N,N,N',N'-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,4)-dianthracenacyclooctaphane-3,7-diamine | 1007601-23-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N,N,N',N'-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,4)-dianthracenacyclooctaphane-3,7-diamine
• 英文别名: 3-N,3-N,18-N,18-N-tetramethyl-2,4,17,19-tetraoxa-3,18-diphosphaheptacyclo[18.10.2.25,16.06,15.08,13.021,30.023,28]tetratriaconta-1(31),5(34),6,8,10,12,14,16(33),20(32),21,23,25,27,29-tetradecaene-3,18-diamine
• CAS: 1007601-23-1
• 化学式: C₃₂H₂₈N₂O₄P₂
• 分子量: 566.533
• InChiKey: SIQRTHMLSKDPJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  40
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N,N',N'-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,4)-dianthracenacyclooctaphane-3,7-diamine 在 urea-hydrogen peroxide 作用下， 以 吡啶 为溶剂， 反应 24.0h， 以53 g的产率得到3,7-bis(dimethylamino)-2,4,6,8-tetraoxa-3λ⁵,7λ⁵-diphospha-1,5(1,4)-dianthracenacyclooctaphane-3,7-dione
  参考文献：
  名称：

  Phosphorylation and cyclophosphorylation of 1,4-diacetoxyanthracene and dianthrone

  摘要：

  Phosphorylation and cyclophosphorylation of 1,4-dihydroxyanthracene and dianthrone by hexaalkylphosphorous triamides in pyridine was effected for the first time. The phosphorylation rate is found depending on the type of the alkyl fragment in the amido group of the phosphorylating agent. Cyclic phosphoramidites derived from anthracene were prepared both by molecular assembling and direct cyclophosphorylation. Thio and oxo derivatives of these cyclic compounds were obtained. Dianthrone derivatives undergo intramolecular cycloaddition at only one anthracene fragment to form an interesting bulky structure containing the phospholane ring.

  DOI：

  10.1134/s1070363207020090
• 作为产物：
  描述：

  1,4-二乙酰氧基蒽 、 三(二甲胺基)膦 以 吡啶 为溶剂， 反应 10.0h， 以58%的产率得到N,N,N',N'-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,4)-dianthracenacyclooctaphane-3,7-diamine
  参考文献：
  名称：

  Phosphorylation and cyclophosphorylation of 1,4-diacetoxyanthracene and dianthrone

  摘要：

  Phosphorylation and cyclophosphorylation of 1,4-dihydroxyanthracene and dianthrone by hexaalkylphosphorous triamides in pyridine was effected for the first time. The phosphorylation rate is found depending on the type of the alkyl fragment in the amido group of the phosphorylating agent. Cyclic phosphoramidites derived from anthracene were prepared both by molecular assembling and direct cyclophosphorylation. Thio and oxo derivatives of these cyclic compounds were obtained. Dianthrone derivatives undergo intramolecular cycloaddition at only one anthracene fragment to form an interesting bulky structure containing the phospholane ring.

  DOI：

  10.1134/s1070363207020090

文献信息

• Phosphorylation and cyclophosphorylation of 1,4-diacetoxyanthracene and dianthrone
  作者：E. N. Rasadkina、A. V. Petrov、E. E. Nifant’ev

  DOI：10.1134/s1070363207020090

  日期：2007.2

  Phosphorylation and cyclophosphorylation of 1,4-dihydroxyanthracene and dianthrone by hexaalkylphosphorous triamides in pyridine was effected for the first time. The phosphorylation rate is found depending on the type of the alkyl fragment in the amido group of the phosphorylating agent. Cyclic phosphoramidites derived from anthracene were prepared both by molecular assembling and direct cyclophosphorylation. Thio and oxo derivatives of these cyclic compounds were obtained. Dianthrone derivatives undergo intramolecular cycloaddition at only one anthracene fragment to form an interesting bulky structure containing the phospholane ring.