N,N'-diisobutylacetamidine | 106500-95-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-diisobutylacetamidine
• 英文别名: N,N'-di-iso-butylacetamidine；N,N'-bis(2-methylpropyl)ethanimidamide
• CAS: 106500-95-2
• 化学式: C₁₀H₂₂N₂
• 分子量: 170.298
• InChiKey: PPKYHRGDPVUEIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  四(二甲氨基)锆 、 N,N'-diisobutylacetamidine 以 甲苯 为溶剂， 以80%的产率得到tetrakis(N,N'-di-iso-butylacetamidinato)zirconium (IV)
  参考文献：
  名称：

  WO2008/2546

  摘要：

  公开号：
• 作为产物：
  描述：

  异丁胺 、 乙腈 在 Ln(CF₃SO₃)3 作用下， 反应 18.0h， 以22%的产率得到2,4,6-三甲基-1,3,5-三嗪
  参考文献：
  名称：

  Use of lanthanide(III) ions as catalysts for the reactions of amines with nitriles

  摘要：

  DOI：

  10.1021/jo00382a009

文献信息

• Synthesis and Characterization of Copper(I) Amidinates as Precursors for Atomic Layer Deposition (ALD) of Copper Metal
  作者：Zhengwen Li、Seán T. Barry、Roy G. Gordon

  DOI：10.1021/ic048492u

  日期：2005.3.21

  A series of copper(I) amidinates of the general type [(R ' NC(R)NR '')Cu](2) (R ' and R '' = n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl; R = methyl, n-butyl) have been synthesized and characterized. These compounds are planar dimers, bridged by nearly linear N-Cu-N bonds. Their properties (volatility, low melting point, high thermal stability, and self-limited surface reactivity) are well-suited for atomic layer deposition (ALD) of copper metal films that are pure, highly conductive, conformal, and strongly adherent to substrates.
• METAL(IV) TETRA-AMIDINATE COMPOUNDS AND THEIR USE IN VAPOR DEPOSITION
  申请人：President and Fellows of Harvard College

  公开号：EP2032529B1

  公开（公告）日：2012-10-17
• Metal (IV) tetra-amidinate compounds and their use in vapor deposition
  申请人：Gordon Roy G.

  公开号：US20080003359A1

  公开（公告）日：2008-01-03

  Metal(IV) tetrakis(N,N′-dialkylamidinates) were synthesized and characterized. Exemplary metals include hafnium, zirconium, tantalum, niobium, tungsten, molybdenum, tin and uranium. These compounds are volatile, highly stable thermally, and suitable for vapor deposition of metals and their oxides, nitrides and other compounds.
• US7638645B2
  申请人：——

  公开号：US7638645B2

  公开（公告）日：2009-12-29
• Use of lanthanide(III) ions as catalysts for the reactions of amines with nitriles
  作者：John H. Forsberg、Vincent T. Spaziano、Trichey M. Balasubramanian、Gordon K. Liu、Steven A. Kinsley、Charles A. Duckworth、John J. Poteruca、Paul S. Brown、Judith L. Miller

  DOI：10.1021/jo00382a009

  日期：1987.3