acetyl-benzenesulfonyl-methyl-amine | 90610-41-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: acetyl-benzenesulfonyl-methyl-amine
• 英文别名: N-Benzolsulfonyl-N-methyl-acetamid；Acetyl-benzolsulfonyl-methyl-amin；N-Acetyl-N-methyl-benzolsulfonamid；N-(benzenesulfonyl)-N-methylacetamide
• CAS: 90610-41-6
• 化学式: C₉H₁₁NO₃S
• 分子量: 213.257
• InChiKey: DZBVJDAMKGJGRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  62.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  acetyl-benzenesulfonyl-methyl-amine 、 盐酸甲胺 生成 trimethylformamidine
  参考文献：
  名称：

  77. Am。第三部分 由铵盐或取代的铵盐和N-酰基苯磺烷基酰胺或酰基苯磺酰苯胺制备取代的idine

  摘要：

  DOI：

  10.1039/jr9470000382
• 作为产物：
  描述：

  N-甲基苯磺酰胺 、 乙酸酐 在 硫酸 作用下， 以 乙腈 为溶剂， 以96%的产率得到acetyl-benzenesulfonyl-methyl-amine
  参考文献：
  名称：

  实用的酸催化磺酰胺与羧酸酐的酰化反应

  摘要：

  描述了在空间和电子上不同的磺酰胺和羧酸酐之间的高效反应，以提供单酰化的N-酰基磺酰胺。这代表了硫酸催化磺酰胺酰化作用范围的首次系统公开。

  DOI：

  10.1016/s0040-4039(03)01324-8

文献信息

• Herbicidal Compounds Based on N-Azinyl-N-Phenylsulfonylureas
  申请人：Rosinger Christoph Hugh

  公开号：US20110105324A1

  公开（公告）日：2011-05-05

  What is described are compounds of the formula (I) in which the respective substituents have the meanings given in the description. The compounds of the formula (I) can be used as herbicides and plant growth regulators.

  描述的是具有式(I)的化合物，其中各自的取代基具有说明书中给出的含义。式(I)的化合物可以用作除草剂和植物生长调节剂。
• 2-(BENZYLSULFONYL)OXAZOLE DERIVATIVES, CHIRAL 2-(BENZYLSULFINYL)OXAZOLE DERIVATIVES...
  申请人：Rosinger Christopher Hugh

  公开号：US20110190125A1

  公开（公告）日：2011-08-04

  The invention relates to 2-(benzylsulfonyl)-oxazole derivatives, chiral 2-(benzylsulfinyl)-oxazole derivatives and 2-(benzylsulfanyl)-oxazole derivatives of general formula (I) and the salts thereof, wherein the individual radicals and indexes have the meaning indicated in the description. Also described are methods for the production thereof as well as the use of said compounds as herbicides and plant growth regulators, in particular as herbicides for selectively controlling weeds in plant crops.

  本发明涉及2-(苄磺酰基)-恶唑衍生物、手性2-(苄亚磺酰基)-恶唑衍生物和通式(I)的2-(苄硫基)-恶唑衍生物及其盐，其中各基团和指数的含义如描述中所示。还描述了它们的制备方法以及这些化合物作为除草剂和植物生长调节剂，特别是用于选择性控制作物中杂草的除草剂的使用。
• USE OF SUBSTITUTED ISOQUINOLINONES, ISOQUINOLINDIONES, ISOQUINOLINTRIONES AND DIHYDROISOQUINOLINONES OR IN EACH CASE SALTS THEREOF AS ACTIVE AGENTS AGAINST ABIOTIC STRESS IN PLANTS
  申请人：Frackenpohl Jens

  公开号：US20140302987A1

  公开（公告）日：2014-10-09

  Use of substituted isoquinolinones, isoquinolinediones, isoquinolinetriones and dihydroisoquinolinones of the general formula (I) or their respective salts where the radicals in the general formula (I) correspond to the definitions given in the description, for enhancing stress tolerance in plants to abiotic stress, for strengthening plant growth and/or for increasing plant yield, and selected processes for preparing the compounds mentioned above.

  使用通式（I）中的替代的异喹啉酮、异喹啉二酮、异喹啉三酮和二氢异喹啉酮或它们的相应盐，其中通式（I）中的基团对应于描述中给出的定义，用于增强植物对非生物胁迫的耐受性，增强植物生长和/或增加植物产量，并选择性地制备上述化合物的过程。
• Infrared Spectra of Phenylsulfonyl Derivatives. (4). The Infrared Spectra of N-Acylsulfonamide Derivatives. (Organic Analysis. XLVIII)
  作者：Yo Ueda、Hiroshige Yano、Tsutomu Momose

  DOI：10.1248/cpb.12.5

  日期：——

  The splitting phenomenon of the carbonyl absorptions and the shifts of S-N stretching vibrations to a longer wave length region of some N-acyl-N-substituted-sulfonamide derivatives measured in solid state were described. Tertiary sulfonamides had their SO2 stretching vibrations at a shorter wave length region than secondary sulfonamides. N-Acetyl-N-alkylmethane (or ethane) sulfonamide showed strong C-N stretching vibrations of the group N-CH2-R at about 1125cm-1. N-Acyl-N-substituted-sulfonamide derivatives had very strong asymmetric stretching vibrations of the group C-CO-N at 1250∼1290cm-1. Synthesis of some sulfonamide derivatives is also described.

  在固态下测得的某些N-酰基-N-取代磺酰胺衍生物的羰基吸收分裂现象以及S-N伸缩振动向长波长区域的位移均有所描述。三级磺酰胺的SO2伸缩振动比二级磺酰胺位于更短的波长区域。N-乙酰基-N-烷基甲烷(或乙烷)磺酰胺在约1125cm-1处显示出强烈的N-CH2-R基团的C-N伸缩振动。N-酰基-N-取代磺酰胺衍生物在1250∼1290cm-1处具有非常强烈的C-CO-N基团的不对称伸缩振动。此外，还描述了一些磺酰胺衍生物的合成。
• 1-(Heteroaryl)pyrazol-4-ylacetic acids, processes for their preparation and their use as herbicides and plant growth regulators
  申请人：Jakobi Harald

  公开号：US20110257014A1

  公开（公告）日：2011-10-20

  The invention provides compounds of the formula (I) and salts thereof which are described herein. The compounds (I) or salts thereof are suitable for use as herbicides and plant growth regulators, in particular as herbicides for the selective control of harmful plants in crops of useful plants, and can be prepared by the described processes.

  该发明提供了公式（I）的化合物及其盐，这些化合物适用于作为除草剂和植物生长调节剂，特别是作为对有用植物作物中有害植物的选择性控制除草剂，并且可以通过所述的方法制备。