2-Amino-benzaldehyd-azin | 1929-18-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Amino-benzaldehyd-azin
• 英文别名: o-Amino-benzaldehyd-azin；2-[[(2-Aminophenyl)methylidenehydrazinylidene]methyl]aniline
• CAS: 1929-18-6
• 化学式: C₁₄H₁₄N₄
• 分子量: 238.292
• InChiKey: VGJHJGQIUUCBNW-UHFFFAOYSA-N

物化性质

• 熔点：
  238 °C
• 沸点：
  428.2±45.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-Amino-benzaldehyd-azin 在 一水合肼 作用下， 生成 2-氨基苯亚甲基肼
  参考文献：
  名称：

  Negotiating the Public Sphere through Private Correspondence: A Woman’s Letters of Liberty in Eighteenth-Century Germany

  摘要：

  The pivotal role played by letters in eighteenth‐century German literary, cultural and everyday life has long been recognised. In contrast to earlier times, many of the letters written in the eighteenth century were composed by women, and their correspondence provides modern scholars with a rich source of information abour the process of communication in the intimate, private and public spheres. The linited correspondence of Charlotte von Hezel, the first woman in Germany to edit a periodical under her own name, is of particular interest because it offers one of the few examaples of a woman corresponding with men for professional, not personal reasons. In addition, Hezel, not her male correspondents, represents the voice of authority within the area of activity being discussed: the publication of her magazine. Hezel’s self‐assurance is remarkable for a German woman of the time, and her letters demonstrate a liberating process of communication that allowed individuals hingered by gender, educational background or social status to debate contemporary issues and exchange serviced as they negotiated their entry into the public sphere.

  DOI：

  10.1111/1468-0483.00178
• 作为产物：
  描述：

  1-nitro-2-(2-nitrovinyl)benzene 在 镍 一水合肼 作用下， 以 乙醇 为溶剂， 生成 2-Amino-benzaldehyd-azin
  参考文献：
  名称：

  由2，β-二硝基苯乙烯制备辛啉和吲哚

  摘要：

  描述了用各种试剂还原2，β-二硝基苯乙烯（主要在4位和5位带有烷氧基或苄氧基）的方法。催化氢化产生吲哚。在阮内镍的存在下，肼可提供硝基苯乙烯或氨基苯甲醛所衍生出的硝基苯甲醛和and和azine。氢化铝锂产生吲哚和cinnolines的混合物。硼氢化钠产生2，β-二硝基苯基乙烷。

  DOI：

  10.1039/j39680000468

文献信息

• Synthesis of 1H-indazole: a combination of experimental and theoretical studies
  作者：Xinzhi Chen、Shaodong Zhou、Chao Qian、Chaohong He

  DOI：10.1007/s11164-012-0488-y

  日期：2012.9

  A new practical synthesis of 1H-indazole is presented. A previous mechanism for the cyclization step is proved to be nonfeasible and a hydrogen bond propelled mechanism is proposed. The new mechanism is suitable for similar cyclization, and a new reaction is predicted.

  介绍了一种1H-吲噁唑的新实用合成方法。之前的环化步骤机制被证明不可行，因此提出了一种由氢键推动的机制。该新机制适用于类似的环化反应，并预测了一种新的反应。
• Interweaved needle‐shaped <i>α</i>‐Ni(OH)₂ nanoparticles adorned on graphene oxide: A new class of heterogeneous catalysts for <i>α</i>‐alkylation of ketones and synthesis of azines
  作者：Shelly Kujur、Shruti Verma、Akash Kumar、Devendra Deo Pathak

  DOI：10.1002/aoc.7331

  日期：2024.2

  Electron Microscopy (FESEM) and Transmission Electron Microscopy (TEM) analysis, respectively. The catalytic potential of the nanocomposite was scrutinized in the synthesis of monosubstituted ketones via a hydrogen autotransfer strategy and synthesis of azines via dehydrogenative pathway. The products of both reactions were isolated in excellent yields and characterized by nuclear magnetic resonance (NMR)

  描述了一种合成装饰在氧化石墨烯α -Ni(OH) 2 -GO上的针状α -Ni(OH) 2纳米粒子的简单方法。纳米复合材料被分离为空气稳定的黑色粉末，并通过各种仪器技术进行表征。分别通过场发射扫描电子显微镜（FESEM）和透射电子显微镜（TEM）分析确定了装饰的α -Ni(OH) 2纳米颗粒的交织针状形态和平均粒径~7 nm 。通过氢自转移策略合成单取代酮和通过脱氢途径合成吖嗪，研究了纳米复合材料的催化潜力。两个反应的产物均以优异的产率分离出来，并通过核磁共振 (NMR) 光谱进行表征。α -Ni(OH) 2 -GO 可以分离并回收最多五个循环。操作简单、底物范围广泛、无毒副产物、可回收性和催化剂的卓越催化潜力是该协议的一些显着特征。
• Seibert, Chemische Berichte, 1948, vol. 81, p. 266,270
  作者：Seibert

  DOI：——

  日期：——
• Seibert, Chemische Berichte, 1947, vol. 80, p. 494,500
  作者：Seibert

  DOI：——

  日期：——
• Bonsignore, Leonardo; Cabiddu, Salvatore; Loy, Giuseppe, Journal of Heterocyclic Chemistry, 1985, vol. 22, p. 463 - 464
  作者：Bonsignore, Leonardo、Cabiddu, Salvatore、Loy, Giuseppe、Secci, Mario

  DOI：——

  日期：——