N,N'-dimethyl-N,N'-disulfanediyl-bis-benzenesulfonamide | 71836-03-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dimethyl-N,N'-disulfanediyl-bis-benzenesulfonamide
• 英文别名: N,N'-Dimethyl-N,N'-disulfandiyl-bis-benzolsulfonamid；N,N'-dimethyl-N,N'-dithiobis(benzenesulfonamide)；Benzenesulfonamide, N,N'-dithiobis[N-methyl-；N-[[benzenesulfonyl(methyl)amino]disulfanyl]-N-methylbenzenesulfonamide
• CAS: 71836-03-8
• 化学式: C₁₄H₁₆N₂O₄S₄
• 分子量: 404.556
• InChiKey: JYRWUKPPRZOIIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  142
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 二氯化二硫 作用下， 生成 N,N'-dimethyl-N,N'-disulfanediyl-bis-benzenesulfonamide
  参考文献：
  名称：

  DE951719

  摘要：

  公开号：

文献信息

• Process for synthesizing N,N'-dithiobis(sulfonamides)
  申请人：The Goodyear Tire & Rubber Company

  公开号：US04877901A1

  公开（公告）日：1989-10-31

  The present invention relates to a process for synthesizing N,N'-dithiobis(sulfonamides) by reacting a sulfonamide of the formula: ##STR1## with sulfur monochloride and caustic in a mixed organic-aqueous mediua, wherein R.sup.1 and R.sup.2 are independently selected from the group consisting of alkyl radicals having from about 1 to about 20 carbon atoms, cycloalkyl radicals having from about 5 to about 20 carbon atoms, phenyl radicals, alkaryl radicals having from about 7 to 20 carbon atoms, and haloaryl radicals having about 6 to about 10 carbon atoms and where R.sup.1 is also selected from radicals having the formula: ##STR2## wherein R.sup.3 and R.sup.4 are individually selected from said alkyl, cycloalkyl, phenyl, alkaryl and haloaryl radicals and wherein R.sup.3 and R.sup.4 can be joined together to represent radicals selected from --CH.sub.2 --.sub.n, where n is an integer of 4 to 7 and --CH.sub.2).sub.2 O--CH.sub.2 --.sub.2.

  本发明涉及一种合成N,N'-二硫代双磺酰胺的方法，其通过将式为：##STR1##的磺酰胺与单氯化硫和碱在混合有机-水介质中反应而得，其中R.sup.1和R.sup.2分别独立地选自于由具有约1至20个碳原子的烷基基团、具有约5至20个碳原子的环烷基团、苯基、具有约7至20个碳原子的烷基芳基基团和具有约6至10个碳原子的卤代芳基基团组成的基团群，其中R.sup.1还选自于具有式：##STR2##的基团，其中R.sup.3和R.sup.4分别独立地选自于上述烷基、环烷基、苯基、烷基芳基和卤代芳基基团，并且R.sup.3和R.sup.4可以结合在一起表示选自于--CH.sub.2 --.sub.n，其中n为4至7的整数和--CH.sub.2).sub.2 O--CH.sub.2 --.sub.2的基团。
• Process for synthesizing N,N'-dithiobis(Sulfonamides)
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0366596A1

  公开（公告）日：1990-05-02

  The present invention relates to a process for synthesizing N,N'-dithiobis(sulfonamides) by reacting a sulfonamide of the formula: with sulfur monochloride and caustic in a mixed organic-aqueous media, wherein R1 and R2 are independently selected from the group consisting of alkyl radicals having from about 1 to about 20 carbon atoms, cycloalkyl radicals having from about 5 to about 20 carbon atoms, phenyl radicals, alkaryl radicals having from about 7 to 20 carbon atoms, and haloaryl radicals having about 6 to about 10 carbon atoms and where R1 is also selected from radicals having the formula: wherein R3 and R4 are individually selected from said alkyl, cycloalkyl, phenyl, alkaryl and haloaryl radicals and wherein R3 and R4 can be joined together to represent radicals selected from (̵CH2)̵n, where n is an integer of 4 to 7 and (̵CH2 )̵2 O(̵CH2 )̵2.

  本发明涉及一种合成 N,N'-二硫代双(磺酰胺)的工艺，其方法是将式中的磺酰胺与一氯 化硫和苛性碱在混合有机-水介质中反应： 其中 R1 和 R2 分别独立地选自具有约 1 至约 20 个碳原子的烷基、具有约 5 至约 20 个碳原子的环烷基、苯基、具有约 7 至约 20 个碳原子的烷芳基和具有约 6 至约 10 个碳原子的卤芳基所组成的组，且 R1 也选自具有以下式子的基团 其中 R3 和 R4 单独选自所述烷基、环烷基、苯基、烷芳基和卤代芳基，且其中 R3 和 R4 可连接在一起代表选自 (̵CH2)̵n 的基，其中 n 为 4 至 7 的整数和 (̵ )̵2 O(̵ )̵2。
• Silica reinforced rubber composition and use in tires
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0723991A1

  公开（公告）日：1996-07-31

  The present invention relates to a rubber composition containing silica reinforcement and pneumatic tires having treads comprised of such rubber composition. The rubber composition comprises an elastomer, silica, optionally carbon black, and a silica coupler comprised of an N,N'-diorgano-N,N'-dithiobis(organosulfonamide).

  本发明涉及一种含有白炭黑补强剂的橡胶组合物和具有由这种橡胶组合物构成的胎面的充气轮胎。该橡胶组合物包含弹性体、白炭黑、可选碳黑以及由 N,N'-二有机-N,N'-二硫代双（有机磺酰胺）组成的白炭黑耦合剂。
• Process for synthesizing N-chlorothio-sulfonamides
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0377552B1

  公开（公告）日：1993-07-28
• US4022828A
  申请人：——

  公开号：US4022828A

  公开（公告）日：1977-05-10