O-(2,4,5-trichlorophenyl)-sulfamate | 25998-94-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: O-(2,4,5-trichlorophenyl)-sulfamate
• 英文别名: O-2,4,5-trichlorophenyl sulfamate；Amidosulfonsaeure-(2,4,5-Trichlorphenyl)-ester；2,4,5-Trichlorophenyl sulfamate；(2,4,5-trichlorophenyl) sulfamate
• CAS: 25998-94-1
• 化学式: C₆H₄Cl₃NO₃S
• mdl: MFCD18430103
• 分子量: 276.528
• InChiKey: YXBUZXVWXBPUFM-UHFFFAOYSA-N

物化性质

• 熔点：
  158 °C
• 沸点：
  410.6±55.0 °C(Predicted)
• 密度：
  1.755±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,4,5-三氯苯酚 在 水 作用下， 以 氯苯 为溶剂， 生成 O-(2,4,5-trichlorophenyl)-sulfamate
  参考文献：
  名称：

  Lohaus,G., Chemische Berichte, 1972, vol. 105, p. 2791 - 2799

  摘要：

  DOI：

文献信息

• Uracil substituted phenyl sulfamoyl carboxamides
  申请人：Intellectual Property Department BASF Aktiengesellschaft

  公开号：US20020045550A1

  公开（公告）日：2002-04-18

  Novel uracil substituted phenyl sulfamoyl carboxamides I 1 and salts thereof, where A=oxygen or sulfur; X 1 =H, halogen, C 1 -C 4 -alkyl; X 2 =H, CN, CS—NH 2 , halogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl; X 3 =H, CN, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxyalkyl, C 3 -C 7 -cycloalkyl, C 3 -C 6 -alkenyl, C 3 -C 6 -alkynyl, optionally substituted benzyl; R 1 , R 2 =H, halogen, optionally substituted hydroxy, C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, C 3 -C 10 -alkynyl, C 3 -C 7 -cycloalkyl, phenyl, benzyl or C 5 -C 7 -cycloalkenyl, or R 1 +R 2 together with the atom to which they are attached form a 3- to 7-membered heterocyclic ring; Q is selected from Q 1 to Q 40 as defined in the description. Use: As herbicides; for the desiccation/defoliation of plants.

  新型尿嘧啶取代苯基磺酰基羧酰胺I1及其盐，其中A＝氧或硫；X1＝H、卤素、C1-C4-烷基；X2＝H、CN、CS—NH2、卤素、C1-C4-烷基、C1-C4-卤代烷基；X3＝H、CN、C1-C6-烷基、C1-C6-烷氧基烷基、C3-C7-环烷基、C3-C6-烯基、C3-C6-炔基、可选择地取代的苄基；R1、R2＝H、卤素、可选择地取代的羟基、C1-C10-烷基、C2-C10-烯基、C3-C10-炔基、C3-C7-环烷基、苯基、苄基或C5-C7-环烯基，或R1＋R2与它们连接的原子共同形成3-至7-成员杂环环；Q从描述中定义的Q1到Q40中选择。用途：作为除草剂；用于植物的干燥/落叶。
• Sulfanomide herbicides
  申请人：Shell Research Limited

  公开号：US05420099A1

  公开（公告）日：1995-05-30

  A compound having the formula ##STR1## wherein A is CR.sub.7 ; and R.sup.1 through R.sup.7 are substituents such as hydrogen, halogen, branched and straight chain hydrocarbons, cyclic hydrocarbons, aromatics, and sulfur and nitrogen containing functional groups. Further, R.sup.5 and R.sup.6 may be taken together with the atom to which they are attached to form a group ##STR2## in which R.sup.9 and R.sup.10 are further functional groups. The compounds are useful in herbicidal compositions, particularly in combination with carriers and surfactants. A process for making this compound is also presented.

