3-(2H-1,2,3-benzotriazol-2-yl)-4-biphenylol | 33981-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(2H-1,2,3-benzotriazol-2-yl)-4-biphenylol
• 英文别名: 3-benzotriazol-2-yl-biphenyl-4-ol；3-(2H-1,2,3-benzotriazol-2-yl)biphenyl-4-ol；2-(2'-Hydroxy-5'-phenylphenyl)-benzotriazol；2-(Benzotriazol-2-yl)-4-phenylphenol
• CAS: 33981-31-6
• 化学式: C₁₈H₁₃N₃O
• 分子量: 287.321
• InChiKey: KGVHAZMHOQLBEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(2H-1,2,3-benzotriazol-2-yl)-4-biphenylol 、 3-氯-2-甲基丙烯 在 potassium carbonate 、 potassium iodide 作用下， 以 丁酮 为溶剂， 反应 12.0h， 以65%的产率得到2-{4-[(2-methyl-2-propen-1-yl)oxy]-3-biphenylyl}-2H-1,2,3-benzotriazole
  参考文献：
  名称：

  Synthesis of New 2-(2´-Hydroxyaryl)benzotriazoles and Evaluation of Their Photochemical Behavior as Potential UV-Filters

  摘要：

  两种新型2-(2'-羟基苯基)苯并三唑衍生物通过光物理和光化学技术合成并研究，以评估它们作为紫外线滤光剂的能力。在不同极性的溶剂中，测定了这两种化合物的吸收和发射特性。在非极性溶剂中，建立了光诱导激发态分子内质子转移，导致紫外线能量的有效非辐射耗散。此外，这些化合物在模拟阳光照射下表现出光稳定性。

  DOI：

  10.3390/molecules15096205
• 作为产物：
  描述：

  3-(2-nitrophenylazo)biphenyl-4-ol 在 sodium hydroxide 、 苯甲醇 作用下， 反应 4.0h， 以98%的产率得到3-(2H-1,2,3-benzotriazol-2-yl)-4-biphenylol
  参考文献：
  名称：

  One-Pot Synthesis of Benzotriazoles and Benzotriazole 1-Oxides by Reductive Cyclization of o-Nitrophenylazo Compounds with Benzyl Alcohol

  摘要：

  Reductive cyclization of 2-[(nitrophenyl)azophenols 1 with benzyl alcohol and sodium hydroxide afforded 2-(2H-benzotriazol-2-yl)phenols 3 and their 1-oxide 2 in good to excellent yields.

  DOI：

  10.3987/com-09-11759

文献信息

• N-[2-hydroxy-3-(2H-benzotriazol-2-yl)benzyl]oxamides as light stabilisers
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0593936A1

  公开（公告）日：1994-04-27

  This invention relates to novel UV absorbers, their methods of preparation, their use in stabilizing polymers and polymers so stabilized against the degradative effects of UV light. The novel compounds of formula I are oxamides which are substituted on one or both nitrogens with a 2-hydroxy-3-(2H-benzotriazol-2-yl)benzyl group. The 2-hydroxy-3-(2H-benzotriazol-2-yl)benzyl groups are efficient UV absorbing groups and the oxamide group contributes additional light stabilizing, heat stabilizing and metal complexing properties to the compounds. The compounds have low-volatility and are especially useful as UV stabilizers for engineering resins processed at high temperatures.

  这项发明涉及新型紫外线吸收剂，其制备方法，其在稳定聚合物中的使用以及通过紫外线光的降解作用而得到稳定的聚合物。公式I的新型化合物是氧酰胺，其在一个或两个氮上被2-羟基-3-(2H-苯并三唑-2-基)苯甲基基团取代。2-羟基-3-(2H-苯并三唑-2-基)苯甲基基团是高效的紫外线吸收基团，而氧酰胺基团则为化合物提供了额外的光稳定、热稳定和金属络合性能。这些化合物具有低挥发性，特别适用于在高温下加工的工程树脂的紫外线稳定剂。
• Benzotriazol UV-Absorber, Verfahren zu ihrer Herstellung und stabilisierte Mischungen
  申请人：CIBA-GEIGY AG

  公开号：EP0031302A2

  公开（公告）日：1981-07-01

  Neue Verbindungen der Formel I worin die Symbole die in Anspruch 1 angegebene Bedeutung haben. Die Verbindungen können als UV-Stabilisatoren, insbesondere in Lacken, verwendet werden.

