(3-chloro-2-propenyl)-benzene | 6268-37-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-chloro-2-propenyl)-benzene
• 英文别名: (3-chloro-2-propenyl)benzene；1-Chlor-3-phenyl-1-propen；1-phenylallyl chloride；1ξ-chloro-3-phenyl-propene；1ξ-Chlor-3-phenyl-propen；1-Chlor-3-phenyl-propen；(3-Chloroallyl)benzene；3-chloroprop-2-enylbenzene
• CAS: 6268-37-7
• 化学式: C₉H₉Cl
• 分子量: 152.623
• InChiKey: JJTUJRVKTPSEFZ-UHFFFAOYSA-N

物化性质

• 沸点：
  213.05°C
• 密度：
  1.0730

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3-chloro-2-propenyl)-benzene 在 水 、 碳酸氢钠 作用下， 生成 苯丙酮
  参考文献：
  名称：

  Production of ketones

  摘要：

  公开号：

  US02658919A1
• 作为产物：
  描述：

  <α,α-Dichlor-methyl>-phenaethyl-sulfon 在 sodium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 生成 (3-chloro-2-propenyl)-benzene
  参考文献：
  名称：

  .alpha.-Halo sulfones. VII. The Ramberg-Baecklund rearrangement of .alpha.,.alpha.-dichloromethyl sulfones

  摘要：

  DOI：

  10.1021/ja00993a043

文献信息

• Selective reduction of tertiary alkyl, benzyl, and allyl halides to hydrocarbons using lithium 9,9-di-n-butyl-9-borabicyclo[3.3.1]nonanate
  作者：Hiroo Toi、Yoshinori Yamamoto、Akio Sonoda、Shun-Ichi Murahashi

  DOI：10.1016/s0040-4020(01)97982-7

  日期：——

  The title 9-borabicyclo[3.3.1]nonane(9-BBN) ate complex (1) brings about selective removal of tertiary alkyl, benzyl and allyl halides to give the corresponding hydrocarbons in excellent yields without concomitant attack on secondary, primary and aryl derivatives. The reduction of cis- and trans - 4 - t - butyl - 1 - methylcyclohexyl chlorides (2) with 1 gives 4 - t - butyl - 1 - methylcyclohexanes

  标题9-borabicyclo [3.3.1]壬烷（9-BBN）配合物（1）可以选择性地除去叔烷基，苄基和烯丙基卤，从而以优异的收率得到相应的烃，而不会伴随着对仲，伯和芳基的攻击衍生品。的还原顺式-和反式- 4 -吨-丁基- 1 -甲基环己基氯化物（2）与1给出4 -吨-丁基- 1 - methylcyclohexanes（3），在环己烷的配置的局部反转，而在苯给出热力学稳定的反式- 3为主。1,1-二甲基-5-己烯基氯化物的反应（4）和1,7,7- -三甲基二环[2.2.1]庚- 2 -基磺酰氯（8）配有1继续进行到碳离子中间特性的重排。要求1所述的还原-乙基- 1 -甲基戊基氯与1如下二阶速率方程。
• COMPOSITIONS AND METHODS FOR STABILIZING WATER SENSITIVE CLAYS AND MIGRATING FINES IN SUBTERRANEAN FORMATIONS
  申请人：PfP TECHNOLOGY, LLC

  公开号：US20180118999A1

  公开（公告）日：2018-05-03

  Clay stabilization compositions include one or a plurality of triamino compounds and/or derivatives thereof, fluids containing an effective amount of the clay stabilization compositions and methods for making and using same.

  黏土稳定剂组合物包括一种或多种三氨基化合物及/或其衍生物，含有有效量的黏土稳定剂组合物的流体以及制备和使用它们的方法。
• 5-Benzyl-2-oxazolidone derivatives and a process for producing the same
  申请人：Nippon Chemiphar Co., Ltd.

  公开号：US04062862A1

  公开（公告）日：1977-12-13

  5-Benzyl-2-oxazolidone derivatives of the formula: ##STR1## wherein R.sub.1 represents a hydrogen, halogen, lower alkyl, trihalogenomethyl, phenyl, benzyl, hydroxy, lower alkoxy, phenoxy, benzyloxy, acyloxy, allyloxy, alkylcarbonyl, arylcarbonyl or alkylenedioxy group, and R.sub.2 represents a hydrogen atom, a lower alkyl, lower alkylcarbonyl, lower-dialkylamino-lower-alkyl, aryl, aralkyl or arylcarbonyl group.

