N,N',N''-triphenylguanidinium chloride | 59283-92-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N',N''-triphenylguanidinium chloride
• 英文别名: triphenylguanidinium chloride；N,N',N''-triphenyl-guanidine; hydrochloride；N,N',N''-Triphenyl-guanidin; Hydrochlorid；N,N',N''-Triphenylguanidine--hydrogen chloride (1/1)；1,2,3-triphenylguanidine;hydrochloride
• CAS: 59283-92-0
• 化学式: C₁₉H₁₇N₃*ClH
• 分子量: 323.825
• InChiKey: QXAFZZMLBQVFDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.69
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2925290090

反应信息

• 作为反应物：
  描述：

  caesium [3,3'-commo-bis(η5-nonahydro-1,2-dicarba-3-nickel-closo-decarborate)] 、 N,N',N''-triphenylguanidinium chloride 在 sodium sulfite 作用下， 以 aq. acetate buffer 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Crystal structure of the N,N′,N″-triphenyl-guanidinium-bis-[η5-π-(3)-dicarbollide]Ni(III) complex

  摘要：

  Single crystals of a new compound containing triphenylguanidinium and bis(dicarbollide)nickel(III) [C(NHC6H5)(3)][Ni(B9C2H11)(2)] are obtained and analyzed by LOW-TEMPERATURE. Crystallographic data are: C23H40B18N3Ni, M = 611.87, monoclinic system, space group P2(1)/c, unit cell parameters: a = 21.9085(5) , b = 19.9294(4) , c = 14.8721(4) , beta = 91.4033(9)A degrees, V = 6491,5(4) (3), Z = 8, d (x) = 1.252 g/cm(3), T = 100 K, F(000) = 2536, mu = 0.621 mm(-1). The structure was solved by direct and Fourier methods and refined by the full matrix least squares technique in the anisotropic/isotropic (for H atoms) approximation up to the final factor R (1) = 0.053 for 10429 I (hkl) a parts per thousand yen 2 sigma (I) (Bruker X8 APEX diffractometer, {ie547-1} radiation). It contains two independent [C(NHC6H5)(3)](+) cations with different conformations and two [Ni(B9C2H11)(2)](-) anions with the same transoid conformation. Three types of weak intermolecular interactions are found: {ie547-2}; C-HaEuro broken vertical bar IEuro between the H(C) atoms of cluster anions and delocalized pi systems of Ph rings of cations; pi aEuro broken vertical bar pi interactions of Ph rings of cation 2 with each other.

  DOI：

  10.1134/s0022476613030116
• 作为产物：
  描述：

  N,N'-二苯基硫脲 在 lead(II) oxide 、 sulfur 、 苯 作用下， 生成 N,N',N''-triphenylguanidinium chloride
  参考文献：
  名称：

  Macholdt-Erdniss, Chemische Berichte, 1958, vol. 91, p. 1992,1994

  摘要：

  DOI：

文献信息

• Synthesis, crystal structure, and properties of triphenylguanidinium perrhenate hemihydrate
  作者：A. Ya. Maruk、M. S. Grigor’ev、K. E. German

  DOI：10.1134/s1070328413040076

  日期：2013.5

  Triphenylguanidinium perrhenate hemihydrate, [(C6H5NH)3C]ReO4 · 0.5H2O (I), is synthesized, and its crystal structure and some properties are studied. The colorless extended plate-like crystals of compound I are triclinic (space group \(P\bar 1\), Z = 4, 293 K, a = 9.8716(17), b = 14.093(2), c = 15.439(3)Å, α = 99.632(9)○, β = 101.802(9)○, γ = 95.361(10)○). Compound I has no isostructural analogs,

  合成了高苯甲酸三苯胍鎓半水合物[（（C 6 H 5 NH）3 C] ReO 4 ·0.5H 2 O（I），并对其晶体结构和某些性能进行了研究。化合物I的无色延伸板状晶体是三斜晶（空间群\（P \ bar 1 \），Z = 4，293 K，a = 9.8716（17），b = 14.093（2），c = 15.439（3 ）Å，α= 99.632（9）○，β= 101.802（9）○，γ= 95.361（10）○）。化合物I没有同构的类似物，并且在晶体学上独立的三苯基胍鎓阳离子的构象与所有其他结构研究的化合物中的这类阳离子相比，具有更高的对称性（C 3 h ）。确定以下参数：化合物I（383 K）的温度稳定性的上限，无水[（C 6 H 5 NH）3 C] ReO 4（Ia）的熔点为441 K，脱水的焓化合物I（ΔH （383 K）脱水= 10.0（8）kJ / mol）和无水Ia的熔化焓（Δ
• Reaction of Thiophosphoryl Trichloride with N,N'-Diphenylthiourea
  作者：Lenka Dastychová、Jiří Příhoda、Jan Taraba

