butane-2,3-dione-bis-(4-nitro-phenylhydrazone) | 94622-67-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: butane-2,3-dione-bis-(4-nitro-phenylhydrazone)
• 英文别名: Butan-2,3-dion-bis-(4-nitro-phenylhydrazon)；Diacetyl-bis-(4-nitro-phenylhydrazon)；4-Nitro-phenylosazon aus Acetoin；4-nitro-N-[3-[(4-nitrophenyl)hydrazinylidene]butan-2-ylideneamino]aniline
• CAS: 94622-67-0
• 化学式: C₁₆H₁₆N₆O₄
• 分子量: 356.341
• InChiKey: TZMRXVVSXVZBTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  140
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3-羟基-2-丁酮 、 4-硝基苯肼 在 溶剂黄146 作用下， 生成 butane-2,3-dione-bis-(4-nitro-phenylhydrazone)
  参考文献：
  名称：

  Hirsch, Biochemische Zeitschrift, 1922, vol. 131, p. 185

  摘要：

  DOI：

文献信息

• Quilico; Musante, Gazzetta Chimica Italiana, 1941, vol. 71, p. 327,336
  作者：Quilico、Musante

  DOI：——

  日期：——
• Wibaut; Boer, Recueil des Travaux Chimiques des Pays-Bas, 1955, vol. 74, p. 241,252
  作者：Wibaut、Boer

  DOI：——

  日期：——
• On the Constitution of α-Tocopherol
  作者：E. Fernholz

  DOI：10.1021/ja01270a057

  日期：1938.3
• 1,2,3-Triazol-1-imines. 1. The synthesis and lead tetraacetate oxidation of biacetyl benzoylhydrazone arylhydrazones to the novel 2-aryl-N-benzoyl-4,5-dimethyl-1,2,3-triazol-1-imines
  作者：C. P. Hadjiantoniou-Maroulis、A. J. Maroulis、A. Terzis、D. Mentzafos

  DOI：10.1021/jo00034a013

  日期：1992.4

  The synthesis and the Pb(OAc)4 oxidation of the mixed bishydrazones of biacetyl 7 was studied. The formation of the novel N-benzoyl-1,2,3-triazol-1-imines 9 from the oxidation of 7 provided support to the proposed in the past mechanism for the oxidation of bis-aroylhydrazones of alpha-dicarbonyl compounds 4. Thermolysis and photolysis of 9a in DMSO was carried out. The results suggested that benzoylnitrene was formed in the photochemical reaction, and therefore compounds such as 9 could serve as non-azide aroyl nitrene precursors. For 9a the results of the X-ray analysis were correlated with charge densities and bond orders gleaned by the MNDO method. Product 9d was alternatively synthesized by the addition of photochemically generated benzoylnitrene to the 1,2,3-triazole 21.
• The Nitrogen Compounds in Petroleum Distillates. XXIV. Isolation and Identification of a C₁₁H₁₇N Base from California Petroleum
  作者：H. L. Lochte、W. W. Crouch、E. D. Thomas

  DOI：10.1021/ja01264a010

  日期：1942.12