3-[4-(4-methoxy{4'-[4-methoxy(3-methylphenyl)anilino][1,1'-biphenyl]-4-yl}anilino)phenoxy]propyl methacrylate | 433716-28-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-[4-(4-methoxy{4'-[4-methoxy(3-methylphenyl)anilino][1,1'-biphenyl]-4-yl}anilino)phenoxy]propyl methacrylate
• 英文别名: 3-[4-[4-[4-(4-methoxy-N-(3-methylphenyl)anilino)phenyl]-N-(4-methoxyphenyl)anilino]phenoxy]propyl 2-methylprop-2-enoate
• CAS: 433716-28-0
• 化学式: C₄₆H₄₄N₂O₅
• 分子量: 704.866
• InChiKey: RMGGPGBFMMBLHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  53
• 可旋转键数：
  16
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  60.5
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  N-(4-methoxyphenyl)-3-methylaniline 在 tris(dibenzylideneacetone)dipalladium (0) 4-二甲氨基吡啶 、 1,1'-双(二苯基膦)二茂铁 、 四丁基氟化铵 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 0.34h， 生成 3-[4-(4-methoxy{4'-[4-methoxy(3-methylphenyl)anilino][1,1'-biphenyl]-4-yl}anilino)phenoxy]propyl methacrylate
  参考文献：
  名称：

  Synthesis of Photo-Crosslinkable Hole-Transport Polymers with Tunable Oxidation Potentials And Their Use In Organic Light-Emitting Diodes

  摘要：

  已经合成了一系列可光交联的芳胺基孔导电共聚物。所采用的合成方法允许通过引入电子供体或吸电子基团来调节聚合物的红氧还原电位。在紫外线辐射照射下，聚合物变得不溶，用UV/Vis吸收光谱学证明了这一点，这一特性对通过溶液处理技术制造多层有机发光二极管（OLED）非常有用。基于这些孔导电聚合物的OLED已经被制造，并对器件性能进行了评估。光交联过程已得到优化，以至于不再对器件性能产生负面影响。

  DOI：

  10.1055/s-2002-32533

文献信息

• [EN] SILOLE-BASED MONOMERS AND POLYMERS FOR ORGANIC LIGHT-EMITTING DIODE DEVICES<br/>[FR] MONOMÈRES À BASE DE SILOLE ET POLYMÈRES POUR DISPOSITIFS À DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：GEORGIA TECH RES INST

  公开号：WO2009080796A1

  公开（公告）日：2009-07-02

  This invention relates generally to organic electroluminescent norbornene-silole monomers, poly (norbornene) homopolymers, and poly (norbornene) copolymers containing functionalized aryl and alkyl silole side chains having good host characteristics and solution processability, and to electron transporting and/or hole blocking layers, and light-emitting layers, organic electronic devices and compositions of matter which include these compounds.

  这项发明涉及一般有机电致发光的诺博烯硅烯单体，聚（诺博烯）均聚物，以及含有功能化芳基和烷基硅烯侧链的聚（诺博烯）共聚物，具有良好的宿主特性和溶液可加工性，以及电子传输和/或阻挡孔层，发光层，有机电子器件和包括这些化合物的物质组合。
• Silole-based monomers and polymers for organic light-emitting diode devices
  申请人：Hayek Ali

  公开号：US20100298590A1

  公开（公告）日：2010-11-25

  This invention relates generally to organic electroluminescent norbornene-silole monomer, poly(norbornene) homopolymer, and poly(norbornene) copolymer compounds, containing functionalized aryl and alkyl silole side chains having good host characteristics and solution processability, and to an electron transporting and/or hole blocking layers, and light-emitting layers, organic electronic devices and compositions of matter, which include these compounds.

  本发明涉及一般有机电致发光诺伯烯-硅氧烷单体、聚(诺伯烯)均聚物和聚(诺伯烯)共聚物化合物，包含具有良好主体特性和溶液可加工性的功能化芳基和烷基硅氧烷侧链，并涉及电子传输和/或阻挡孔层，发光层，有机电子设备和物质组成，其中包括这些化合物。
• Synthesis of Photo-Crosslinkable Hole-Transport Polymers with Tunable Oxidation Potentials And Their Use In Organic Light-Emitting Diodes
  作者：Bernard Kippelen、Seth Marder、Richard Hreha、Ya-Dong Zhang、Benoit Domercq、Nathalie Larribeau、Joshua Haddock

  DOI：10.1055/s-2002-32533

  日期：——

  A series of photo-crosslinkable arylamine-based hole-transport copolymers has been synthesized. The synthetic methodology employed allows for the redox potential of the polymer to be tuned by the incorporation of electron-donating or -withdrawing moieties. Upon exposure to ultraviolet radiation, the polymers become insoluble, as evidenced by UV/Vis absorption spectroscopy, a feature that is useful for the fabrication of multilayer organic light-emitting diodes (OLEDs) by solution processing techniques. OLEDs based on these hole-transport polymers have been fabricated and the performance of the devices has been evaluated. The photo-crosslinking process has been optimized so that it no longer adversely impacts device performance.

  已经合成了一系列可光交联的芳胺基孔导电共聚物。所采用的合成方法允许通过引入电子供体或吸电子基团来调节聚合物的红氧还原电位。在紫外线辐射照射下，聚合物变得不溶，用UV/Vis吸收光谱学证明了这一点，这一特性对通过溶液处理技术制造多层有机发光二极管（OLED）非常有用。基于这些孔导电聚合物的OLED已经被制造，并对器件性能进行了评估。光交联过程已得到优化，以至于不再对器件性能产生负面影响。