) represented by Formula (2)—2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate (BHEET). The prepared first and second monomer are then mixed to form a mixture, and then the mixture is subjected to a pre-polymerization reaction at a first temperature not higher than 230° C. to form a prepolymer while a glycol compound represented by Formula (3) wherein R independently represents hydrogen, a C1-C6 linear or branched alkyl group, or phenyl; is continuously removed by distillation. The method also includes subjecting the prepolymer to a polymerization reaction at a second temperature higher than the first temperature to obtain the polyester.

  生产聚酯的方法包括：a) 制备由式（1）代表的第一单体，例如-对苯二甲酸二（β-羟乙基）酯（BHET）；b) 制备由式（2）代表的第二单体，即式（2）-2-（2-羟乙氧基）乙基对苯二甲酸二羟乙基酯（BHEET）。然后将制备的第一单体和第二单体混合形成混合物，然后在不高于 230℃的第一温度下对混合物进行预聚反应以形成预聚物，同时通过蒸馏连续除去由式（3）代表的乙二醇化合物，其中 R 独立地代表氢、C1-C6 直链或支链烷基或苯基。该方法还包括将预聚物在高于第一温度的第二温度下进行聚合反应，以获得聚酯。
• Polyethylene terephthalate for molding and production the same
  申请人：Inada Shuji

  公开号：US20060135739A1

  公开（公告）日：2006-06-22

  There is provided a method for producing a polyethylene terephthalate for molding which has a low content of cyclic trimer. The present invention is a method for producing a polyethylene terephthalate for molding which comprises (1) a condensation step of condensing bis(2-hydroxyethyl)terephthalate having an ion content of 10 ppm or less and an acid value of 30 mgKOH/g or less to produce an oligomer having an average polymerization degree of 4 to 10, (2) a melt-polymerization step of melt-polymerizing the oligomer to produce a prepolymer having an intrinsic viscosity of 0.50 to 0.65, and (3) a solid-state polymerization step of crystallizing pellets of the prepolymer and then solid-state polymerizing the prepolymer at a temperature of 190 to 230° C. to produce a polyethylene terephthalate having an intrinsic viscosity of not lower than 0.65; and a polyethylene terephthalate for molding which is obtained by the method and has specific properties.

  本发明提供了一种生产模塑用聚对苯二甲酸乙二醇酯的方法，这种聚对苯二甲酸乙二醇酯的环状三聚体含量较低。本发明是一种生产模塑用聚对苯二甲酸乙二醇酯的方法，该方法包括：(1) 缩合步骤，缩合离子含量为 10 ppm 或以下、酸值为 30 mgKOH/g 或以下的对苯二甲酸二(2-羟乙基)酯，生成平均聚合度为 4 至 10 的低聚物；(2) 熔融聚合步骤，熔融聚合低聚物，生成本征粘度为 0.50至0.65的预聚物，和(3)固态聚合步骤，将预聚物的颗粒结晶，然后在190至230℃的温度下固态聚合预聚物，生成固有粘度不低于0.65的聚对苯二甲酸乙二醇酯；以及通过该方法获得的具有特定性能的模塑用聚对苯二甲酸乙二醇酯。
• EP1510514
  申请人：——

  公开号：——

  公开（公告）日：——