4-(Hydroxymethyl)-1-phenylpyrazolidin-3-one | 30346-45-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(Hydroxymethyl)-1-phenylpyrazolidin-3-one
• CAS: 30346-45-3
• 化学式: C₁₀H₁₂N₂O₂
• 分子量: 192.21
• InChiKey: KMXZBJKUSIYRPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  52.6
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• A method for stabilizing synthetic thermoplastic materials against thermal degradation
  申请人：CIBA-GEIGY AG

  公开号：EP0462068A2

  公开（公告）日：1991-12-18

  The present invention relates to a novel method for stabilizing synthetic thermoplastic materials against thermal degradation, which comprises incorporating in said materials one or more compounds of the formula (I) in which R₁ is unsubstituted or substituted phenyl, n is e.g. 1, 2 or 3, and, when n is 1, R₂ is e.g. -COR₃, - COOR₄ or -CO-N(R₅)R₆ in which R₃ is e.g. C₄-C₁₇alkyl, R₄ is e.g. C₄-C₁₈alky cyclohexyl or t-butylcyclohexyl, R₅ and R₆ which can be identical or different are e.g. C₂-C₈alkyl or cyclohexyl, and, when n is 2, R₂ is e.g. -CO-R₁₀-OC, -COO-R₁₁-OOC- or -CONH-R₁₂-NHCO- in which R₁₀ is e.g. C₂-C₈alkylene, R₁₁ is e.g. C₄-C₆alkylene and R₁₂ is e.g. C₄-C₆alkylene, and, when n is 3, R₂ is e.g. benzenetricarbonyl. Several compounds of the formula (I) are new

  本发明涉及一种新型方法，用于稳定合成热塑性材料，防止热降解，该方法包括在所述材料中加入一种或多种式 (I) 化合物 其中 R₁ 是未取代或取代的苯基，n 例如是 1、2 或 3，当 n 是 1 时，R₂ 例如是-COR₃、-COOR₄ 或-CO-N(R₅)R₆，其中 R₃ 例如是.g. C₄-C₁₇ 烷基，R₄ 例如是 C₄-C₁₈ 烷基环己基或叔丁基环己基，R₅ 和 R₆ 可以相同或不同。g. C₂-C₈ 烷基或环己基，且当 n 为 2 时，R₂ 例如是-CO-R₁₀-OC、-COO-R₁₁-OOC-或-CONH-R₁₂-NHCO-，其中 R₁₀ 为 e。R₁₁-OOC-或-CONH-R₁₂-NHCO-，其中 R₁₂ 如为 C₂-C₈烷基，R₁₁ 如为 C₄-C₆烷基，R₁₂ 如为 C₄-C₆烷基，当 n 为 3 时，R₂ 如为苯三羰基。 几种新的式 (I) 化合物
• Silver halide photographic light-sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0540295A1

  公开（公告）日：1993-05-05

  A silver halide photographic light-sensitive material optically sensitized in red wavelength region. The light-sensitive material comprises a support having thereon a silver halide emulsion layer containing an optical sensitizing dye represented by the following formula I; wherein Z is a group of atoms necessary to form a thiazole ring, a benzothiazole ring, a naphthothiazole ring, a selenazole ring, a benzoselenazole ring or a naphthoselenazole ring; R₁, R₂, R₃, R₄ and R₅ are independently a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, provided that at least three of groups represented by R₁, R₂, R₃, R₄ and R₅ each has an organic group having a water-solubilizing group. The light-sensitive material is excellent in storage stability and lowered color stain after processing.

  一种在红色波长区域光学感光的卤化银感光材料。这种感光材料包括一个支架，支架上有一个卤化银乳剂层，该层含有由下式 I 表示的一种光学感光染料； 其中 Z 是形成噻唑环、苯并噻唑环、萘并噻唑环、硒唑环、苯并硒唑环或萘并硒唑环所必需的原子团；R₁、R₂、R₃、R₄ 和 R₅ 独立地为氢原子、取代或未取代的烷基或取代或未取代的芳基，条件是 R₁、R₂、R₃、R₄ 和 R₅ 所代表的基团中至少有三个各自具有水溶性基团的有机基团。这种感光材料具有极佳的储存稳定性，并能在加工后降低色斑。
• Silver halide light-sensitive photographic comprising a phosphazene compound
  申请人：KONICA CORPORATION

  公开号：EP0921432A1

  公开（公告）日：1999-06-09

  A silver halide light-sensitive photographic material comprising at least one silver halide light-sensitive emulsion layer and at least one hydrophilic colloidal layer provided on the same side of a support wherein the silver halide light-sensitive photographic material comprises a phosphazen compound having at least one of the structural units represented by the general formula (1) or (2) the silver halide light-sensitive emulsion layer or the hydrophilic colloidal layer and a total coated gelatin amount of not more than 3.7g/m2 on the silver halide emulsion layer and the hydrophilic colloidal layer side in respect to the support: General formula (1) General formula (2) In the formula R1 and R2 each represents an alkyl group, an alkoxy group, an aryloxy group, an aryl group, an isothiocyanate group, an amino group, an alkylthio group, an arylthio group, an azide group, an alkenyl group, an alkinyl group, an acyl group, a cyano group, a cyanate group or isocyanate group, each of which group may be substituted or non-substituted, and R1 and R2 are the same or different; n1 represent a positive integer of 1 to 50000; n2 represents a positive integer of 3 or more.

  一种卤化银感光照相材料，包括至少一个卤化银感光乳剂层和至少一个亲水胶体层，提供在支撑物的同一侧，其中卤化银感光照相材料包括具有通式(1)或(2)所代表的结构单元中至少一个结构单元的磷氮化合物，卤化银感光乳剂层或亲水胶体层和涂布明胶总量不超过3.7g/m2： 通式（1） 通式（2） 式中 R1 和 R2 各代表一个烷基、一个烷氧基、一个芳氧基、一个芳基、一个异硫氰酸酯基、一个氨基、一个烷硫基、一个芳硫基、一个叠氮基、一个烯基、一个炔基、一个酰基、一个氰基、一个氰酸酯基或异氰酸酯基，其中每个基团可以是取代的或非取代的，R1 和 R2 相同或不同；n1 代表 1 至 50000 的正整数； n2 代表 3 或更多的正整数。
• US4835285A
  申请人：——

  公开号：US4835285A

  公开（公告）日：1989-05-30
• US5210118A
  申请人：——

  公开号：US5210118A

  公开（公告）日：1993-05-11