phenyl N-(2-propenyl)carbamate | 40580-72-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl N-(2-propenyl)carbamate
• 英文别名: phenyl-N-allylcarbamate；Phenyl allylcarbamate；Phenyl-N-allylcarbamat；phenyl N-prop-2-enylcarbamate
• CAS: 40580-72-1
• 化学式: C₁₀H₁₁NO₂
• mdl: MFCD20355253
• 分子量: 177.203
• InChiKey: LMUQEPCBEXZZIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  phenyl N-(2-propenyl)carbamate 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 60.0h， 以100%的产率得到Phenyl oxiran-2-ylmethylcarbamate
  参考文献：
  名称：

  Alkynyliodonium Salts in Organic Synthesis. Development of a Unified Strategy for the Syntheses of (−)-Agelastatin A and (−)-Agelastatin B

  摘要：

  The total syntheses of natural agelastatin A and agelastatin B were accomplished via a strategy that utilized an alkynyliodonium. salt --> alkylidenecarbene --> cyclopentene transformation to convert a relatively simple amino alcohol derivative to the functionalized core of the agelastatin system. Subsequent manipulations delivered debromoagelastatin, which served as a precursor to both agelastatin A and agelastatin B. Alkylidenecarbene insertion chemoselectivity issues were explored en route to the final targets.

  DOI：

  10.1021/jo026287v
• 作为产物：
  描述：

  苯酚 在 三乙胺 作用下， 以 二氯甲烷 、 苯 为溶剂， 反应 1.67h， 生成 phenyl N-(2-propenyl)carbamate
  参考文献：
  名称：

  Patonay, Tamas; Patonay-Peli, Erzsebet; Mogyorodi, Ferenc, Synthetic Communications, 1990, vol. 20, # 18, p. 2865 - 2885

  摘要：

  DOI：

文献信息

• [EN] HERBICIDAL PYRIMIDINE COMPOUNDS<br/>[FR] COMPOSÉS HERBICIDES DE PYRIMIDINE
  申请人：BASF SE

  公开号：WO2018019574A1

  公开（公告）日：2018-02-01

  The present invention relates to the pyrimidine compounds of formula (I), or their agriculturally acceptable salts or derivatives as herbicides, wherein the variables are defined according to the description, use of pyrimidine compounds of formula (I) as herbicide, compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidal effective amount of at least one pyrimidine compounds of the formula (I) to act on plants, their seed and/or their habitat.

  本发明涉及式(I)的嘧啶化合物，或其农业上可接受的盐或衍生物作为除草剂，其中变量根据描述定义，使用式(I)的嘧啶化合物作为除草剂，包含它们的组合物及其用作除草剂，即用于控制有害植物，以及一种控制不需要的植被的方法，该方法包括使至少一种式(I)的嘧啶化合物以除草有效量作用于植物、其种子和/或其栖息地。
• Manganese dioxide in a new role of Sulfur extrusion in thioamides
  作者：B. Radha Rani、M.F. Rahman、U.T. Bhalerao

  DOI：10.1016/s0040-4020(01)88517-3

  日期：1992.1

  A simple and efficient procedure for the mild conversion of thioamides to amides in good yields using active manganese dioxide is described.

  描述了使用活性二氧化锰以高收率将硫酰胺轻度转化为酰胺的简单有效的方法。
• [EN] CONDENSED ISOXAZOLINE DERIVATIVES AND THEIR USE AS HERBICIDES<br/>[FR] DÉRIVÉS D'ISOXAZOLINE CONDENSÉS ET LEUR UTILISATION COMME HERBICIDES
  申请人：BASF SE

  公开号：WO2021224040A1

  公开（公告）日：2021-11-11

  The invention relates to compounds of formula (I), and their use as herbicides. In said formula, R1 to R6 represent groups such as hydrogen, halo-gen or organic groups such as alkyl, alkenyl, alkynyl, or alkoxy; W is a bicyclic heterocycle; X is a bond or a divalent unit; Y is hydrogen, cyano, hydroxyl or a linear or cyclic organic group. The invention further refers to a composition comprising such compound and to the use thereof for controlling unwanted vegetation.

  该发明涉及公式（I）的化合物，以及它们作为除草剂的用途。在该公式中，R1到R6代表诸如氢、卤素或有机基团（如烷基、烯基、炔基或烷氧基）等基团；W是一个双环杂环；X是一个键或二价基团；Y是氢、氰基、羟基或线性或环状有机基团。该发明还涉及包含这种化合物的组合物以及将其用于控制不受欢迎的植被。
• [EN] HERBICIDAL BENZOXAZINONES<br/>[FR] BENZOXAZINONES HERBICIDES
  申请人：BASF SE

  公开号：WO2012041789A1

  公开（公告）日：2012-04-05

  The present invention provides benzoxazinones of formula I wherein R1 is hydrogen or halogen; R2 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl, C1-C6-alkoxy or C3- C6-cycloalkyl-C1-C6-alkyl; R3 is halogen; R4 is halogen; X is O or S; and Y is a substituted or unsubstituted heterocycle; Benzoxazinones of formula I are useful as herbicides.

  本发明提供式I苯并噁嗪酮，其中R1为氢或卤素；R2为氢、C1-C6烷基、C1-C6卤代烷基、C3-C6环烷基、C3-C6烯基、C3-C6卤代烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基或C3-C6环烷基-C1-C6烷基；R3为卤素；R4为卤素；X为O或S；Y为取代或未取代的杂环；式I苯并噁嗪酮可作为除草剂使用。
• [EN] PYRAZOLOPYRANS HAVING HERBICIDAL AND PHARMACEUTICAL PROPERTIES<br/>[FR] PYRAZOLOPYRANES DOTÉS DE PROPRIÉTÉS PHARMACEUTIQUES ET HERBICIDES
  申请人：BASF SE

  公开号：WO2013182472A1

  公开（公告）日：2013-12-12

  The present invention relates to a pyrazolopyran of the general formula I wherein the variables are defined according to the description, including a tautomer, salt, cleavable prodrug, or mixtures thereof, in particular to said pyrazolopyran for use as a medicament and/or an inhibitor of the enzyme serinehydroxymethyltransferase (SHMT). The invention also relates to a process the preparation of a pyrazolopyran of the formula I, to compositions comprising said compound and processes for the preparation of these compositions. Further it relates to use of the pyrazolopyran of formula I as an herbicide as well as to a method of controlling undesired vegetation.

  本发明涉及一种通式I的吡唑吡喃化合物，其中变量根据描述定义，包括互变异构体、盐、可裂解的前药或其混合物，特别是用作药物和/或酶丝氨酸羟甲基转移酶（SHMT）的抑制剂的所述吡唑吡喃化合物。该发明还涉及一种制备通式I的吡唑吡喃化合物的方法，包括含有所述化合物的组合物以及制备这些组合物的方法。此外，本发明还涉及将通式I的吡唑吡喃化合物用作除草剂，以及一种控制不受欢迎植被的方法。