ethylsulfanyl | 14836-22-7

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: ethylsulfanyl
• 英文别名: ethyl mercaptyl radical；ethylthio radical；Ethylmercaptan-Radikal；Aethanthiyl-Radikal；Ethylsulfid-radikal；Aethylthio-Radikal；CH3CH2S
• CAS: 14836-22-7
• 化学式: C₂H₅S
• 分子量: 61.1277
• InChiKey: WYRSGXAIHNMKOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  ethylsulfanyl 在 phosphonate 作用下， 以 水 为溶剂， 生成 乙硫醇 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  硫醇和二硫化物与亚磷酸酯基的反应。链机制和RS.cnt./PO32-.cntdot。平衡

  摘要：

  DOI：

  10.1021/j150607a024
• 作为产物：
  描述：

  ethanethiolate 在 phosphite radicals 作用下， 以 水 为溶剂， 生成 ethylsulfanyl
  参考文献：
  名称：

  亚磷酸根及其反应。氧化还原，取代和加成反应的例子

  摘要：

  DOI：

  10.1021/j100454a010

文献信息

• Electron spin resonance spin trapping of thiyl, radicals from the decomposition of thionitrites
  作者：P.David Josephy、Detlef Rehorek、Edward G. Janzen

  DOI：10.1016/s0040-4039(01)81144-8

  日期：1984.1

  Alkyl thiyl radicals produced by the homolytic decomposition of thionitrites are detected by ESR spin trapping using 5,5-dimethyl-1-Δ-pyrroline-N-oxide (DMPO).

  使用5，5-二甲基-1-Δ-吡咯啉-N-氧化物（DMPO）通过ESR自旋捕集检测由亚硫氰酸盐的均相分解产生的烷基噻吩基。
• Radical adducts of dibenzofulvenes and 9-methylenanthrone - an esr study
  作者：Angelo Alberti、Gian Franco Pedulli、Rino Leardin、Antonio Tundo、Giuseppe Zanardi

  DOI：10.1016/0040-4020(86)80018-7

  日期：1986.1

  R3M. radicals (M=C, Si, Ge, Sn, P, O, S) to give the corresponding paramagnetic adducts. In the case of 9-methylenanthrone radical addition occurred selectively at the exocyclic carbon-carbon double bond even with Group IV B organometallic radicals for which attack at the carbonyl oxygen would give rise to thermodynamically more stable adducts. When irradiating solutions of 9-methylenanthrone a photoinduced

  使标题化合物与一系列R 3 M.基团（M = C，Si，Ge，Sn，P，O，S）反应，得到相应的顺磁性加合物。在9-亚甲基蒽酮基团的情况下，即使在IV B族有机金属基团上，环碳-碳双键选择性地发生加成，其对羰基氧的攻击将产生热力学上更稳定的加合物。辐射9-甲基蒽酮溶液时，发生了光致自反应，导致形成了二聚体。根据测得的ESR光谱参数，讨论了加合物的结构，以及R n M基团对β-质子超细分裂常数的影响。
• Hypovalent radicals. 13. Gas-phase nucleophilic reactivities of phenylnitrene (PhN^- •) and sulfur anion radicals (S^-•) at sp³ and carbonyl carbon
  作者：Richard N. McDonald、A. Kasem Chowdhury

  DOI：10.1021/ja00340a010

  日期：1983.1
• Reactions of triplet carbenes with sulfides and disulfides: ylide vs. radical formation
  作者：A. Alberti、D. Griller、A. S. Nazran、G. F. Pedulli

  DOI：10.1021/ja00271a035

  日期：1986.5
• Photofragment vector correlations measured by transient absorption spectroscopy: cyanogen fragments from ethyl thiocyanate photodissociation
  作者：Gregory E. Hall、Ming Wu

  DOI：10.1021/j100144a003

  日期：1993.10

  The correlated angular distribution of translational and rotational motion of photofragments is probed by Doppler-broadened transient absorption line shapes. The one-photon nature of the probe process reduces the complexity of the analysis, while maintaining sensitivity to five bipolar moments of the translational and rotational angular distributions. The 193-nm photodissociation of C2H5SCN illustrates the method, with CN products detected with a titanium:sapphire ring laser probing the A2PI-X2SIGMA+ transition. The vector correlations in the high rotational states of CN indicate a direct dissociation following a transition of mixed symmetry at 193 nm: the recoil is preferentially but not exclusively parallel to a transition moment, and the perpendicular component is dominated by a rotation axis parallel to a C2H5SCN transition moment. The strong rotational excitation is generated by planar bending forces in a bent excited state. Lower rotational states are formed with a composite kinetic energy distribution, indicating an additional, slower, less highly polarized channel that partitions more energy into the unobserved C2H5S radical than does the direct channel. At 248 nm, a weaker absorption also generates CN photofragments with a preferentially parallel recoil, requiring a reassessment of the excited-state assignments in the alkyl thiocyanates.