p-chloro-α,α-dimethyl α-toluenethiol | 54894-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-chloro-α,α-dimethyl α-toluenethiol
• 英文别名: 2-(4-Chlorophenyl)propane-2-thiol
• CAS: 54894-87-0
• 化学式: C₉H₁₁ClS
• 分子量: 186.705
• InChiKey: CUWMXZJKHOFENI-UHFFFAOYSA-N

物化性质

• 沸点：
  252.7±15.0 °C(Predicted)
• 密度：
  1.127±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  chloromethyl p-chloro-α,α-dimethyl-benzyl sulfide 、 p-chloro-α,α-dimethyl α-toluenethiol 、 4-氯-alpha,alpha-二甲基苄醇 、 二硫代磷酸二乙酯钾盐 以 二氯甲烷 、 丙酮 为溶剂， 生成 S-(p-Chloro-α,α-Dimethylbenzylthio)methyl O,O-Diethyl Phosphorodithioate
  参考文献：
  名称：

  S-(.alpha.-substituted-arylmethylthio, -arylmethylsulfinyl, and

  摘要：

  提供了一种新型的S-（.alpha.-取代基-芳基甲硫基，芳基甲硫氧基和芳基甲磺酰基）甲基磷酸酯，具有降低哺乳动物毒性的特点，并提供了使用这些酯类控制昆虫和螨虫的方法。同时，还提供了一种方法，通过将上述酯类的杀虫或杀螨有效量施用于植物的叶面或生长土壤中，保护植物免受昆虫和螨虫的攻击。

  公开号：

  US04000269A1

文献信息

• PROCESS FOR PRODUCING BORON COMPOUNDS
  申请人：Showa Denko Kabushiki Kaisha

  公开号：EP0974595A1

  公开（公告）日：2000-01-26

  A method of producing a boron-based compound represented by general formula (1) including a first step of reacting lithium, magnesium or a compound containing lithium, a compound represented by general formula (2), and a compound represented by general formula (3): R2-Y to produce a borate metal salt represented by general formula (4), and a second step of adding to the borate metal salt an onium halide represented by general formula (5): Z+ · X- to effect ion exchange reaction (the symbols in the formulae have the same meanings as described in the specification). According to the production method of the present invention, a high purity boron-based compound represented by the general formula (1) above useful as a photopolymerization initiator and a light-absorbing decolorizing agent can be obtained in a short time and a high yield as compared with the conventional method.

  一种生产通式(1)代表的硼基化合物的方法，包括第一步使锂、镁或含锂的化合物、通式(2)代表的化合物和通式(3)代表的化合物反应：R2-Y 反应生成通式（4）代表的硼酸盐金属盐，第二步向硼酸盐金属盐中加入通式（5）代表的卤化铌：Z+ - X- 进行离子交换反应（式中符号的含义与说明书中描述的相同）。 根据本发明的生产方法，与传统方法相比，可在短时间内高产率地获得上述通式 （1）所代表的高纯度硼基化合物，该化合物可用作光聚合引发剂和光吸收脱色剂。
• Ink composition, inkjet recording method, production method of planographic printing plate, and planographic printing plate
  申请人：Fujifilm Corporation

  公开号：EP1795564A1

  公开（公告）日：2007-06-13

  An ink composition includes a polymerizable compound (a) having a cyclic ether-containing partial structure and at least one fluorine atom in a molecule, a polymerization initiator (b), and a colorant (c). A hydrophobic image region can be formed on a planographic printing plate by ejecting the ink composition onto a support for the planographic printing plate and curing the ejected ink composition. Also provided is an inkjet recording method using the ink composition, a printed matter obtained by using a curable ink composition with high sensitivity, a planographic printing plate, and a method of producing a planographic printing plate.

  一种油墨组合物包括一种可聚合化合物（a），该化合物具有含环醚的部分结构，分子中至少有一个氟原子；一种聚合引发剂（b）和一种着色剂（c）。通过将墨水组合物喷射到平版印刷板的支架上并固化喷射出的墨水组合物，可在平版印刷板上形成疏水图像区域。此外，还提供了使用该墨水组合物的喷墨记录方法、使用高灵敏度固化墨水组合物获得的印刷品、平版印刷板以及平版印刷板的生产方法。
• ELECTRICALLY CONDUCTIVE COMPOSITION, ELECTRICALLY CONDUCTIVE FILM USING SAID COMPOSITION AND PRODUCTION METHOD THEREFOR
  申请人：FUJIFILM Corporation

  公开号：EP2692762A1

  公开（公告）日：2014-02-05

  An electrically conductive composition, containing an electrically conductive polymer, and an onium salt compound as a dopant to the electrically conductive polymer, an electrically conductive film formed by shaping the composition and a method of producing the electrically conductive film.

  一种导电组合物，含有一种导电聚合物和一种作为导电聚合物掺杂剂的铌盐化合物，一种通过塑造该组合物形成的导电薄膜，以及一种生产该导电薄膜的方法。
• CONDUCTIVE COMPOSITION, CONDUCTIVE FILM USING CONDUCIVE COMPOSITION, AND METHOD FOR MANUFACTURING CONDUCTIVE FILM
  申请人：FUJIFILM Corporation

  公开号：EP2693444A1

  公开（公告）日：2014-02-05

  Disclosed are: a conductive composition containing (A) carbon nanotubes, (B) a conductive polymer, and (C) an onium salt compound; a conductive film using the composition; and a method for manufacturing the conductive film.

  公开了：一种导电组合物，包含 (A)碳纳米管、(B) 导电聚合物和 (C) 铟盐化合物；一种使用该组合物的导电薄膜；以及一种制造该导电薄膜的方法。
• THERMOELECTRIC CONVERSION MATERIAL AND THERMOELECTRIC CONVERSION ELEMENT
  申请人：FUJI-FILM Corporation

  公开号：EP2763200A1

  公开（公告）日：2014-08-06

  A thermoelectric conversion material containing an electrically conductive polymer and a thermal excitation assist agent, wherein the thermal excitation assist agent is a compound that does not form a doping level in the electrically conductive polymer, an energy level of LUMO (lowest unoccupied molecular orbital) of the thermal excitation assist agent and an energy level of HOMO (highest occupied molecular orbital) of the electrically conductive polymer satisfy following numerical expression (I): Numerical expression (I); 0.1⁢eV≤HOMO of an electrically conductive polymer-LUMO of a thermal excitation assistant agent≤1.9eV wherein, in numerical expression (I), |HOMO of an electrically conductive polymer| represents an absolute value of an energy level of HOMO of the electrically conductive polymer, and |LUMO of a thermal excitation assist agent| represents an absolute value of an energy level of LUMO of the thermal excitation assist agent, respectively.

  一种包含导电聚合物和热激发辅助剂的热电转换材料，其中热激发辅助剂为不在导电聚合物中形成掺杂水平的化合物，热激发辅助剂的 LUMO（最低未占据分子轨道）能级和导电聚合物的 HOMO（最高占据分子轨道）能级满足以下数值表达式（I）：数值表达式（I）；0.1eV≤导电聚合物的 HOMO-热激发辅助剂的 LUMO≤1.9eV 其中，在数值表达式（I）中，|导电聚合物的 HOMO|分别表示导电聚合物 HOMO 能级的绝对值，|热激发辅助剂的 LUMO|分别表示热激发辅助剂 LUMO 能级的绝对值。