1,3-Diethyl-2-methylenbenzimidazolin | 93661-57-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1,3-Diethyl-2-methylenbenzimidazolin
• 英文别名: 1,3-diethyl-2-methylidene-2,3-dihydro-1H-benzimidazole；1,3-diethyl-2-methylidenebenzimidazole
• CAS: 93661-57-5
• 化学式: C₁₂H₁₆N₂
• 分子量: 188.272
• InChiKey: SHYTXTWQVLSMHK-UHFFFAOYSA-N

物化性质

• 沸点：
  110 °C(Press: 0.003 Torr)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  五氟碘乙烷 、 1,3-Diethyl-2-methylenbenzimidazolin 在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 4.0h， 以40%的产率得到2-<3-(1,3-diethylbenzimidazolin-2-ylidene)-2-trifluoromethylprop-1-enyl>-1,3-diethylbenzimidazolium perchlorate
  参考文献：
  名称：

  ?-Perfluoroalkylimidocarbocyanines

  摘要：

  DOI：

  10.1007/bf00506414
• 作为产物：
  描述：

  1,3-Diethyl-2-methylbenzimidazolium-tetrafluoroborat 在 sodium hydride 、 四甲基胍 作用下， 以 苯 为溶剂， 反应 48.0h， 以72%的产率得到1,3-Diethyl-2-methylenbenzimidazolin
  参考文献：
  名称：

  Reichardt, Christian; Kaufmann, Norbert, Chemische Berichte, 1985, vol. 118, # 8, p. 3424 - 3427

  摘要：

  DOI：

文献信息

• DMF in Acetic Anhydride: A Useful Reagent for Multiple-Component Syntheses of Merocyanine Dyes
  作者：Frank Würthner

  DOI：10.1055/s-1999-3635

  日期：1999.12
• REICHARDT, CH.;KAUFMANN, N., CHEM. BER., 1985, 118, N 8, 3424-3427
  作者：REICHARDT, CH.、KAUFMANN, N.

  DOI：——

  日期：——
• PAZENOK, S. V.;KULCHINSKIJM, M. M.;YAGUPOLSKIJ, L. M., XIMIYA GETEROTSIKL. SOEDIN., 1984, N 9, 1285-1286
  作者：PAZENOK, S. V.、KULCHINSKIJM, M. M.、YAGUPOLSKIJ, L. M.

  DOI：——

  日期：——
• PHOTOELECTRIC CONVERSION MATERIAL, FILM CONTAINING THE MATERIAL, PHOTOELECTRIC CONVERSION DEVICE, PRODUCTION METHOD THEREOF, PHOTOSENSOR, IMAGING DEVICE AND THEIR USE METHODS
  申请人：HAMANO Mitsumasa

  公开号：US20110056562A1

  公开（公告）日：2011-03-10

  A compound represented by the following formula (I), and a photoelectric conversion device containing the compound: wherein Z 1 is a ring containing two carbon atoms and represents a 5-membered ring, a 6-membered ring or a condensed ring containing at least either a 5-membered ring or a 6-membered ring, each of L 1 , L 2 and L 3 independently represents an unsubstituted methine group or a substituted methine group, n represents an integer of 0 or more, each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 independently represents a hydrogen atom or a substituent, R 1 and R 2 , R 2 and R 3 , R 4 and R 5 , or R 5 and R 6 may be combined with each other to form a ring, and each of R 21 and R 22 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, provided that the case where both R 21 and R 22 are an unsubstituted phenyl group is excluded.
• PHOTOELECTRIC CONVERSION DEVICE, PRODUCTION METHOD THEREOF, PHOTOSENSOR, IMAGING DEVICE AND THEIR DRIVE METHODS
  申请人：NOMURA Kimiatsu

  公开号：US20110063485A1

  公开（公告）日：2011-03-17

  A photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film and an electrically conductive film in this order, wherein the photoelectric conversion film comprises a photoelectric conversion layer, and an electron blocking layer, wherein the electron blocking layer contains a compound represented by the specific formula.