trans-3-tert-butyl-2-phenyloxetane | 74267-41-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-3-tert-butyl-2-phenyloxetane
• 英文别名: (2R,3R)-3-tert-butyl-2-phenyloxetane
• CAS: 74267-41-7；74267-43-9
• 化学式: C₁₃H₁₈O
• 分子量: 190.285
• InChiKey: HEMFYTNGFWWBIC-NEPJUHHUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans-3-tert-butyl-2-phenyloxetane 生成 苯甲醛
  参考文献：
  名称：

  IMAI, TOSHIRO;NISHIDA, SHINYA, CAN. J. CHEM., 1981, 59, N 16, 2503-2509

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-3-tert-butyl-2-phenyloxetane 以15%的产率得到
  参考文献：
  名称：

  IMAI, TOSHIRO;NISHIDA, SHINYA, CAN. J. CHEM., 1981, 59, N 16, 2503-2509

  摘要：

  DOI：

文献信息

• Pigment dispersion and actinic radiation curable type ink jet ink composition
  申请人：Konica Minolta Medical & Graphic Inc.

  公开号：EP1508600A1

  公开（公告）日：2005-02-23

  A pigment dispersion including photopolymerizable compounds and pigments as well as an actinic radiation curable type ink jet composition including photopolymerizable compounds, photopolymerization initiators, and pigments are provided. The hydrophilicity δm of the surface of pigments incorporated therein is at most 22.

  本发明提供了一种包括可光聚合化合物和颜料的颜料分散体，以及一种包括可光聚合化合物、光聚合引发剂和颜料的光辐射固化型喷墨组合物。 其中颜料表面的亲水性 δm 最多为 22。
• Photocurable ink-jet ink, ink-jet image forming method and ink-jet recording apparatus using the same
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1614730A1

  公开（公告）日：2006-01-11

  A photocurable composition containing a photopolymerizable compound, a photoinitiator, a compound selected from the group consisting of a deodorizer, a perfume and an antioxidant.

  一种光固化组合物，含有一种可光聚合的化合物、一种光引发剂、一种从除臭剂、香水和抗氧化剂组成的组中选出的化合物。
• ACTIVE RAY CURABLE COMPOSITION, ACTIVE RAY CURABLE INKJET INK, IMAGE FORMING METHOD USING THE ACTIVE RAY CURABLE INKJET INK, AND INKJET RECORDING APPARATUS
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP2011811A1

  公开（公告）日：2009-01-07

  Disclosed is an active ray curable composition which is excellent in ejectability by an inkjet system and can be cured with high sensitivity. This active ray curable composition enables to form a coating film having high image quality and high film strength under various printing conditions. Also disclosed are an inkjet ink using such an active ray curable composition, an image forming method and an inkjet recording apparatus. Specifically disclosed is an active ray curable composition containing a photopolymerizable compound and a photopolymerization initiator. This active ray curable composition is characterized in that the photopolymerizable compound is a cationically polymerizable compound, and the composition contains a terminally polyether-modified silicone surface active agent.

  本发明公开了一种活性射线固化组合物，该组合物在喷墨系统中的顶出性极佳，并能以高灵敏度固化。这种活性射线固化组合物能够在各种印刷条件下形成具有高图像质量和高薄膜强度的涂膜。此外，还公开了使用这种活性射线固化组合物的喷墨墨水、图像形成方法和喷墨记录装置。具体公开了一种活性射线可固化组合物，其中含有一种可光聚合化合物和一种光聚合引发剂。这种活性射线可固化组合物的特点是：可光聚合化合物是阳离子可聚合化合物，组合物含有端聚醚改性的有机硅表面活性剂。
• INKJET HEAD, INKJET PRINTER, AND INKJET RECORDING METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP2110253A1

  公开（公告）日：2009-10-21

  Disclosed is an inkjet recording method wherein an image is formed on a recording medium by spraying an ink containing at least a photopolymerizable compound onto the recording medium through a nozzle of an inkjet head. This inkjet recording method enables to perform a stable image recording by suppressing formation of a precipitate in the head. This inkjet recording method is characterized in that in an inkjet head, which is used for forming an image on a recording medium by spraying an inkjet ink containing at least a photopolymerizable compound through a nozzle, the surface of at least a part of metals constituting the internal member of the inkjet head which is in contact with the inkjet ink is subjected to a passivation treatment or an insulation coating treatment.

  本发明公开了一种喷墨记录方法，通过喷墨头的喷嘴向记录介质喷射至少含有可光聚合化合物的墨水，从而在记录介质上形成图像。这种喷墨记录方法可抑制喷墨头中沉淀物的形成，从而实现稳定的图像记录。这种喷墨记录方法的特点是，在通过喷嘴喷射至少含有可光聚合化合物的喷墨墨水以在记录介质上形成图像的喷墨头中，构成喷墨头内部构件的至少一部分与喷墨墨水接触的金属表面要经过钝化处理或绝缘涂层处理。
• Image forming method
  申请人：——

  公开号：US20040246323A1

  公开（公告）日：2004-12-09

  A method for forming an image with an ink-jet printer, the ink-jet printer being provided with: (i) a recording head having a plurality of nozzles; and (ii) a radiation means to irradiate an ink ejected on a recording media, wherein the method comprises the steps of: (a) ejecting droplets of the ink from the nozzles on the recording media, provided that: (1) the ink contains a cationic polymerizable monomer and a photo acid generating agent; (2) the recording media has a surface pH value of not less than 6; and (3) a volume of each droplets is from 2 to 10 pl, (b) irradiating the ejected droplets of the ink on the recording media within a period of time between 0.01 and 1.0 second after arrival of the droplets on the recording media.

  一种用喷墨打印机形成图像的方法，该喷墨打印机配备有(i) 具有多个喷嘴的记录头；和 (ii) 用于照射喷射到记录介质上的墨水的辐射装置，其中该方法包括以下步骤：(a) 将墨水液滴从喷嘴喷射到记录介质上，条件是(1) 墨水含有阳离子可聚合单体和光酸生成剂；(2) 记录介质的表面 pH 值不小于 6；(3) 每个液滴的体积为 2 至 10 pl，(b) 在液滴到达记录介质后的 0.01 秒至 1.0 秒的时间段内，对记录介质上喷出的墨水液滴进行辐照。