  式 I 的新型化合物 其中符号的含义如权利要求 1 所述。 这些化合物可用作紫外线稳定剂，特别是在油漆中。
• Vinyl chloride resin composition
  申请人：NIPPON CARBIDE KOGYO KABUSHIKI KAISHA

  公开号：EP0134389A2

  公开（公告）日：1985-03-20

  A vinyl chloride resin composition with a yield stress of 1 to 5 g/mm2, composed of (A) 100 parts by weight of a vinyl chloride resin containing 0 to about 20% by weight of a comonomer, (B) about 10 to about 80 parts by weight, per 100 parts by weight of the resin (A), of (B-1) a liquid polyester plasticizer having a number average molecular weight (Mn) of not less than about 1,500 and 0 to about 10 parts by weight, per 100 parts by weight of the resin (A), of (B-2) a plasticizer for the resin (A), which is other than said plasticizer (B-1), and (C) about 0.2 to about 200% by weight, based on the total weight of said plasticizers (B-1) and (B-2), of a low-molecular-weight acrylic or methacrylic resin having a number average molecular weight (Mn) of about 1,500 to about 50,000 and being solid at 23'C.

  一种屈服应力为 1 至 5 克/平方毫米的氯乙烯树脂组合物，由以下成分组成 (A) 100 份（按重量计）氯乙烯树脂，其中共聚单体的含量为 0%至约 20%、 (B) 以每 100 份树脂（A）的重量计，约 10 至约 80 份（B-1）平均分子量 （Mn）不小于约 1,500 的液态聚酯增塑剂，以及以每 100 份树脂（A）的 重量计，0 至约 10 份（B-2）除上述增塑剂（B-1）外的树脂（A）增塑剂， 以及 (C) 以所述增塑剂（B-1）和（B-2）的总重量为基准，约 0.2%至约 200%（重量比）的低分子量丙烯酸或甲基丙烯酸树脂，其平均分子量（Mn）约为 1,500 至约 50,000 且在 23'C 下为固态。
• HYDROTALCITE COMPOUND, PROCESS FOR PRODUCING THE SAME, AND AGRICULTURAL FILM CONTAINING THE SAME
  申请人：Kyowa Chemical Industry Co., Ltd.

  公开号：EP1052223A1

  公开（公告）日：2000-11-15

  A hydrotalcite compound which has the excellent ability to absorb infrared rays and has excellent light transmission when contained in an agricultural film; a process for producing the compound; and an infrared absorber and an agricultural film both containing the compound. The hydrotalcite compound is characterized by retaining as the interlayer anions at least one kind of anions selected among ions of silicon-, phosphorus-, and boron-containing polymeric oxyacids and another kind of anions.

  一种水滑石化合物，它具有极佳的红外线吸收能力，并且在农膜中含有该化合物时具有极佳的透光性；一种生产该化合物的工艺；以及一种含有该化合物的红外线吸收剂和农膜。该氢铝酸盐化合物的特点是，作为层间阴离子，至少保留了一种从含硅、磷和硼的聚合氧酸离子中选出的阴离子和另一种阴离子。
• FLUORESCENT RETROREFLECTIVE SHEET
  申请人：Nippon Carbide Kogyo Kabushiki Kaisha

  公开号：EP1273933A1

  公开（公告）日：2003-01-08

  This invention provides encapsulated type fluorescent retroreflective sheeting which is excellent in appearance and weatherability, and which comprises a surface-protective layer disposed on the side on which light is to strike, a binder layer connected to the surface-protective layer through network bonding parts, an air layer which is sealed-up by the network bonding parts between the surface-protective layer and the binder layer, and a retroreflective element layer disposed between the surface-protective layer and the air layer, or between the binder layer and the air layer, wherein at least one layer located on the light-incident side of sealed-up air layer contains at least one fluorescent dye selected from the group consisting of benzimidazole coumarin type-fluorescent dyes of formula (1) as follows: and benzopyran type-fluorescent dyes of formula (2) as follows:

  本发明提供了外观和耐候性极佳的封装型荧光逆反射薄板，它包括设置在光线照射侧的表面保护层、通过网络粘接部件与表面保护层连接的粘结剂层、通过网络粘接部件密封在表面保护层和粘结剂层之间的空气层，以及设置在表面保护层和空气层之间或粘结剂层和空气层之间的逆反射元件层、以及位于表面保护层和空气层之间或粘结剂层和空气层之间的逆反射元件层，其中位于密封的空气层受光侧的至少一层含有至少一种荧光染料，该荧光染料选自由如下式（1）的苯并咪唑香豆素型荧光染料组成的组： 和如下式（2）的苯并吡喃型荧光染料：