2-[2-[(2-aminophenyl)methylideneamino]ethyliminomethyl]aniline | 4408-47-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[2-[(2-aminophenyl)methylideneamino]ethyliminomethyl]aniline
• 英文别名: N,N'-ethylenebis(2-aminobenzylidene)
• CAS: 4408-47-3
• 化学式: C₁₆H₁₈N₄
• 分子量: 266.346
• InChiKey: ZFIFWHZGMOGXDV-AYKLPDECSA-N

物化性质

• 熔点：
  182°C
• 溶解度：
  在热甲苯中有非常微弱的浑浊

计算性质

• 辛醇/水分配系数(LogP)：
  2.39
• 重原子数：
  20.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  76.76
• 氢给体数：
  2.0
• 氢受体数：
  4.0

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2921590090

反应信息

• 作为产物：
  描述：

  2-氨基苯甲醛 、 乙二胺 以 乙醇 为溶剂， 反应 1.0h， 以70%的产率得到2-[2-[(2-aminophenyl)methylideneamino]ethyliminomethyl]aniline
  参考文献：
  名称：

  A comparison of the intramolecular and intermolecular hydrogen bonding of N,N′-ethylenebis(aminobenzylidene) in the solid state with its salen analogue

  摘要：

  The crystal structure of H(2)amben has been elucidated for the first time. The close NH...N contact between neighbouring molecules supports strongly the notion that intermolecular hydrogen bonding exists within the crystal lattice, creating a series of molecular chains, which are crosslinked in a three-dimensional array. This intermolecular bonding is suggested to account for the anomalously high melting point of H(2)amben (176-178 degreesC) compared to its H(2)salen counterpart (126-128 degreesC). Although strong intramolecular forces are present in both ligands, H(2)salen contains no intermolecular hydrogen bonds. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.10.032

文献信息

• [EN] PREPARATION OF ISOCYANATOSILANES<br/>[FR] PRÉPARATION D'ISOCYANATOSILANES
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2018222486A1

  公开（公告）日：2018-12-06

  There is provided herein a method of preparing an isocyanatosilane including reacting an olefinic isocyanate with a hydridosilane in the presence of a dinuclear rhodium complex under hydro silylation conditions.

  本文提供了一种制备异氰酸硅烷的方法，包括在水合硅烷化条件下，在二核铑配合物的存在下，将烯丙基异氰酸酯与氢化硅烷反应。
• Method for producing phenol condensate
  申请人：——

  公开号：US20040267057A1

  公开（公告）日：2004-12-30

  Provided is a method for producing a phenol condensate by oxidative condensation of a phenol compound not having a substituted group on at least one ortho-position, in the presence of a specific complex (II) and oxygen, wherein a condensate coupled at para-position of the phenol can be produced in an excellent yield, L-M (X) n (II) wherein L represents a ligand having 2 to 4 nitrogen atoms as donor atoms, M represents copper ion, nickel ion, cobalt ion, iron ion, manganese ion, chromium ion or vanadyl ion, X represents a counter ion, n is a number of Xs.

  提供一种方法，通过在特定复合物（II）和氧的存在下，对至少一个邻位没有取代基的酚化合物进行氧化缩合，从而可以产生一个在酚的对位耦合的缩合物，其产率优异，公式为L-M（X）n（II），其中L代表具有2至4个氮原子作为供体原子的配体，M代表铜离子，镍离子，钴离子，铁离子，锰离子，铬离子或钒离子，X代表计数离子，n是X的数量。
• Method for Producing Aromatic Compound Polymer
  申请人：Higashimura Hideyuki

  公开号：US20090018309A1

  公开（公告）日：2009-01-15

  A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P=Af/Ai (A) and Eo =( Epa+Epc )/2[V]  (B).

  一种生产芳香族化合物聚合物的方法，包括在氧化剂存在下氧化聚合具有两个或更多氢原子直接连接到芳香环的一个或多个芳香族化合物，其中该方法采用由过渡金属配合物或由过渡金属配合物和活化剂制备的催化剂，所述催化剂具有以下公式（A）定义的参数P，P的值为0.50或更高，并且具有以下公式（B）定义的参数Eo，Eo的值为0.50 [V]或更高：P=Af/Ai（A）和Eo=(Epa+Epc)/2[V]（B）。
• RESIN COMPOSITION AND PROCESS FOR PRODUCING THE SAME
  申请人：Japan as represented by Secretary of Agency of Industrial Science and Technology

  公开号：EP1114836A1

  公开（公告）日：2001-07-11

  A curable resin composition, which comprises a resin formed, in the presence of a transition metal complex, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil. A method for producing a curable resin composition comprising a resin formed, in the presence of a catalyst, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil, wherein the catalyst is a transition metal complex. The curable resin composition is useful as a raw material for a urushi-like coating, a friction material, a brake lining material, a brake pad material, a material for forming a coating film, a compound for a recording material, a raw material for an ink, a raw material for a coating, a raw material for a adhesive, a raw material for an epoxy resin, a raw material for a photoresist or antioxidant, and a starting material for a functional polymer.

  一种可固化树脂组合物，它包括在过渡金属络合物存在下，通过聚合含有含酚化合物的植物油的可氧化聚合化合物而形成的树脂。一种生产可固化树脂组合物的方法，该树脂组合物包括在催化剂存在下，通过聚合含有含酚化合物植物油的可氧化聚合化合物而形成的树脂，其中催化剂为过渡金属络合物。这种可固化树脂组合物可用作乌拉石般的涂层的原料、摩擦材料、制动衬片材料、制动片材料、形成涂膜的材料、记录材料的化合物、油墨的原料、涂层的原料、粘合剂的原料、环氧树脂的原料、光刻胶或抗氧化剂的原料以及功能聚合物的起始原料。
• CROSSLINKED POLYMER, PROCESS FOR PRODUCING THE SAME, ABSORBENT STRUCTURE, AND ABSORBENT ARTICLE
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP1275669A1

  公开（公告）日：2003-01-15

  A crosslinked polymer (A) which comprises, as essential structural units, units derived from (a) one or more vinyl monomers selected from the group consisting of water-soluble vinyl monomers and/or vinyl monomers which become water-soluble upon hydrolysis and units derived from (b) a crosslinking agent and which satisfies the following requirements: (1): (X) ≧ 25g/g, (2): (Y) ≧ 15g/g, and (3): (Y) ≧ -0.54 (X) + 41. It has exceedingly high water retentivity and exceedingly high absorbing power under load. When applied to an absorbent structure and an absorbent article, the polymer has excellent absorbing performance. In the relationships, (X) is the amount of physiological saline retained through 1-hour absorption and (Y) is the amount of physiological saline absorbed through 1-hour standing under a load of 60 g/cm2.

  一种交联聚合物(A)，其基本结构单元包括(a)一种或多种乙烯基单体衍生的单 元，这些乙烯基单体选自由水溶性乙烯基单体和/或水解后变成水溶性的乙烯基单体 组成的组，以及(b)一种交联剂衍生的单元，并满足以下要求：(1):(X) ≧ 25g/g, (2)：(Y) ≧ 15 克/克，及 (3)：(Y) ≧ -0.54 (X) + 41。它具有极高的保水性和极高的负载吸附力。当应用于吸水结构和吸水物品时，该聚合物具有优异的吸水性能。在上述关系中，(X) 是在 60 克/平方厘米的负载下，通过 1 小时的吸收所保留的生理盐水量，(Y) 是在 60 克/平方厘米的负载下，通过 1 小时的静置所吸收的生理盐水量。

表征谱图