1-biphenyl-4-yloxy-2-vinyloxy-ethane | 102534-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-biphenyl-4-yloxy-2-vinyloxy-ethane
• 英文别名: 4-(2-Vinyloxy-aethoxy)-biphenyl；1-Biphenyl-4-yloxy-2-vinyloxy-aethan；4-[2-(ethenyloxy)ethoxy]-1,1'-biphenyl；1-(2-Ethenoxyethoxy)-4-phenylbenzene
• CAS: 102534-51-0
• 化学式: C₁₆H₁₆O₂
• 分子量: 240.302
• InChiKey: HDRRUNJJFKSXKE-UHFFFAOYSA-N

物化性质

• 熔点：
  73-76 °C
• 沸点：
  373.6±35.0 °C(Predicted)
• 密度：
  1.046±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对羟基联苯 、 2-氯乙基乙烯基醚 在 sodium hydroxide 作用下， 生成 1-biphenyl-4-yloxy-2-vinyloxy-ethane
  参考文献：
  名称：

  US2244308

  摘要：

  公开号：

文献信息

• RECORDING MATERIAL PRODUCED USING NON-PHENOL COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：US20150284321A1

  公开（公告）日：2015-10-08

  An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol compound that is a safe compound in no danger of corresponding to an endocrine disruptor and is good in color developing performance. The non-phenol compound used in the present invention is at least one selected from the group consisting of compounds represented by the following formulas (I) to (III).

  本发明的目的是提供一种使用非酚类化合物作为显色剂的记录材料或记录纸，该非酚类化合物是一种安全化合物，不会对应到内分泌干扰物，并且在显色性能方面表现良好。本发明中使用的非酚类化合物至少选自以下化合物所代表的化合物组，其化学式为(I)至(III)。
• Thermosensitive recording material and color developer compound therefor
  申请人：——

  公开号：US20040071187A1

  公开（公告）日：2004-04-15

  A thermosensitive recording material has a support and a thermosensitive coloring layer formed thereon containing a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer including at least one compound (A) having in a molecule thereof at least two aromatic ring moieties with specific structures, selected from the group consisting of an aromatic ring moiety having at least one carboxyl group and electron-attracting functional group, an aromatic ring moiety having at least one carboxyl group and electron-donating functional group, and an aromatic ring moiety having at least one carboxyl group, free of the electron-attracting and electron-donating functional groups. An aromatic carboxylic acid compound serving as the above-mentioned compound (A) and the producing method thereof are also disclosed.

  一种热敏感记录材料具有支撑体和在其上形成的热敏感着色层，其中该着色层含有一种白色染料和一种色素显色剂，能够在施加热量时诱导白色染料发生显色反应，其中色素显色剂包括至少一种化合物（A），其分子中至少含有两个具有特定结构的芳香环基团，所述芳香环基团选自具有至少一个羧基和电子吸引基团的芳香环基团、具有至少一个羧基和电子给予基团的芳香环基团以及不含电子吸引和电子给予功能基团的芳香环基团。还公开了作为上述化合物（A）的芳香羧酸化合物及其生产方法。
• Intramolecular Triplet Energy Transfer in Flexible Molecules:  Electronic, Dynamic, and Structural Aspects
  作者：Peter J. Wagner、Petr Klán

  DOI：10.1021/ja990224l

  日期：1999.10.1

  Exothermic intramolecular triplet energy transfer (TET) rate constants in various flexible bichromophoric systems D-(CH2)n-O-A (D = benzoyl, 4-methylbenzoyl; A = 2-naphthyl, 4-, 3-, 2-biphenyl; n = 3−14) have been determined from steady-state quenching and quantum yield measurements. The magnitude of the rate constants in molecules where n = 3 is comparable to those in molecules with a rigid spacer between

  各种柔性双发色系统中的放热分子内三线态能量转移 (TET) 速率常数 D-(CH2)nOA（D = 苯甲酰基、4-甲基苯甲酰基；A = 2-萘基、4-、3-、2-联苯；n = 3− 14) 已从稳态猝灭和量子产率测量中确定。n = 3 的分子中的速率常数的大小与在生色团之间具有刚性间隔物的分子中的速率常数的大小相当，因此推测直通键机制仍然很重要。随着连接的多亚甲基链变长，TET 速率常数逐渐下降，表明空间相互作用竞争，并且显然是当 n ≥ 5 时负责转移的唯一机制。长分子（n = 11-14）的速率常数仍然非常高（~108 s-1），比四原子系链的速率常数仅低 1 个数量级。这种效应的解释是基于快速构象平衡，始终保持足够比例的分子卷曲，从而使两个色...
• Thermosensitive recording material using phthalic acid derivatives
  申请人：Ricoh Company, Ltd

  公开号：EP0612628A1

  公开（公告）日：1994-08-31

  A thermosensitive recording material composed of a support, and a thermosensitive recording layer formed on the support, containing a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, the color developer including at least one compound selected from the group consisting of the compounds of formulas (I) to (IV):

  一种热敏记录材料，由支撑体和在支撑体上形成的热敏记录层组成，热敏记录层含有一种白兰地染料和一种显色剂，该显色剂能在加热时诱导白兰地染料形成颜色，该显色剂包括至少一种从式(I)至(IV)化合物组成的组中选出的化合物：
• Aqueous resin dispersion liquid for heat-sensitive recording material and heat-sensitive recording material using the same
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0614767A1

  公开（公告）日：1994-09-14

  An aqueous resin dispersion for a heat-sensitive recording material is disclosed. The aqueous resin dispersion is obtained by the use of polyvinyl alcohol as an emulsifier and the use of two steps of polymerization. In the first step of polymerization, a polymeric monomer composition A is polymerized, composition A containing polymeric multi-functional monomers which constitute 15% by weight or more of the total weight of the polymeric monomers used for the first step. And, in the second step, a polymeric monomer composition B is polymerized, The invention also discloses a heat-sensitive recording material using such an aqueous resin dispersion as a color-developing layer or a protective coating.

  本发明公开了一种用于热敏记录材料的水性树脂分散体。这种水性树脂分散液是通过使用聚乙烯醇作为乳化剂和两个聚合步骤获得的。在第一步聚合中，聚合单体组合物 A，组合物 A 中含有聚合多功能单体，其重量占第一步所用聚合单体总重量的 15%或以上。本发明还公开了一种热敏记录材料，使用这种水性树脂分散体作为显色层或保护层。