phenyl-propiolic acid ; silver (I)-compound | 97649-31-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl-propiolic acid ; silver (I)-compound
• 英文别名: Phenyl-propiolsaeure; Silber(I)-Verbindung；Silver;3-phenylprop-2-ynoate
• CAS: 97649-31-5
• 化学式: Ag*C₉H₅O₂
• 分子量: 253.006
• InChiKey: MGGIUSCEEFSDGT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.21
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  phenyl-propiolic acid ; silver (I)-compound 生成 methylammonium carbonate 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Wieland; Fischer, Justus Liebigs Annalen der Chemie, 1926, vol. 446, p. 63

  摘要：

  DOI：
• 作为产物：
  描述：

  苯丙炔酸 生成 phenyl-propiolic acid ; silver (I)-compound
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0351860A2

  公开（公告）日：1990-01-24

  A color light-sensitive material comprising a support having provided thereon a light-sensitive silver halide, a binder, a reducible dye donating compound, and at least one reducing agent selected from the group consisting of a compound represented by formula (IA) and a compound represented by formula (IB): wherein R1, R2, R3, R4, R5, and R6, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acryl group, a substituted or unsubstituted sulfonyl group, a substituted or unsubstituted carbamoyl group, or a substituted or unsubstituted sulfamoyl group, provided that at least one of R1 and R3 and at least one of R4 and R6 represent a hydroxyl group; or any adjacent two of R1, R2, R3, R4, R5, and R6 are connected to each other to form a carbocyclic ring; X represents a divalent linking group; and t represents 0 or 1; wherein R" and R12, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acyl group, a substituted or unsubstituted sulfonyl group, a substituted or unsubstituted carbamoyl group, or a substituted or unsubstituted sulfamoyl group, or R" and R12 are taken together to form a carbocyclic ring; R13 represents an unsubstituted or alkyl-substituted alkylene group; R14, R15, R16, R17, and R18, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted amino group, a substituted or unsubstituted acyl group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted carbamoylamino group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted sulfamoylamino group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkoxysulfonyl group, or a substituted or unsubstituted aryloxysulfonyl group; R14, R15, and R16 each may further represent a hydroxyl group; or any adjacent two of R14, R15, R16, R17, and R18 are connected to each other to form a carbocyclic or heterocyclic ring; X represents -CO- or -S02-; m and n each represents 0 or 1; and the total number of carbon atoms in R", R12, R'3, R14, R15, R'6, R17, and R'8 is 8 or more.

  一种彩色光敏材料，包括在其上提供有光敏卤化银的支持物、粘合剂、可还原染料捐赠化合物和至少一种选自由式(IA)代表的化合物和由式(IB)代表的化合物组成的组的还原剂： 其中 R1、R2、R3、R4、R5 和 R6 可以相同或不同，各自代表氢原子、卤素原子、羟基、取代或未取代的烷基、取代或未取代的芳基、取代或未取代的酰氨基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的丙烯基、取代或未取代的磺酰基、取代或未取代的氨基甲酰基或取代或未取代的氨基磺酰基，条件是 R1 和 R3 中的至少一个以及 R4 和 R6 中的至少一个代表羟基；或 R1、R2、R3、R4、R5 和 R6 中任意相邻的两个相互连接形成碳环；X 代表二价连接基团；t 代表 0 或 1； 其中 R "和 R12 可以相同或不同，各自代表氢原子、卤素原子、取代或未取代的烷基、取代或未取代的芳基、取代或未取代的酰氨基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的酰基、取代或未取代的磺酰基、取代或未取代的氨基甲酰基或取代或未取代的氨基磺酰基，或 R "和 R12 共同形成碳环；R13 代表未取代或烷基取代的亚烷基；R14、R15、R16、R17 和 R18 可以相同或不同，各自代表氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的酰氨基、取代或未取代的磺酰胺基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的氨基、取代或未取代的酰基、一个取代或未取代的酰氧基， 一个取代或未取代的氨基甲酰基， 一个取代或未取代的氨基甲酰胺基， 一个取代或未取代的氨基磺酰基， 一个取代或未取代的氨基磺酰胺基、取代或未取代的烷氧羰基、取代或未取代的芳氧羰基、取代或未取代的杂环基、取代或未取代的烷氧基磺酰基或取代或未取代的芳氧基磺酰基；R14、R15 和 R16 可各自进一步代表羟基；或 R14、R15、R16、R17 和 R18 中任意相邻的两个相互连接以形成碳环或杂环；X 代表 -CO- 或 -S02-；m 和 n 各自代表 0 或 1；且 R"、R12、R'3、R14、R15、R'6、R17 和 R'8 中的碳原子总数为 8 或更多。
• Silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0394943A2

  公开（公告）日：1990-10-31

  A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photographic material contains an image forming compound represented by the following general formula (I): (Dye-X)q-Y      (I) wherein Dye represents a cyan dye group represented by the general formula (II) described below or a precursor thereof; X represents a chemical bond or a linking group; Y represents a group having a property of releasing Dye in correspondence or counter-corres­pondence to development of a light-sensitive silver salt having a latent image distributed imagewise and making a difference in diffusibility between the dye thus-­released and the compound represented by (Dye-X)q-Y; Dye and X are connected with each other by C or E in the general formula (II); and q represents an integer of 1 or 2, and when q is 2, the two groups (Dye-X) may be the same or different: wherein A represents a halogen atom, -OR¹ or -SR¹ (wherein R¹ represents an alkyl group, an aryl group or a heterocyclic group); B represents an electron withdrawing group having a Hammett's σp value of not less than 0.3; C represents a chemical bond, a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, a halogen atom, -OR⁴, -CONR⁴R⁵, -SO₂NR⁴R⁵, -N(R³)-COR₄ or -N(R³) -SO₂R₄ (wherein R³, R⁴ and R⁵ each represents a hydrogen atom or a group selected from those defined for R¹, or R⁴ and R⁵ may combine with each other to form a 5-­membered or 6-membered ring); E represents a chemical bond, a hydrogen atom, an alkyl group, a halogen atom, -OR⁴, -CONR⁴R⁵, -SO₂NR⁴R⁵, -N(R⁵)-COR⁴ or -N(R⁵)-SO₂R⁴ (wherein R⁴ and R⁵ have the same meaning as defined above); and G represents a hydroxy group or a salt thereof, or a group selected from those represented by the formula (T), (U) or (V): wherein R²¹ and R²², which may be the same or different, each represents an alkyl group, a cycloalkyl group, an alkenyl group, an aralkyl group, an aryl group, a heterocyclic group, an alkylthio group, an arylthio group, an alkoxy group, an aryloxy group or an amino group, or R²¹ and R²² may combine with each other to form a 5-membered or 6-membered ring.

  一种卤化银彩色感光材料，包括一个支撑体，支撑体上至少有一层卤化银乳剂层，其中卤化银彩色感光材料含有由下式通式(I)表示的图像形成化合物： (Dye-X)q-Y (I) 其中，染料代表由下述通式（II）表示的青色染料基团或其前体；X 代表化学键或连接基团；Y 代表一种基团，该基团具有在显影时相应或反相应地释放染料的特性，该银盐具有按图像方向分布的潜像，并使由此释放的染料与（Dye-X）q-Y 所代表的化合物之间的扩散性不同；染料和 X 在通式(II)中通过 C 或 E 相互连接；q 代表 1 或 2 的整数，当 q 为 2 时，两个基团 (Dye-X) 可以相同或不同： 其中 A 代表卤素原子、-OR¹ 或 -SR¹（其中 R¹ 代表烷基、芳基或杂环基）； B 代表具有不小于 0.3;C 代表化学键、氢原子、烷基、环烷基、芳基、卤素原子、-OR⁴、-CONR⁴R⁵、-SO₂NR⁴R⁵、-N(R³)-COR₄或 -N(R³)-SO₂R₄（其中 R³、和 R⁵ 各代表一个氢原子或一个选自 R¹ 所定义的基团，或 R⁴ 和 R⁵ 可相互结合形成一个 5 元环或 6 元环）；E 代表化学键、氢原子、烷基、卤素原子、-OR⁴、-CONR⁴R⁵、-SO₂NR⁴R⁵、-N(R⁵)-COR⁴ 或 -N(R⁵)-SO₂R⁴（其中 R⁴ 和 R⁵ 的含义与上述定义相同）；G 代表羟基或其盐，或选自式 (T)、(U) 或 (V) 所代表的基团： 其中 R²¹ 和 R²²（可以相同或不同）各自代表烷基、环烷基、烯基、芳烷基、芳基、杂环基、烷硫基、芳硫基、烷氧基、芳氧基或氨基，或 R²¹ 和 R²² 可相互结合形成 5 元环或 6 元环。
• Light-sensitive element for the diffusion transfer process
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0378174A2