  化合物的化学式为##STR1##其中A是CR.sub.7；R.sup.1到R.sup.7是取代基，例如氢、卤素、支链和直链烃、环烃、芳香族和含有硫和氮的功能基团。此外，R.sup.5和R.sup.6可以与它们所连接的原子一起形成一个基团##STR2##其中R.sup.9和R.sup.10是进一步的功能基团。这些化合物在除草剂组合物中特别有用，尤其是与载体和表面活性剂结合使用。还提供了一种制备该化合物的方法。
• URACIL SUBSTITUTED PHENYL SULFAMOYL CARBOXAMIDES
  申请人：——

  公开号：US20040220172A1

  公开（公告）日：2004-11-04

  Novel uracil substituted phenyl sulfanoyl carboxamides I 1 and salts thereof, where A=oxygen or sulfur; X 1 =H, halogen, C 1 -C 4 -alkyl; X 2 =H, CN, CS—NH 2 , halogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl; X 3 =H, CN, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxyalkyl, C 3 -C 7 -cycloalkyl, C 3 -C 6 -alkenyl, C 3 -C 6 -alkynyl, optionally substituted benzyl; R 1 , R 2 =H, halogen, optionally substituted hydroxy, C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, C 3 -C 10 -alkynyl, C 3 -C 7 -cycloalkyl, phenyl, benzyl or C 5 -C 7 -cycloalkenyl, or R 1 +R 2 together with the atom to which they are attached form a 3- to 7-membered heterocyclic ring; Q is selected from Q 1 to Q 40 as defined in the description. Use: As herbicides; for the desiccation/defoliation of plants.

  新型尿嘧啶取代苯基磺酰基羧酰胺I1及其盐，其中A = 氧或硫；X1 = H、卤素、C1-C4烷基；X2 = H、CN、CS—NH2、卤素、C1-C4烷基、C1-C4卤代烷基；X3 = H、CN、C1-C6烷基、C1-C6烷氧基烷基、C3-C7环烷基、C3-C6烯基、C3-C6炔基、可选取代苄基；R1、R2 = H、卤素、可选取代羟基、C1-C10烷基、C2-C10烯基、C3-C10炔基、C3-C7环烷基、苯基、苄基或C5-C7环烯基，或R1+R2结合成3-至7-成员杂环环；Q从Q1到Q40中选择，如描述中所定义。用途：作为除草剂；用于植物的脱水/落叶。
• Sulphonamide herbicides
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0549079A1

  公开（公告）日：1993-06-30

  Compounds of the formula in which    A is nitrogen or CR⁷;    R¹, R² and R⁷ each independently are hydrogen, halogen, formyl, cyano, carboxy or azido, or optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkenyloxy, alkynyloxy, aryloxy, alkylthio, alkenylthio, alkynylthio, arylthio, alkylcarbonyl, alkoxycarbonyl, amino. aminoxy or dialkyliminoxy;    R³ is hydrogen, or optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclic, aralkyl or aryl;    R⁴ is hydrogen or optionally substituted alkyl, alkenyl, aralkyl, aryl, heterocyclic or acyl; and    R⁵ and R⁶ each independently are hydrogen or optionally substituted alkyl, alkoxy, alkenyl, alkynyl, aryl, aralkyl, amino, cycloalkyl or heterocyclic, or a sulphonyl-containing group, or where R¹¹ is alkylthio, or together form where R⁹ and R¹⁰ each independently are hydrogen, alkyl, alkoxy, aryl, aralkyl or dialkylamino, or R⁹ and R¹⁰ together form optionally substituted heterocyclic or optionally interrupted alkylene chain; and salts thereof, have herbicidal properties.

  式中的化合物 其中 A 是氮或 CR⁷； R¹、R²和R⁷各自独立地为氢、卤素、甲酰基、氰基、羧基或叠氮基，或任选取代的烷基、烯基、炔基、环烷基、烷氧基、烯氧基、炔氧基、芳氧基、烷硫基、烯硫基、炔硫基、芳硫基、烷基羰基、烷氧基羰基、氨基、氨氧基或二烷基亚氨基氧基； R³ 是氢、或任选取代的烷基、烯基、炔基、环烷基、杂环基、芳基或芳基； R⁴ 是氢或任选取代的烷基、烯基、芳基、芳烷基、杂环基或酰基；以及 R⁵ 和 R⁶ 各自独立地为氢或任选取代的烷基、烷氧基、烯基、炔基、芳基、芳烷基、氨基、环烷基或杂环基，或含磺酰的基团，或 其中 R¹¹ 是烷硫基，或共同形成 其中 R⁹ 和 R¹⁰ 各自独立地为氢、烷基、烷氧基、芳基、芳烷基或二烷基氨基，或 R⁹ 和 R¹⁰ 共同形成任选取代的杂环或任选间断的亚烷基链；及其盐类具有除草特性。
• SUBSTITUTED PHENYL SULFAMOYL CARBOXAMIDES
  申请人：BASF SE

  公开号：EP1226127B1

  公开（公告）日：2009-07-01