1-[(Diphenylphosphorylamino)oxy-(4-methylphenyl)phosphoryl]-4-methylbenzene | 193346-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-[(Diphenylphosphorylamino)oxy-(4-methylphenyl)phosphoryl]-4-methylbenzene
• 英文别名: 1-[(diphenylphosphorylamino)oxy-(4-methylphenyl)phosphoryl]-4-methylbenzene
• CAS: 193346-72-4
• 化学式: C₂₆H₂₅NO₃P₂
• 分子量: 461.437
• InChiKey: LJKSNHMRIQCQLT-UHFFFAOYSA-N

物化性质

• 沸点：
  586.0±53.0 °C(Predicted)
• 密度：
  1.26±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[(Diphenylphosphorylamino)oxy-(4-methylphenyl)phosphoryl]-4-methylbenzene 在 potassium tert-butylate 、 水 作用下， 以 氘代苯 、 叔丁醇 为溶剂， 生成 [甲氧基(苯基)磷酰基]苯
  参考文献：
  名称：

  Transposition of the phosphinoyl groups in the base-induced rearrangements of N,O-Bis(diarylphosphinoyl)hydroxylamines

  摘要：

  Because the N- and O-phosphinoyl groups can change places prior to rearrangement, Ph2P(O)NHOP(O)Ar-2 and Ar2P(O)NHOP(O)Ph-2 (Ar = p-tolyl) both give mixtures of two phosphonamidic-phosphinic anhydrides, Ph(PhNH)P(O)OP(O)Ar-2, and Ar(ArNH)P(O)OP(O)Ph-2, on treatment with KOBut in (BuOH)-O-t. The transposition of the phosphinoyl groups may involve phosphorane intermediates (7 and 9) having the P atom contained within a three-membered ring. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00915-5
• 作为产物：
  描述：

  1-[(Diphenylphosphoryloxyamino)-(4-methylphenyl)phosphoryl]-4-methylbenzene 在 potassium tert-butylate 作用下， 以 氘代苯 、 叔丁醇 为溶剂， 生成 1-[(Diphenylphosphorylamino)oxy-(4-methylphenyl)phosphoryl]-4-methylbenzene
  参考文献：
  名称：

  Transposition of the phosphinoyl groups in the base-induced rearrangements of N,O-Bis(diarylphosphinoyl)hydroxylamines

  摘要：

  Because the N- and O-phosphinoyl groups can change places prior to rearrangement, Ph2P(O)NHOP(O)Ar-2 and Ar2P(O)NHOP(O)Ph-2 (Ar = p-tolyl) both give mixtures of two phosphonamidic-phosphinic anhydrides, Ph(PhNH)P(O)OP(O)Ar-2, and Ar(ArNH)P(O)OP(O)Ph-2, on treatment with KOBut in (BuOH)-O-t. The transposition of the phosphinoyl groups may involve phosphorane intermediates (7 and 9) having the P atom contained within a three-membered ring. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00915-5

文献信息

• Transposition of the phosphinoyl groups in the base-induced rearrangements of N,O-Bis(diarylphosphinoyl)hydroxylamines
  作者：Martin J.P. Harger

  DOI：10.1016/s0040-4039(97)00915-5

  日期：1997.6

  Because the N- and O-phosphinoyl groups can change places prior to rearrangement, Ph2P(O)NHOP(O)Ar-2 and Ar2P(O)NHOP(O)Ph-2 (Ar = p-tolyl) both give mixtures of two phosphonamidic-phosphinic anhydrides, Ph(PhNH)P(O)OP(O)Ar-2, and Ar(ArNH)P(O)OP(O)Ph-2, on treatment with KOBut in (BuOH)-O-t. The transposition of the phosphinoyl groups may involve phosphorane intermediates (7 and 9) having the P atom contained within a three-membered ring. (C) 1997 Elsevier Science Ltd.