m-Fluorbenzoldiazonium | 20460-04-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: m-Fluorbenzoldiazonium
• 英文别名: 3-Fluorobenzenediazonium
• CAS: 20460-04-2
• 化学式: C₆H₄FN₂
• 分子量: 123.11
• InChiKey: DRWIWCJJCVACHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  m-Fluorbenzoldiazonium 在 铜 、 potassium iodide 作用下， 生成 3-氟联苯
  参考文献：
  名称：

  Fukui et al., Nippon Kagaku Zasshi, 1958, vol. 79, p. 1120

  摘要：

  DOI：

文献信息

• [EN] PREPARATION OF 3,3-DIALKXOY-1-METHYLENEPROPYL ARENES<br/>[FR] PRÉPARATION DE 3,3-DIALKOXY-1-MÉTHYLÈNEPROPYL ARÈNES
  申请人：LONZA AG

  公开号：WO2012150281A1

  公开（公告）日：2012-11-08

  The invention discloses a method for the preparation of 3,3-dialkxoy-1-methylenepropyl arenes from crotonaldehyde and aryldiazonium salts, and intermediates for the preparation of perfumes.

  该发明公开了一种从己烯醛和芳基重氮盐制备3,3-二烷氧基-1-亚甲基丙基芳烃的方法，以及用于制备香水的中间体。
• Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
  作者：Lorenzo Di Terlizzi、Simone Scaringi、Carlotta Raviola、Riccardo Pedrazzani、Marco Bandini、Maurizio Fagnoni、Stefano Protti

  DOI：10.1021/acs.joc.2c00225

  日期：2022.4.1

  The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh3AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions.

  在PPh 3 AuCl作为催化剂的情况下，在可见光照射下成功地通过芳基偶氮砜制备了对称（杂）联芳基化合物。本方案可以在无光催化剂的条件下在有机水溶剂中有效合成多种目标化合物。
• Transition metal tris(1-pyrazolyl)borates containing nitroso and arylazo ligands
  作者：Swiatoslav Trofimenko

  DOI：10.1021/ic50082a028

  日期：1969.12
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.5, 1.5.3, page 22 - 36
  作者：

  DOI：——

  日期：——
• NEW PROCESS FOR PREPARING ARYLBORANES BY ARYLATION OF ORGANOBORON COMPOUNDS
  申请人：UNIVERSITE DE BORDEAUX

  公开号：US20150191493A1

  公开（公告）日：2015-07-09

  A new process for the preparation of an arylborane compound, by arylation of a B—H bond, which includes a step (1) of contacting an arenediazonium salt or a heteroarenediazonium salt with an organoboron compound containing at least one B—H bond, in a reaction medium containing a solvent, in the absence of base, in the absence or in the presence of an activating agent, for the preparation of an arylborane compound, and a possible step (2) of recovery and purification of the arylborane compound obtained at the step (1), the arylborane being in particular an aminoarylborane, and a possible step (3) of refunctionalization of the arylborane obtained at step (1) or (2) for the preparation of aryl boronic derivatives or arylborates.