1,10-diaminodecane, terephthalic acid | 3316-85-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,10-diaminodecane, terephthalic acid
• 英文别名: 1,10-diaminodecane,terephthalic acid；1,10-decanediamine terephthalate；Decane-1,10-diamine;terephthalic acid
• CAS: 3316-85-6
• 化学式: C₈H₆O₄*C₁₀H₂₄N₂
• 分子量: 338.447
• InChiKey: FAVDVUWGQXXIIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.11
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  127
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  癸二胺 、 对苯二甲酸 以 乙醇 、 水 为溶剂， 以68%的产率得到1,10-diaminodecane, terephthalic acid
  参考文献：
  名称：

  对苯二甲酸酯和 2-氨基对苯二甲酸酯配合物与 1,10-二铵-癸烷阳离子的晶体结构测定和振动光谱研究

  摘要：

  摘要 晶体工程的最新进展表明，苯多羧酸和多胺共晶的应用前景越来越好。在这项工作中，我们展示了来自对苯二甲酸衍生物和长链二胺（1,10-二氨基癸烷）的两种“新”配合物的合成和表征。我们首先报告了其中两个配合物的 X 射线单晶衍射分析和 FT-IR 结果。然后我们通过 DFT 分析的支持分配观察到的实验振动模式。

  DOI：

  10.1016/j.molstruc.2019.127231

文献信息

• SEMIAROMATIC POLYAMIDE AND METHOD FOR PRODUCING SAME
  申请人：Unitika, Ltd.

  公开号：EP2554566A1

  公开（公告）日：2013-02-06

  The semiaromatic polyamide of the present invention includes a terephthalic acid component and a diamine component, wherein the diamine component is any of 1,8-octanediamine, 1,10-decanediamine and 1,12-dodecanediamine, and the proportion of the triamine unit in relation to the diamine unit in the polyamide is 0.3 mol% or less.

  本发明的半芳香族聚酰胺包括对苯二甲酸组分和二胺组分，其中二胺组分是 1,8-辛二胺、1,10-癸二胺和 1,12-十二烷二胺中的任何一种，三胺单元在聚酰胺中与二胺单元的比例为 0.3 摩尔%或更少。
• Eutectic melting behavior of polyamide 10,T-co-6,T and 12,T-co-6,T copolyterephthalamides
  作者：Theodore F. Novitsky、Christopher A. Lange、Lon J. Mathias、Scott Osborn、Roger Ayotte、Steven Manning

  DOI：10.1016/j.polymer.2010.03.045

  日期：2010.5

  Semi-aromatic polyterephthalamides 10,T and 12,T were synthesized with 0-60 wt-% PA-6,T comonomer by a melt polycondensation process. Molecular weights of the copolymers ranged from 12,000 to 27,000 g/mol and all produced tough melt-pressed films. The substituted aromatic carbon of the C-13 NMR spectra revealed that comonomer sequences are statistical: e.g., 50:50 wt-% PA-12,T-co-6,T copolymer had 12,T-12,T:12,T-6,T:6,T-6,T sequence ratios of approximately 1:2:1. Copolymers of both PA-10,T and 12. T exhibited a eutectic melting point at 30 wt-% PA-6,T, with melting points decreasing linearly from 315 and 292 degrees C to minima of 280 and 272 degrees C, respectively. Melting enthalpies showed similar minima at ca. 35 wt-% PA-6,T. WAXD and DMA were used to further characterize the eutectic behavior, and a comprehensive analysis of PA-6,T copolymer melting behavior is given. (C) 2010 Elsevier Ltd. All rights reserved.
• POLYAMIDE MOLDING COMPOSITIONS AND ELECTRICAL AND ELECTRONIC COMPONENTS MOLDED THEREFROM HAVING IMPROVED HEAT STABILITY
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP1539885A1

  公开（公告）日：2005-06-15
• [EN] POLYAMIDE MOLDING COMPOSITIONS AND ELECTRICAL AND ELECTRONIC COMPONENTS MOLDED THEREFROM HAVING IMPROVED HEAT STABILITY<br/>[FR] MELANGES A MOULER A BASE DE POLYAMIDE ET COMPOSANTS ELECTRIQUES ET ELECTRONIQUES MOULES A PARTIR DE CES MELANGES PRESENTANT UNE STABILITE THERMIQUE AMELIOREE
  申请人：DU PONT

  公开号：WO2004015010A1

  公开（公告）日：2004-02-19

  Polyamide molding compositions with improved blistering properties and electrical or electronic components made therefrom are provided. These compositions and components comprise 20-80 weight percent of polyamide or polyamide blend and comprising units derived from terephthalic acid or a derivative, and an aliphatic diamine with 10-20 carbons. Select ranges of inorganic filler and flame retardant and synergist are also disclosed.
• Crystal structure determination and vibrational spectroscopic studies of terephthalate and 2-amino terephthalate complexes with the 1,10-di-amonium-decane cation
  作者：A. Santoro、G. Bruno、F. Nicolò、G. Bella、G. Messina

  DOI：10.1016/j.molstruc.2019.127231

  日期：2020.2

  Abstract Recent advances in crystal engineering have shown an increasing trend in the promising employment of co-crystals obtained by benzene poly-carboxylic acids and polyamines. In this work, we present the synthesis and characterization of two “new” complexes coming from terephthalic derivates and a long chain diamine (1,10-diaminodecane). We firstly report the X-ray single crystal diffraction analysis

  摘要 晶体工程的最新进展表明，苯多羧酸和多胺共晶的应用前景越来越好。在这项工作中，我们展示了来自对苯二甲酸衍生物和长链二胺（1,10-二氨基癸烷）的两种“新”配合物的合成和表征。我们首先报告了其中两个配合物的 X 射线单晶衍射分析和 FT-IR 结果。然后我们通过 DFT 分析的支持分配观察到的实验振动模式。