N-di(propan-2-yl)phosphanylaniline | 70589-60-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-di(propan-2-yl)phosphanylaniline
• CAS: 70589-60-5
• 化学式: C₁₂H₂₀NP
• 分子量: 209.271
• InChiKey: OYGZJVGZXQEYQS-UHFFFAOYSA-N

物化性质

• 沸点：
  95-96 °C(Press: 1 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-di(propan-2-yl)phosphanylaniline 在 碘 、 三乙胺 作用下， 生成 Iodo-phenylimino-di(propan-2-yl)-lambda5-phosphane
  参考文献：
  名称：

  Foss, V. L.; Veits, Yu. A.; Chernykh, T. E., Journal of general chemistry of the USSR, 1984, vol. 54, # 12, p. 2386 - 2399

  摘要：

  DOI：
• 作为产物：
  描述：

  [tert-butyl(propan-2-yl)phosphanyl]-phenylimino-di(propan-2-yl)-λ5-phosphane 生成 N-di(propan-2-yl)phosphanylaniline
  参考文献：
  名称：

  VEJTS, YU. A.;NEGANOVA, E. G.;BORISENKO, A. A.;FOSS, V. L.;LUTSENKO, I. F+, ZH. OBSHCH. XIMII, 59,(1989) N, S. 1733-1740

  摘要：

  DOI：

文献信息

• C–H vs. N–H Bond Activation in Aminophosphane Ligands: Reaction of [Cp*Ru(MeCN) ₂ (PR ¹ ₂ NHR ² )] ⁺ (R ¹ = Ph, <i>i</i> Pr; R ² = Ph, C ₆ F ₅ ) with Alkynes
  作者：Manuel Jiménez‐Tenorio、M. Carmen Puerta、Pedro Valerga

  DOI：10.1002/ejic.200500034

  日期：2005.7

  amidobutadiene complexes of the type [Cp*Ruη 4 -C 4 H 3 (R) 2 -PR 1 2 NR 2 -κ 1 N]] + or [Cp*Ruη 4 -C 4 H 3 (CH 2 XCH 2 )PR 1 2 NR 2 -κ 1 N)] + . The complexes [Cp*Ruη 4 -C 4 H 3 (CH 2 OCH 2 )-PPh 2 NPh-κ 1 N}][PF 6 ] (la) and [Cp*Ruη 4 -C 4 H 3 (CH 2 -OCH 2 )PiPr 2 NC 6 F 5 -κ 1 N}][PF 6 ] (2a) have been structurally characterized by X-ray crystallography. In other cases, for example the reaction of 3 with

  配合物的反应 [Cp*Ru(MeCN) 2 (PR 1 2 NHR 2 )] + (R 1 = R 2 = Ph 1; R 1 = iPr, R 2 = C 6 F 5 2; R 1 = iPr , R 2 = Ph 3) 与 1-炔烃 HC≡CR (R = H, nBu, SiMe 3 ) 或二炔烃 HC≡CCH 2 XCH 2 C≡CH (X = O, CH 2 , CH 2 CH 2 ) 产生不同的产物取决于氨基膦配体的性质。在某些情况下，发生涉及磷烷迁移和 NH 活化的炔烃偶联，产生 [Cp*Ruη 4 -C 4 H 3 (R) 2 -PR 1 2 NR 2 -κ 1 N]] 类型的酰胺基丁二烯配合物+ 或 [Cp*Ruη 4 -C 4 H 3 (CH 2 XCH 2 )PR 1 2 NR 2 -κ 1 N)] + 。配合物[Cp*Ruη 4 -C 4 H 3 (CH 2 OCH
• Hydrophosphination of vinyl-boranes with phosphinoamines
  作者：Chunfang Jiang、Douglas W. Stephan

  DOI：10.1039/c2dt32677a

  日期：——

  Phosphinoamine ligands PhN(H)PR2 (R = iPr 1, tBu 2) react with R1CHCR2B(C6F5)2 (R1 = Ph, p-FC6H4, nPr, Et, R2 = H, Ph, Et, C6F5) to effect uncatalyzed hydrophosphination of the olefinic bond, affording the C2BNP five-membered cyclization compounds 3–14. All the compounds are fully characterized and compounds 4, 7, 8 and 9 are studied by X-ray diffraction analysis.

  膦胺配体 PhN(H)PR2 (R = iPr 1, tBu 2) 与 R1CHCR2B(C6F5)2 (R1 = Ph, p-FC6H4, nPr, Et, R2 = H, Ph, Et, C6F5) 反应，实现非催化氢膦化烯键，得到 C2BNP 五元环化化合物 3-14。所有化合物均经过充分表征，并通过 X 射线衍射分析研究了化合物 4、7、8 和 9。
• Foss, V. L.; Chernykh, T. E.; Staroverova, I. N., Journal of general chemistry of the USSR, 1983, vol. 53, # 10, p. 1969 - 1976
  作者：Foss, V. L.、Chernykh, T. E.、Staroverova, I. N.、Veits, Yu. A.、Lutsenko, I. F.

  DOI：——

  日期：——
• Brueck, A.; Kuchen, W.; Peters, W., Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 107, # 1-4, p. 129 - 134
  作者：Brueck, A.、Kuchen, W.、Peters, W.

  DOI：——

  日期：——
• Heterobimetallic Ti/Co Complexes That Promote Catalytic N–N Bond Cleavage
  作者：Bing Wu、Kathryn M. Gramigna、Mark W. Bezpalko、Bruce M. Foxman、Christine M. Thomas

  DOI：10.1021/acs.inorgchem.5b01962

  日期：2015.11.16

  Treatment of the tris(phosphinoamide) titanium precursor ClTi(XylNP(i)Pr(2))(3) (1) with CoI2 leads to the heterobimetallic complex (eta(2)-(i)Pr(2)PNXyl)Ti(XylNP(i)Pr(2))(2)(mu-Cl)CoI (2). One-electron reduction of 2 affords (eta(2)-(i)Pr(2)PNXyl)-Ti(XylNP(i)Pr(2))(2)CoI (3), which can be reduced by another electron under dinitrogen to generate the reduced diamagnetic complex (THF)Ti(XylNP(i)Pr(2))(3)CoN2 (4). The removal of the dinitrogen ligand from 4 under vacuum affords (THF)Ti-(XylNP(i)Pr(2))(3)Co (5), which features a TiCo triple bond. Treatment of 4 with hydrazine or methyl hydrazine results in NN bond cleavage and affords the new diamagnetic complexes (L)Ti(XylNP(i)Pr(2))(3)CoN2 (L = NH3 (6), MeNH2 (7)). Complexes 4, 5, and 6 have been shown to catalyze the disproportionation of hydrazine into ammonia and dinitrogen gas through a mechanism involving a diazene intermediate.