trans-bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium | 1069063-63-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium
• 英文别名: Benzene-2-ide-1,3-dicarboxylic acid;bromopalladium(1+);triphenylphosphane
• CAS: 1069063-63-3
• 化学式: C₄₄H₃₅BrO₄P₂Pd
• 分子量: 876.031
• InChiKey: VVKNKBHZBNNBSL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  8.62
• 重原子数：
  52
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  DL-2-氨基-3-甲基-1-丁醇 、 trans-bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium 在 草酰氯 、 甲基磺酰氯 、 三乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 以57%的产率得到(2,6-bis[(4S)-4-(1-methylethyl)-2-oxazolinyl]phenyl)chloropalladium
  参考文献：
  名称：

  Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route

  摘要：

  A series of [2,6-bis(2-oxazolinyl)phenyl]palladium (Phebox-Pd) complexes were synthesized via the ligand introduction route. trans-Bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium was prepared by the reaction of 2-bromoisophthalic acid with Pd(PPh3)(4) in 93% yield, and the carboxy groups of the palladium complex were converted into oxazolinyl groups to give the Phebox-Pd complexes in 44-57% yield.

  DOI：

  10.1021/om800666x
• 作为产物：
  描述：

  四(三苯基膦)钯 、 2-溴异酞酸 以 乙酸乙酯 为溶剂， 以93%的产率得到trans-bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium
  参考文献：
  名称：

  Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route

  摘要：

  A series of [2,6-bis(2-oxazolinyl)phenyl]palladium (Phebox-Pd) complexes were synthesized via the ligand introduction route. trans-Bromo(2,6-dicarboxyphenyl)bis(triphenylphosphine)palladium was prepared by the reaction of 2-bromoisophthalic acid with Pd(PPh3)(4) in 93% yield, and the carboxy groups of the palladium complex were converted into oxazolinyl groups to give the Phebox-Pd complexes in 44-57% yield.

  DOI：

  10.1021/om800666x