  DOI：10.1135/cccc20070297

  日期：——

  New heterocyclic thiophosphoric compounds containing the N-C-N sequence in the ring were prepared by the reaction of thiophosphoryl trichloride (PSCl₃) with N,N'-diphenylthiourea. Depending on the reaction conditions, two types of heterocyclic compounds were obtained, namely 2-chloro-1,3-diphenyl-1,3,2λ⁵-diazaphosphetidine-2,4-dithione (1) and 2-chloro-1,3,5-triphenyl-1,3,5,2λ⁵-triazaphosphinane-2,4,6-trithione (2). N,N',N″-Triphenylguanidinium chloride (3) was identified in the reaction mixture as a by-product in all cases. The course of reactions was followed by ³¹P NMR spectroscopy and compound 3 was characterized by single-crystal X-ray diffraction.

  通过 thiophosphoryl trichloride (PSCl3) 与 N, N'-二苯基硫脲反应制备了含有环中 N-C-N 序列的新杂环硫代磷化合物。根据反应条件，得到了两种类型的杂环化合物，即 2-氯-1,3-二苯基-1,3,2λ5-二氮杂磷硫杂环-2,4-二硫酮 (1) 和 2-氯-1,3,5-三苯基-1,3,5,2λ5-三氮杂磷杂环-2,4,6-三硫酮 (2)。在所有情况下，反应混合物中检测到了副产物 N, N', N''-三苯基脲盐酸盐 (3)。反应过程通过31P NMR光谱学进行了跟踪，化合物3通过单晶X射线衍射进行了表征。
• Route to Stabilization of Nanotechnetium in an Amorphous Carbon Matrix: Preparative Methods, XAFS Evidence, and Electrochemical Studies
  作者：Vitaly V. Kuznetsov、Konstantin E. German、Olga A. Nagovitsyna、Elena A. Filatova、Mikhail A. Volkov、Anastasiia V. Sitanskaia、Tatiana V. Pshenichkina

  DOI：10.1021/acs.inorgchem.3c03001

  日期：2023.11.13

  pertechnetates with large organic cations under an argon atmosphere. Parallel carbonization of organic cations (hexamethyleneiminium and triphenylguanidinium), which occurs during the thermal decomposition of their pertechnetates, leads to the formation of X-ray amorphous solid products. An X-ray absorption fine structure study revealed that they have a crystal structure containing technetium–carbon bonds

  锝-碳纳米相是通过高锝酸盐与大有机阳离子在氩气氛下热分解而获得的。有机阳离子（六亚甲基亚胺和三苯基胍）在其高锝酸盐热分解过程中发生平行碳化，导致 X 射线无定形固体产物的形成。X射线吸收精细结构研究表明，它们具有含有长度为1.76 Å的锝-碳键的晶体结构。随后在 1073–1673 K 下进行退火处理后，合成的锝-碳相具有a为 4.01 ± 0.03 Å 的立方晶格。相同高铼酸盐的热分解产物也是X射线无定形的；然而，与高锝酸盐不同的是，其中铼和碳原子之间的距离明显更大（2.14 Å）。随后退火后，它们具有六方晶格。通过热分解具有大有机阳离子的高锝酸盐制备的锝-碳纳米相的电化学性能与用金属锝制备的锝-碳纳米相的性能不同。在循环伏安图的第一次阳极扫描中观察到的碳化锝在电极表面氧化成氧化物的情况可用于在开路条件下沉积贵金属纳米团簇，以制备用于析氢反应的复合催化剂。无定形碳基质中的纳米锝也可以成为
• EVERS R.; FISCHER E., Z. CHEM. <ZECE-AL>, 1976, 16, NO 1, 15-16
  作者：EVERS R.、 FISCHER E.

  DOI：——

  日期：——
• HIGH TEMPERATURE MATERIAL COMPOSITIONS FOR HIGH TEMPERATURE THERMAL CUTOFF DEVICES
  申请人：Kent Perry

  公开号：US20120121795A1

  公开（公告）日：2012-05-17

  The present disclosure provides a high-temperature thermal pellet composition that maintains structural rigidity up to a transition temperature of about 240° C. The composition comprises at least one organic compound (e.g., triptycene or 1-aminoanthroquinone). The pellet can be disposed in a housing of a thermally-actuated, current cutoff device, such as a high-temperature thermal cutoff device (HTTCO). Also provided are material systems, which include the pellet composition and a high-temperature seal that provides substantial sealing up to at least the transition temperature. Methods of making such high-temperature pellet compositions and incorporating them into a thermally-actuated, current cutoff device are also provided.