  式子为：##STR1##的5-苄基-2-噁唑啉衍生物中，其中R.sub.1代表氢、卤素、较低的烷基、三卤甲基、苯基、苄基、羟基、较低的烷氧基、苯氧基、苄氧基、酰氧基、烯丙氧基、烷基羰基、芳基羰基或烷基二氧基基团，而R.sub.2代表氢原子、较低的烷基、较低的烷基羰基、较低的二烷基氨基较低的烷基、芳香族、arylalkyl或芳基羰基基团。
• End-capped polyarylene polyethers, articles made therefrom and process for preparing such polyarylene polyethers
  申请人：AMOCO CORPORATION

  公开号：EP0106023A2

  公开（公告）日：1984-04-25

  Class of high performance thermosetting materials composed of polyarylene polyether resins having each of their ends capped with a monovalent unsaturated organo radical. The end-capped polyarylene polyether resins have the formula: wherein Z and Z' are each a monovalent unsaturated organo radical. Usually Z and Z' are alkylene, aralkylene or cycloalkylene moieties. The end-capped polyarylene polyethers can be cured as is or in the presence of one or more unsaturated comonomers to afford homopolymers or copolymers, respectively. Such cured systems exhibit high glass transition temperatures, good tensile properties, excellent electric and alkali resistance and improved stress cracking resistance. End- terminated polysulfone resins having molecular weight of 5,00 to 15.000 are especially advantageous. The properties exhibited by the vinyl/allyl terminated oligomers are useful in fields which require high temperature performance, excellent solvent resistance and good fabrication characteristics. Specific areas of application include high performance molded products for appliances and electronics, high temperature laminates and adhesives and protective and insulative coatings.

  一类高性能热固性材料，由聚芳醚树脂组成，每种树脂的末端都有一个一价不饱和有机基。末端封端的聚芳基聚醚树脂的结构式如下 其中 Z 和 Z'各为一价不饱和有机基。通常 Z 和 Z' 为亚烷基、芳烷基或环烷基。末端封端的聚芳基醚可以原样固化，也可以在一种或多种不饱和共聚单体的存在下固化，分别生成均聚物或共聚物。这种固化体系具有较高的玻璃化转变温度、良好的拉伸性能、优异的耐电和耐碱性能以及更强的抗应力开裂性能。分子量在 5,00 至 15,000 之间的端末端聚砜树脂尤其具有优势。乙烯基/烯丙基端接低聚物所表现出的特性适用于需要高温性能、优异的耐溶剂性和良好的制造特性的领域。 具体应用领域包括用于电器和电子产品的高性能模塑产品、高温层压板和粘合剂以及保护性和绝缘性涂层。
• Method for improving impulse breakdown strength of electrically insulating materials
  申请人：Nippon Petrochemicals Co., Ltd.

  公开号：EP0180771A1

  公开（公告）日：1986-05-14

  The present invention provides a method for improving the impulse breakdown strength of an electrically insulating material which is characterized by employing, as said electrical insulating material, an ethylene copolymer prepared by high-pressure radical polymerization of ethylene or a mixture of ethylene and another monomer in the presence. of at least one compound selected from the group consisting of one- to three-ring aromatic compounds (except styrene and substituted styrenes each having a single ring) each having one carbon-carbon double bond in one molecule, at a polymerization pressure of 500 to 4,000 kg/cm2 at a polymerization temperature of 50 to 400°C, wherein said ethylene copolymer contains 0.005 to 1 mol% of a unit derived from said aromatic compound as component of the polymer.

  本发明提供了一种提高电绝缘材料脉冲击穿强度的方法，其特征在于作为所述电绝缘材料，采用乙烯共聚物，该乙烯共聚物是由乙烯或乙烯与另一种单体的混合物在存在下列物质的情况下通过高压自由基聚合制备的。在聚合压力为 500 至 4000 公斤/厘米2、聚合温度为 50 至 400 摄氏度的条件下，至少含有一种选自单环至三环芳香族化合物（苯乙烯和具有单环的取代苯乙烯除外）组的化合物，其中所述乙烯共聚物含有 0.005 至 1 摩尔%由所述芳香族化合物衍生的单元作为聚合物的组分。