2-tert-amyl-4-methylphenol | 34072-71-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tert-amyl-4-methylphenol
• 英文别名: 4-methyl-2-(tert-pentyl)phenol；4-Methyl-2-(2-methylbutan-2-yl)phenol
• CAS: 34072-71-4
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: HSFXPWKQBDHWCN-UHFFFAOYSA-N

物化性质

• 熔点：
  26.5-27 °C
• 沸点：
  125-125.5 °C(Press: 9 Torr)
• 密度：
  0.951±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-tert-amyl-4-methylphenol 在 二叔丁基过氧化物 作用下， 反应 12.0h， 以57%的产率得到2-[2-hydroxy-5-methyl-3-(2-methylbutan-2-yl)phenyl]-4-methyl-6-(2-methylbutan-2-yl)phenol
  参考文献：
  名称：

  可见光驱动的过氧化二叔丁基促进酚类的氧化同源偶联和交叉偶联

  摘要：

  介绍了一种方便有效的双酚衍生物合成方法。在外部无光敏剂的条件下，可见光驱动的酚类氧化均偶联和交叉偶联反应顺利进行，从而得到具有高化学和区域选择性的双酚衍生物。

  DOI：

  10.1002/ejoc.202101469
• 作为产物：
  描述：

  对甲酚 、 2-甲基-丁烯 在 硫酸 作用下， 生成 2-tert-amyl-4-methylphenol
  参考文献：
  名称：

  Rubbery polymers stabilized with metal salts of alpha, alpha-bis (2-hydroxy-3:5-dialkyl-phenyl) alkanes

  摘要：

  公开号：

  US02748181A1

文献信息

• THE INFRARED FREQUENCIES AND INTENSITIES OF THE HYDROXYL BAND IN ORTHO-SUBSTITUTED PHENOLS
  作者：K. U. Ingold、D. R. Taylor

  DOI：10.1139/v61-056

  日期：1961.3.1

  The infrared frequencies, intensities, and half-band widths of the fundamental stretching vibration of the hydroxyl group have been measured for a large number of ortho-alkyl phenols. It has been found that phenols containing a single ortho-alkyl substituent exist as cis and trans isomers in unequal amounts, the trans isomer being the more abundant. The difference in free energy between the two isomers

  已经测量了大量邻烷基苯酚的羟基基本伸缩振动的红外频率、强度和半带宽。已经发现含有单个邻烷基取代基的酚以不等量的顺式和反式异构体形式存在，反式异构体更为丰富。对于邻甲酚、2,3-二甲基苯酚和几种邻叔烷基苯酚，在 24 °C 的四氯化碳稀溶液中测量了两种异构体之间的自由能差异。
• Zirconia-Modified Superacid UDCaT-5: An Efficient and Versatile Catalyst for Alkylation Reactions under Solvent-Free Conditions
  作者：Ganapati D. Yadav、Ganesh S. Pathre

  DOI：10.1080/00397910802139387

  日期：2008.7.24

  Abstract UDCaT-5, a modified version of zirconia, efficiently catalyzes alkylation of phenols with alcohols under environmentally safe, heterogeneous reaction conditions with high selectivity and in excellent yields. The high content present in UDCaT-5 with preservation of tetragonal phase of zirconia was responsible for the superactivity. Several phenolic compounds carrying either electron-sulfer

  摘要 UDCaT-5 是氧化锆的改性形式，可在环境安全的非均相反应条件下以高选择性和优异的产率高效催化酚与醇的烷基化反应。UDCaT-5 中存在的高含量同时保留了氧化锆的四方相是超活性的原因。几种酚类化合物在邻位、间位和对位上带有电子-硫释放或吸电子取代基，可提供高产率的产物。
• Colorants and polyester shaped articles mass-colored therewith
  申请人：Nippon Ester Company Ltd.

  公开号：EP0266754A2

  公开（公告）日：1988-05-11

  A heat resistant colorant for mass-coloring polyesters such as polyethylene terephthalate, comprising pigments and/or dyes and 42-2,000 parts per 100 parts of pigments and/or dyes by weight of a dispersing medium having a hydroxyl value not exceeding 25 mgKOH/g. The dispersing medium comprises a liquid dispersing medium, such as polyether, polyether-ester and the like, and a liquid aliphatic polyester dispersing medium. The colorants of the invention are easily blended and uniformly dispersed in a shape grade polyester, without causing degradation of the polyester, and the polyester shaped articles, such as fibers and films, mass-colored by the colorant are excellent in stability during the manufacture and are uniform in quality.

  一种用于聚酯（如聚对苯二甲酸乙二酯）大规模着色的耐热着色剂，包括颜料和/或染料，以及每 100 份颜料和/或染料重量中含 42-2000 份羟基值不超过 25 mgKOH/g 的分散介质。分散介质包括液体分散介质，如聚醚、聚醚酯等，以及液体脂肪族聚酯分散介质。本发明的着色剂易于混合并均匀地分散在定型级聚酯中，不会导致聚酯降解，而且由着色剂大量着色的聚酯定型制品（如纤维和薄膜）在制造过程中稳定性极佳，质量均匀。
• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• THERMOPLASTIC RESIN COMPOSITION CONTAINING THERMOPLASTIC POLYMER CONTAINING ALICYCLIC GROUP AND MOLDED OBJECT
  申请人：TEIJIN LIMITED

  公开号：EP1266937A1

  公开（公告）日：2002-12-18

  A thermoplastic resin composition (molding material) which suppresses dynamic brittleness caused by a reduction in molecular weight when a thermoplastic resin such as a hydrogenated styrene polymer is melt molded and does not generate crazes even when it is used at an atmosphere of high temperature and high humidity, and a substrate for optical recording media, which is made from the same. The thermoplastic resin composition comprises a thermoplastic polymer having an alicyclic group and an addition stabilizer which can undergo addition reaction with a radical formed by the cleavage of the thermoplastic polymer.

  一种热塑性树脂组合物（成型材料），可抑制热塑性树脂（如氢化苯乙烯聚合物）在熔融成型时因分子量降低而产生的动态脆性，即使在高温高湿的环境中使用也不会产生裂纹，以及由其制成的光学记录媒体基板。 热塑性树脂组合物包括一种具有脂环基的热塑性聚合物和一种可与热塑性聚合物裂解形成的自由基发生加成反应的加成稳定剂。