4-(tert-pentyl)-N-phenylaniline | 4494-65-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(tert-pentyl)-N-phenylaniline
• 英文别名: 4-(2-methylbutan-2-yl)-N-phenylaniline
• CAS: 4494-65-9
• 化学式: C₁₇H₂₁N
• 分子量: 239.36
• InChiKey: YAILAPMSVGHHGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-叔丁基环己酮 、 硝基苯 在 palladium diacetate 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 24.0h， 以88%的产率得到4-(tert-pentyl)-N-phenylaniline
  参考文献：
  名称：

  硝基芳烃和环己酮形成钯催化的一锅二芳基胺

  摘要：

  描述了使用借来的氢由硝基芳烃和环己酮衍生物形成的第一钯催化的二芳基胺。以良好至优异的收率选择性地获得了各种二芳基胺。该反应可耐受多种功能。硝基还原，环己酮脱氢以及亚胺的形成和还原是在没有外部还原剂和氧化剂的情况下串联实现的。

  DOI：

  10.1021/ol3002442

文献信息

• Pd-Catalyzed Synthesis of Aryl Amines via Oxidative Aromatization of Cyclic Ketones and Amines with Molecular Oxygen
  作者：Simon A. Girard、Xiong Hu、Thomas Knauber、Feng Zhou、Marc-Olivier Simon、Guo-Jun Deng、Chao-Jun Li

  DOI：10.1021/ol3027279

  日期：2012.11.2

  Pd-catalyzed intermolecular aerobic dehydrogenative aromatizations have been developed for the arylation of amines with nonaromatic ketones. Under optimized reaction conditions, primary and secondary amines are selectively arylated in good yields with cyclohexanones and 2-cyclohexen-1-ones in the presence of a Pd-catalyst under an atmosphere of molecular oxygen.

  已经开发了钯催化的分子间需氧脱氢芳构化，用于胺与非芳族酮的芳基化。在优化的反应条件下，在分子氧气氛下，在钯催化剂存在下，环己酮和2-环己烯-1-酮以高收率选择性地将伯胺和仲胺芳基化。
• Reaction products of alkenylsuccinic compounds with aromatic amines and lubricant compositions thereof
  申请人：MOBIL OIL CORPORATION

  公开号：EP0191967A2

  公开（公告）日：1986-08-27

  Products made by reacting (i) an alkenylsuccinic compound with (ii) an arylamine and (iii) an alkanolamine, an aminomethane or a hindered alcohol and borated reaction products thereof which provide superior dispersant and antioxidant activity to lubricant compositions when incorporated therein.

  (i)烯基琥珀酸化合物与(ii)芳基胺和(iii)烷醇胺、氨基甲烷或受阻醇反应生成的产品及其硼化反应产物，当加入润滑剂组合物中时，可为其提供优异的分散剂和抗氧化剂活性。
• Heat processing of liquid hydrocarbonaceous medium
  申请人：BETZ EUROPE, INC.

  公开号：EP0532265A2

  公开（公告）日：1993-03-17

  Reaction products of (a) polyalkenylsuccinic anhydride; (b) secondary, aromatic amines, and (c) hindered alcohols are used as effective antifoulants in liquid hydrocarbonaceous mediums, such as crude oils and gas oils, during processing of such liquids at elevated temperatures. The reaction products may be formed via a two-step reaction in which the polyalkenylsuccinic anhydride is reacted with the secondary, aromatic amine as a first step. The resulting polyalkenylsuccinimide may then be reacted with a hindered alcohol to form the desired antifoulant.

  (a)聚烯基丁二酸酐；(b)仲胺、芳香胺和(c)受阻醇的反应产物可用作液态烃类介质（如原油和气油）在高温下加工过程中的有效防污剂。反应产物可通过两步反应形成，其中第一步是聚烯基琥珀酸酐与仲胺、芳香胺反应。然后，生成的聚烯基琥珀酰亚胺可与受阻醇反应，形成所需的防污剂。
• Organic lectroluminescent element
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP1775335A2

  公开（公告）日：2007-04-18

  Materials for organic electroluminescence devices and organic electroluminescence devices which exhibit high efficiency of light emission and have a long life and excellent heat resistance, novel compounds and processes for producing the materials for organic electroluminescence devices are provided. The material for organic electroluminescence devices is represented by following general formula [1]: wherein A represents a substituted or unsubstituted arylene group having 22 to 60 carbon atoms, X1 to X4 each independently represent a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, X1 and X2 may be bonded to each other, X3 and X4 may be bonded to each other, Y1 to Y4 each independently represent an organic group represented by general formula [2], a to d each represent an integer of 0 to 2 and, when the arylene group represented by A has 26 or less carbon atoms, a+b+c+d>0 and the arylene group does not contain two or more anthracene nucleus; general formula [2] being: wherein R1 to R4 each independently represent hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, cyano group or form a triple bond by a linkage of R1 and R2 or R3 and R4, Z represents a substituted or unsubstituted aryl group having 6 to 20 carbon atoms and n represents 0 or 1.

  本发明提供了有机电致发光器件材料和有机电致发光器件，这些材料和器件发光效率高、寿命长、耐热性能优异，还提供了新型化合物和生产有机电致发光器件材料的工艺。 有机电致发光器件材料由以下通式[1]表示： 其中 A 代表具有 22 至 60 个碳原子的取代或未取代芳基，X1 至 X4 各自独立地代表具有 6 至 30 个碳原子的取代或未取代芳基，X1 和 X2 可以相互键合，X3 和 X4 可以相互键合、Y1至Y4各自独立地代表通式[2]所代表的有机基团，a至d各自代表0至2的整数，当A所代表的芳烯基团具有26个或更少的碳原子时，a+b+c+d>0，且芳烯基团不包含两个或更多的蒽核； 通式[2]为 其中 R1 至 R4 各自独立地代表氢原子、具有 1 至 20 个碳原子的取代或未取代的烷基、具有 6 至 20 个碳原子的取代或未取代的芳基、氰基或通过 R1 和 R2 或 R3 和 R4 的连接形成三键，Z 代表具有 6 至 20 个碳原子的取代或未取代的芳基，n 代表 0 或 1。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Hosokawa Chishio

  公开号：US20120153815A1

  公开（公告）日：2012-06-21

  A material for an organic electroluminescence device having the formula: wherein Ar 1 and Ar 3 each independently represent a substituted or unsubstituted phenylene group, X 5 represents a substituted or unsubstituted naphthyl group or a substituted or unsubstituted phenanthryl group, X 6 represents a substituted or unsubstituted phenyl group, and X 7 and X 8 each independently represent a substituted or unsubstituted biphenyl group or a substituted or unsubstituted terphenyl group. An organic electroluminescence device having (i) a light emitting layer, or (ii) a plurality of thin films of organic compounds having a light emitting layer, disposed between a pair of electrodes, wherein at least one of the thin films of organic compounds is a layer containing the material having the formula above.