trans-1,1,1-Trifluoro-2-(trifluoromethyl)-4-nonene | 141810-17-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: trans-1,1,1-Trifluoro-2-(trifluoromethyl)-4-nonene
• 英文别名: (E)-1,1,1-trifluoro-2-(trifluoromethyl)non-4-ene
• CAS: 141810-17-5
• 化学式: C₁₀H₁₄F₆
• 分子量: 248.212
• InChiKey: PNERSBJKVMVMGT-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-庚烯 在 偶氮二异丁腈 、 sodium amide 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 生成 trans-1,1,1-Trifluoro-2-(trifluoromethyl)-4-nonene
  参考文献：
  名称：

  Conversion of trifluoromethyl groups into nitrile functions during cyclization of hexafluoroiodoalkanes with sodium amide

  摘要：

  The cyclization of (CF3)2CHCH2CIR1CHR2R3 (1) (1a: R1 = Me, R2 = R3 = H; 1b: R1 = H, R2 = R3 = Me; 1c: R1 = R2 = H, R3 = Bu) with sodium amide occurs with conversion of trifluoromethyl groups to cyano functions or with their replacement by hydrogen atoms.

  DOI：

  10.1016/s0022-1139(00)82353-2

文献信息

• Solvent Compositions Comprising Unsaturated Fluorinated Hydrocarbons
  申请人：NAPPA MARIO JOSEPH

  公开号：US20110041878A1

  公开（公告）日：2011-02-24

  Disclosed is a method for removing residue from a surface comprising: contacting the surface with a composition comprising at least one unsaturated fluorinated hydrocarbon selected from the group consisting of compounds having the formula E- or Z—R 1 CH═CHR 2 , wherein R 1 and R 2 are, independently, C 1 to C 6 perfluoroalkyl groups, or C 1 to C 6 hydrofluoroalkyl groups, and recovering the surface from the composition.

  本发明公开了一种去除表面残留物的方法，包括：将表面与含有至少一种不饱和氟化碳化合物的组合物接触，所述不饱和氟化碳化合物的选择来自于具有E-或Z-R1CH═CHR2式的化合物，其中R1和R2分别独立地是C1到C6的全氟烷基，或C1到C6的氢氟烷基；并从组合物中回收表面。
• CASCADE REFRIGERATION SYSTEM WITH FLUOROOLEFIN REFRIGERANT
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2591296A2

  公开（公告）日：2013-05-15
• COMPOSITIONS COMPRISING FLUOROOLEFINS AND USES THEREOF
  申请人：Nappa Mario Joseph

  公开号：US20100132387A1

  公开（公告）日：2010-06-03

  The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
• IONIC LIQUID STABILIZER COMPOSITIONS
  申请人：Mouli Nandini C.

  公开号：US20110005723A1

  公开（公告）日：2011-01-13

  The present invention relates to compositions comprising at least one ionic liquid and CF 3 I; and mixtures thereof. Such compositions may be useful as low GWP working fluids. These compositions have a variety of utilities in working fluids, which include for example, blowing agents, solvents, aerosol propellants, fire extinguishants, sterilants or heat transfer mediums (such as heat transfer fluids and refrigerants for use in refrigeration systems, refrigerators, air conditioning systems, heat pumps, chillers, and the like).
• COMPOSITIONS COMPRISING IODOTRIFLUOROMETHANE AND STABILIZERS
  申请人：Leck Thomas J.

  公开号：US20110037017A1

  公开（公告）日：2011-02-17

  The present invention relates to compositions comprising iodotrifluoromethane and an effective amount of at least one stabilizer selected from the group consisting of hindered phenols, thiophosphates, butylated triphenylphosphorothionates, organo phosphates, phosphites, aryl alkyl ethers, terpenes, terpenoids, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, amines, nitromethane, alkylsilanes, benzophenone derivatives, aryl sulfides, divinyl terephalic acid, diphenyl terephalic acid, ionic liquids, and mixtures thereof. These stabilized iodotrifluoromethane compositions may be useful as working fluids in multiple applications including cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps.