barium DL-alanyldithiocarbamate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: barium DL-alanyldithiocarbamate
• 英文别名: N-dithiocarboxy-DL-alanine ; barium salt；N-Dithiocarboxy-DL-alanin; Barium-Salz；Barium(2+);2-(sulfidocarbothioylamino)propanoate；barium(2+);2-(sulfidocarbothioylamino)propanoate
• 化学式: Ba*C₄H₅NO₂S₂
• 分子量: 300.551
• InChiKey: SZYPXDCEXUVFKU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.83
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  85.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ammonium tetrathiomolybdate 、 barium DL-alanyldithiocarbamate 以 水 为溶剂， 生成 barium di-μ-sulphidobis{(DL-alanyldithiocarbamato)sulphidomolybate(V)}
  参考文献：
  名称：

  Sulphidomolybdenum(V) complexes with amino acid dithiocarbamates

  摘要：

  The interaction of ammonium tetrathiomolybdate with the barium salts of the dithiocarbamates (dtc) of glycine, DL-alanine and DL-2-aminobutyric acid yielded Ba[Mo2S4(dtc)2]. The molar conductivities (approximately 50 OMEGA(-1) cm-1) in DMSO indicated the ionic nature of the complexes. The subnormal magnetic moment (0.4 B.M.), electronic and IR spectral data and CVM peak potentials (-0.95 and -1.25 V vs SCE) suggested a dimeric species with a [Mo2S4]2+ core. The IR spectral data suggested the bidentate coordination of the dithiocarbamate groups and the absence of coordination by the carboxylate group. Thermal properties of the complexes are discussed.

  DOI：

  10.1016/s0277-5387(00)83370-7

文献信息

• Lanthanum(III) and praseodymium(III) derivatives with dithiocarbamates derived from α-amino acids
  作者：Anita Rai、Soumitra K. Sengupta、Om P. Pandey

  DOI：10.1016/j.saa.2005.06.051

  日期：2006.6

  Lanthanum(III) and praseodymium(III) complexes with dithiocarbamates have been synthesized by the reactions of lanthanum(III) and praseodymium(III) chloride with barium dithiocarbamate and complexes of type [LnCl(L)H2O]n have been obtained (where Ln=La(III) or Pr(III); L=barium salt of dithiocarbamate derived from glycine, L-leucine, L-valine, DL-alanine). The complexes have been characterized by elemental

  通过镧（III）和氯化ase（III）与二硫代氨基甲酸钡的反应合成了镧（III）和ase（III）配合物，得到了[LnCl（L）H2O] n类型的配合物（其中Ln ＝ La（III）或Pr（III）； L ＝衍生自甘氨酸，L-亮氨酸，L-缬氨酸，DL-丙氨酸的二硫代氨基甲酸酯的钡盐）。通过元素分析，摩尔电导，电子吸收和荧光，红外，远红外，1H NMR光谱研究对复合物进行了表征。从热重分析可以推断出配位水分子的存在，这表明一个水分子在150-170摄氏度时会损失。对于不同的跃迁，已经获得了振荡器强度，Judd-Ofelt强度参数，受激发射截面等。 Pr3 +。
• Sulphidomolybdenum(V) complexes with amino acid dithiocarbamates
  作者：Vasanthi Lakshmanan、M.R. Udupa、K.S. Nagaraja

  DOI：10.1016/s0277-5387(00)83370-7

  日期：1992.1

  The interaction of ammonium tetrathiomolybdate with the barium salts of the dithiocarbamates (dtc) of glycine, DL-alanine and DL-2-aminobutyric acid yielded Ba[Mo2S4(dtc)2]. The molar conductivities (approximately 50 OMEGA(-1) cm-1) in DMSO indicated the ionic nature of the complexes. The subnormal magnetic moment (0.4 B.M.), electronic and IR spectral data and CVM peak potentials (-0.95 and -1.25 V vs SCE) suggested a dimeric species with a [Mo2S4]2+ core. The IR spectral data suggested the bidentate coordination of the dithiocarbamate groups and the absence of coordination by the carboxylate group. Thermal properties of the complexes are discussed.