2,2,3,3-tetraphenyl-propionitrile | 1249-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,3,3-tetraphenyl-propionitrile
• 英文别名: 2,2,3,3-Tetraphenyl-propionitril；2,2,3,3-Tetraphenyl-propionsaeure-nitril；2,2,3,3-Tetraphenylpropionitril；2,2,3,3-Tetraphenylpropanenitrile
• CAS: 1249-27-0
• 化学式: C₂₇H₂₁N
• 分子量: 359.47
• InChiKey: BBEFTPCDCMLEGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,2,3,3-tetraphenyl-propionitrile 在 乙醚 、 氨 、 potassium amide 作用下， 生成 1,1,2,2-四苯乙烯
  参考文献：
  名称：

  Alkylations of Diphenylacetonitrile with Certain Halides by Potassium Amide in Liquid Ammonia. Dehydrocyanations of Polyphenyl Nitriles to Form Olefins¹

  摘要：

  DOI：

  10.1021/ja01582a025
• 作为产物：
  描述：

  二苯乙腈 、 二苯基溴甲烷 在 potassium amide 作用下， 生成 2,2,3,3-tetraphenyl-propionitrile
  参考文献：
  名称：

  Alkylations of Diphenylacetonitrile with Certain Halides by Potassium Amide in Liquid Ammonia. Dehydrocyanations of Polyphenyl Nitriles to Form Olefins¹

  摘要：

  DOI：

  10.1021/ja01582a025

文献信息

• MOLECULE RECOGNIZING MATERIAL AND PROCESS FOR PRODUCING THE MOLECULE RECOGNIZING MATERIAL
  申请人：Keio University

  公开号：EP2198952A1

  公开（公告）日：2010-06-23

  The present invention provides a new molecular recognition material, wherein the control of morphology is possible and the selectivity and capture efficiency of the template molecule are excellent, and to provide a simple production method thereof. The molecular recognition material of the present invention is a core-shell particle, which has a shell layer on the core particle surface, and the material is characterized in that template molecules are imprinted on the above-described shell layer. And a production method of the molecular recognition material of the present invention comprising: (a) introducing an iniferter group on the core particle surface, (b) adsorbing the template molecule, after process (a), onto the core particle surface, and (c) forming the shell layer, after process (b), on the core particle surface.

  本发明提供了一种新的分子识别材料，其形态可控，模板分子的选择性和捕获效率优异，并提供了一种简单的生产方法。本发明的分子识别材料是一种核壳粒子，其核壳粒子表面有一层壳层，该材料的特征在于模板分子印刻在上述壳层上。本发明分子识别材料的生产方法包括：(a)在芯颗粒表面引入增感基团；(b)将(a)工序后的模板分子吸附在芯颗粒表面；(c)在芯颗粒表面形成(b)工序后的壳层。
• Molecular recognition material and production method thereof
  申请人：Shiseido Co., Ltd.

  公开号：EP2500088A2

  公开（公告）日：2012-09-19

  The present invention provides a new molecular recognition material, wherein the control of morphology is possible and the selectivity and capture efficiency of the template molecule are excellent, and to provide a simple production method thereof. The molecular recognition material of the present invention is a core-shell particle, which has a shell layer on the core particle surface, and the material is characterized in that template molecules are imprinted on the above-described shell layer. And a production method of the molecular recognition material of the present invention comprising: (a) introducing an iniferter group on the core particle surface, (b) adsorbing the template molecule, after process (a), onto the core particle surface, and (c) forming the shell layer, after process (b), on the core particle surface.

  本发明提供了一种新的分子识别材料，其形态可控，模板分子的选择性和捕获效率优异，并提供了一种简单的生产方法。本发明的分子识别材料是一种核壳粒子，其核壳粒子表面有一层壳层，该材料的特征在于模板分子印刻在上述壳层上。本发明分子识别材料的生产方法包括：(a)在芯颗粒表面引入增感基团；(b)将(a)工序后的模板分子吸附在芯颗粒表面；(c)在芯颗粒表面形成(b)工序后的壳层。
• Molecule Recognizing Material And Process For Producing The Molecule Recognizing Material
  申请人：Ugajin Hiroshi

  公开号：US20110021347A1

  公开（公告）日：2011-01-27

  The present invention provides a new molecular recognition material, wherein the control of morphology is possible and the selectivity and capture efficiency of the template molecule are excellent, and to provide a simple production method thereof. The molecular recognition material of the present invention is a core-shell particle, which has a shell layer on the core particle surface, and the material is characterized in that template molecules are imprinted on the above-described shell layer. And a production method of the molecular recognition material of the present invention comprising: (a) introducing an iniferter group on the core particle surface, (b) adsorbing the template molecule, after process (a), onto the core particle surface, and (c) forming the shell layer, after process (b), on the core particle surface.
• Alkylations of Diphenylacetonitrile with Certain Halides by Potassium Amide in Liquid Ammonia. Dehydrocyanations of Polyphenyl Nitriles to Form Olefins¹
  作者：Charles R. Hauser、Wallace R. Brasen

  DOI：10.1021/ja01582a025

  日期：1956.1