2,4,6-trichlorophenyl methacrylate | 18967-27-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 2,4,6-trichlorophenyl methacrylate
• 英文别名: methacrylic acid-(2,4,6-trichloro-phenyl ester)；Methacrylsaeure-(2,4,6-trichlor-phenylester)；2-methyl-2-propenoic acid, 2,4,6-trichlorophenyl ester；2-methyl-acrylic acid 2,4,6-trichloro-phenyl ester；2-Propenoic acid, 2-methyl-, 2,4,6-trichlorophenyl ester；(2,4,6-trichlorophenyl) 2-methylprop-2-enoate
• CAS: 18967-27-6
• 化学式: C₁₀H₇Cl₃O₂
• 分子量: 265.523
• InChiKey: DGZZQOZXBPFEIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4,6-三氯苯酚 、 甲基丙烯酰氯 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 2,4,6-trichlorophenyl methacrylate
  参考文献：
  名称：

  Estimation on the optic loss for acrylic polymers by theoretical modification

  摘要：

  Various fluorinated/chlorinated polymers were synthesized and characterized by FT-IR and H-1 NMR. Also, theoretical optic loss of the POF were investigated and proposed for the purpose of finding a definite rule of the optic loss.From the computation of the results, the modified equation was theoretically deduced, and the optic loss of each prepared polymer was measured and compared with the calculated optical loss of polymers. Also, it was found that the optic loss from the modified equation fitted well with the experimental data. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(03)00144-1

文献信息

• Polymers for antifouling coatings and a process for the preparation thereof
  申请人：Jotun A/S

  公开号：US20030225230A1

  公开（公告）日：2003-12-04

  Polymer for antifouling coatings which comprises units corresponding to the following monomers: A) 5 to 100 mol. % of one or more compounds of general formula (I) in which R=H or CH 3 ; X=O or S; R 1 =Ph(R 2 ) m , —C(H) 3−(p+q) (CO—R) 3 p (COOR 3 ) q , —(CH 2 ) n −(CO) t —COOR 3 or optionally substituted thiadiazolyl and thiazolylsulfamyl groups; Ph=phenyl; m=1-3; p=0-3; q=0-3; p+q=1-3; s=0 or 1; t=0 or 1; R 2 =each independently selected from halogen, —C(O)H, —COOR 3 , —CH 2 —COOR 3 , —O—R 3 , —NH COOR 3 , —NH—CO—R 3 and —NH 2 ; R 3 =II or optionally halogen substituted alkyl, aryl, cycloalkyl, aralkyl groups with 1-10 C atoms; and B) 0 to 95 mol. % of one or more other ethylenically unsaturated compound. Processes for preparing the polymers defined above, points containing said polymers, and the use of monomers of the above formula (I) for preparing for antifouling coatings. 1

  抗污涂层聚合物，其包含与以下单体相应的单位：A）5至100摩尔％的一个或多个化合物，其通式为（I），其中R= H或CH3; X= O或S; R1= Ph（R2）m，-C（H）3−（p+q）（CO-R）3p（COOR3）q，-（CH2）n−（CO）t-COOR3或可选的取代硫脲基和噻唑磺酰基；Ph=苯基；m=1-3；p=0-3；q=0-3；p+q=1-3；s=0或1；t=0或1；R2=各自独立选择自卤素，-C（O）H，-COOR3，-CH2-COOR3，-O-R3，-NH COOR3，-NH-CO-R3和-NH2; R3=II或可选的卤素取代的烷基，芳基，环烷基，芳基烷基，具有1-10个C原子；和B）0至95摩尔％的一个或多个其他乙烯基不饱和化合物。制备上述聚合物的过程，包含该聚合物的点，以及上述式（I）的单体用于制备抗污涂层的使用。
• PHOTOPOLYMER FORMULATIONS HAVING A LOW CROSSLINKING DENSITY
  申请人：Weiser Marc-Stephan

  公开号：US20100087564A1

  公开（公告）日：2010-04-08

  The invention relates to photopolymer formulations based on a polymeric network as a matrix and at least one photopolymerizable monomer dissolved therein and to a method for the production of holographic media from such photopolymers and to the use thereof.

  该发明涉及基于聚合网络作为基质并至少溶解其中一种光聚合单体的光聚合物配方，以及从这种光聚合物制备全息介质的方法和使用它的方法。
• SPECIAL POLYETHER-BASED POLYURETHANE FORMULATIONS FOR THE PRODUCTION OF HOLOGRAPHIC MEDIA
  申请人：Weiser Marc-Stephan

  公开号：US20100086861A1

  公开（公告）日：2010-04-08

  The present invention relates to novel polyurethane compositions which are advantageous for the production of holographic media, inter alia for data storage, but also for optical applications of different types.

  本发明涉及新型聚氨酯组合物，其对于全息媒体的生产具有优势，包括数据存储，但也适用于不同类型的光学应用。
• POLYETHER-BASED POLYURETHANE FORMULATIONS FOR THE PRODUCTION OF HOLOGRAPHIC MEDIA
  申请人：Weiser Marc-Stephan

  公开号：US20100112459A1

  公开（公告）日：2010-05-06

  The present invention relates to novel polyurethane compositions which are advantageous for the production of holographic media, inter alia for data storage, but also for optical applications of different types.

  本发明涉及新型聚氨酯组合物，这些组合物对于生产全息媒体具有优势，包括数据存储，但也适用于不同类型的光学应用。
• PREPOLYMER-BASED POLYURETHANE FORMULATIONS FOR PRODUCING HOLOGRAPHIC MEDIA
  申请人：Weiser Marc-Stephan

  公开号：US20110189591A1

  公开（公告）日：2011-08-04

  The present invention relates to a polyurethane composition comprising A) a polyisocyanate component comprising an exclusively diol-based NCO-terminated polyurethane prepolymer, wherein the NCO groups are bonded in a primary manner, B) an isocyanate-reactive polymer, C) a compound having groups which react by polymerizing with an ethylenically unsaturated compound under the action of actinic radiation (radiation-curing groups) wherein the compound is free of NCO groups, D) a free-radical stabilizer, E) a photo initiator, F) optionally a catalyst, G) optionally assistants and additives.

  本发明涉及一种聚氨酯组合物，包括A）聚异氰酸酯组分，其中包括一种仅基于二元醇的NCO-末端聚氨酯预聚体，其中NCO基团以一次方式键合，B）异氰酸酯反应性聚合物，C）具有在光致辐射作用下与乙烯基不饱和化合物聚合反应的基团（辐射固化基团）的化合物，该化合物不含NCO基团，D）自由基稳定剂，E）光引发剂，F）可选催化剂，G）可选助剂和添加剂。

表征谱图