  公开（公告）日：1990-07-18

  A light-sensitive element for the diffusion transfer process which comprises a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a yellow dye providing compound represented by the following general formula (I): wherein CAR represents a carrier moiety which is capable of releasing a diffusible dye from the compound in correspondence or counter-correspondence to development under alkaline conditions; Link represents a group connecting CAR with a diffusible dye; m represents 0 or 1; the dotted lines mean that at least one of the dotted lines is a bond; R¹ represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group or a carbamoyl group; R² represents an alkyl group or an aryl group; and R³ represents an aryl group excepting an aryl group having the Hammett's σp value less than 0.01. The yellow dye providing compound has a dye moiety whose transferability is high and whose hue is excellent and provides a stable yellow dye image which does not substantially change hue over a wide pH range

  一种用于扩散转移工艺的光敏元件，它包括一个支撑体，支撑体上有一个光敏卤化银乳剂层，该乳剂层上有一个由下列通式(I)表示的提供黄色染料的化合物： 其中 CAR 代表载体分子，它能在碱性条件下与显影相应或相反地从化合物中释放出扩散染料；Link 代表连接 CAR 与扩散染料的基团；m 代表 0 或 1；虚线表示虚线中至少有一条是键；R¹ 代表氢原子、烷基、芳基、烷氧基、芳氧基、烷氧羰基、芳氧羰基或氨基甲酰基； R² 代表烷基或芳基；以及 R³ 代表芳基，但 Hammett's σp 值小于 0 的芳基除外。01. 提供黄色染料的化合物具有染料分子，其转移性高，色调优异，并提供稳定的黄色染料图像，在较宽的 pH 值范围内不会发生实质性色调变化。
• Dye diffusion transfer type heat developable color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0479167A1

  公开（公告）日：1992-04-08

  5n7 A dye diffusion transfer type heat developable color light-sensitive material is described including a support having thereon at least three light-sensitive layers containing, in combination, silver halide emulsions which are sensitive in different spectral regions from one another and dye providing compounds capable of releasing or forming diffusible dyes having different hues from one another, wherein the material has an exposure side which is subjected to incident light from a light source, wherein at least two layers of the at least three light-sensitive layers include a first light-sensitive layer containing an emulsion spectrally sensitized to a part of infrared rays and a second light-sensitive layer which is positioned on the exposure side nearer to the light source than is the first light-sensitive layer and contains an emulsion spectrally sensitized to a part of infrared rays having a wavelength shorter than that of the infrared rays applied to the emulsion of the first light-sensitive layer, and the first light-sensitive layer contains a non-transferring filter dye which absorbs at least a part of light to which the second light-sensitive layer is exposed, and wherein the light-sensitive layer or layers other than the first and second light-sensitive layers can be arranged in any order.

  5n7 描述了一种染料扩散转移型热显影彩色光敏材料，该材料包括一个支撑体，支撑体上至少有三层光敏层，这三层光敏层分别含有在不同光谱区域彼此敏感的卤化银乳剂和能够释放或形成彼此具有不同色调的可扩散染料的染料提供化合物，其中该材料有一个曝光面，该曝光面受到来自光源的入射光、其中至少三层感光层中的至少两层包括第一感光层和第二感光层，第一感光层包含对部分红外线分光感光的乳剂，第二感光层位于曝光侧，比第一感光层更靠近光源，包含对部分红外线分光感光的乳剂，其波长短于施加到第一感光层乳剂上的红外线波长、第一感光层含有非转移滤色染料，它至少吸收第二感光层所照射到的部分光线，其中第一和第二感光层以外的感光层可以任意顺序排列。
• Color-developing agent, silver halide photographic light-sensitive material and image-forming method
  申请人：——

  公开号：US20020102489A1

  公开（公告）日：2002-08-01

  There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.

  本发明公开了一种 1,2,4-噻二唑-5-基肼型新型显色剂。本发明还公开了一种卤化银感光材料，使用该显色剂可通过显影形成足够的颜色，并形成图像质量和图像存储性极佳的图像。此外，还公开了一种使用该感光材料的图像形成方法。