1,1,1-trichloropentane | 3922-27-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1,1,1-trichloropentane
• 英文别名: 1,1,1-trichloro-pentane；1,1,1-Trichlor-pentan；Trichloro-1,1,1-pentan；1,1,1-Trichlorpentan
• CAS: 3922-27-8
• 化学式: C₅H₉Cl₃
• 分子量: 175.485
• InChiKey: MPSRDSQITWIFME-UHFFFAOYSA-N

物化性质

• 熔点：
  18°C (estimate)
• 沸点：
  174.39°C (estimate)
• 密度：
  1.1840

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903199000

反应信息

• 作为反应物：
  描述：

  1,1,1-trichloropentane 在 氯 作用下， 以 二硫化碳 为溶剂， 生成 1,1,1,4-tetrachloro-pentane
  参考文献：
  名称：

  Burton,T.; Bruylants,A., Bulletin des Societes Chimiques Belges, 1972, vol. 81, p. 639 - 642

  摘要：

  DOI：
• 作为产物：
  描述：

  四氯化碳 、 乙烯 生成 1,1,1-trichloropentane
  参考文献：
  名称：

  Chukovskaya,E.Ts. et al., Journal of Organic Chemistry USSR (English Translation), 1967, vol. 3, p. 1320 - 1324

  摘要：

  DOI：

文献信息

• Halogenated hydrocarbons and method for their preparation
  申请人：DU PONT

  公开号：US02440800A1

  公开（公告）日：1948-05-04

  Telomers are prepared by subjecting aliphatic mono-olefines and a substance YZ to elevated temperature and pressure in the presence of an ethylene polymerization catalyst. The substance YZ is defined as being free from aliphatic carbon-carbon unsaturation and capable of forming monovalent fragments Y and Z, one of which is an inorganic acid radicle and the other is either an inorganic acid radicle or a radicle containing carbon and which is (a) a halogen, e.g. chlorine, bromine and iodine; (b) a halogen containing carbon compound, e.g. chloriodoform, a -brompropionic acid, propyl trichloracetate, chloracetic anhydride, chlorpropionaldehyde, ethylene bromhydrin, glycerol a -monochlorhydrin, monochlormethyl ether, methyl chloride and chloracetyl chloride; (c) or compounds containing halogen in combination with an inorganic acid radicle, e.g. cyanogen chloride and bromide; (d) a sulphur halide, e.g. benzene sulphonyl chloride and sulphuryl chloride; (e) cyanogen; or (f) an ester of an inorganic acid, e.g. triethyl borate, tetraethyl silicate, tributyl phosphate and methyl sulphate. Suitable catalysts are oxygen, hydrogen, acetyl, benzoyl, diethyl and tetrahydronaphthalene peroxides, alkali ammonium persulphates, perborates and percarbonates, tetraethyl and tetraphenyl lead, ultra-violet light especially in the presence of photosensitizers such as mercury, alkyl iodides, benzoin and acetone, di-, tri-methylamine oxides dibenzoyl hydrazine, hydrazine hydrochloride and sebacate and hexachloroethane water solvents, e.g. isooctane, cyclohexane, benzene and dioxane, surface active agents, e.g. sodium acetoxyoctadecyl sulphate, buffers, and substances capable of forming interpolymers with olefines, e.g. vinyl compounds and unsaturated acids, esters and ketones may be present. Examples describe the telomerization of ethylene and carbon tetrachloride (1 to 5); chloroform (6 to 7); methylene chloroiodide (8); chloral hydrate (9); 1,1,1-trichloroethane (10); ethyl dichloroacetate (11); dichloroacetic acid (12); hexachloroethane (13); tetra- and pentra-chloroethylbenzenes (14); hexachlorobenzene (15); trichlorofluoromethane (16); dimethyl sulphate (17); ethyl orthosilicate (18); sulphuryl chloride (19); ethyl iodide (20); a ,a 1-dichloro-dimethyl ether (25); isobutylene and carbon tetrachloride (21); ethylene carbon tetrachloride and n-octene-1 (22), styrene (23); and vinyl chloride (24). The products may contain pure compounds, e.g. of the type Cl(CH2.CH2)nCCl3, where n is an integer. They may be used as solvents, heat transfer media, plasticisers, wax substitutes, coating materials and as additions to lubricating oils. Specifications 471,590, 497,643, 578,584 and 581,900 are referred to.

  端粒是通过将脂肪族单烯烃和一种名为YZ的物质在乙烯聚合催化剂存在下在高温高压下处理制备的。物质YZ被定义为不含脂肪族碳碳不饱和度并且能够形成一价片段Y和Z的物质，其中一个是无机酸基团，另一个是含碳的无机酸基团或含有碳的基团，其为(a) 卤素，例如氯、溴和碘；(b) 含碳卤素化合物，例如氯碘甲烷、α-溴丙酸、三氯乙酸丙酯、氯乙酸酐、氯丙醛、溴水合乙烯、甘油α-单氯水合物、单氯甲基醚、氯化甲烷和氯乙酰氯；(c) 或含有卤素与无机酸基团结合的化合物，例如氰化氯和溴化物；(d) 硫卤素，例如苯磺酰氯和亚砜氯；(e) 氰化物；或(f) 无机酸酯，例如三乙基硼酸酯、四乙基硅酸酯、三丁基磷酸酯和硫酸甲酯。适用的催化剂包括氧气、氢气、乙酰、苯甲酰、双乙基和四氢萘过氧化物、碱金属过硫酸盐、过硼酸盐和过碳酸盐、四乙基和四苯基铅、紫外光尤其在存在光敏剂如汞、烷基碘化物、苯甲醇和丙酮、二甲基胺氧化物、二苯甲酰肼、盐酸和己二酸和六氯乙烷水溶剂，例如异辛烷、环己烷、苯和二噁烷、表面活性剂，例如乙酰氧基十八烷基硫酸钠、缓冲剂和能够与烯烃形成共聚物的物质，例如乙烯化合物和不饱和酸、酯和酮可能存在。示例描述了乙烯和四氯化碳（1至5）；氯仿（6至7）；氯碘甲烷（8）；氯乙醛（9）；1,1,1-三氯乙烷（10）；二氯乙酸乙酯（11）；二氯乙酸（12）；六氯乙烷（13）；四氯和五氯乙基苯（14）；六氯苯（15）；三氟氯甲烷（16）；硫酸二甲酯（17）；正硅酸乙酯（18）；亚砜氯（19）；碘化乙基（20）；α,α'-二氯二甲醚（25）；异丁烯和四氯化碳（21）；乙烯四氯化碳和正辛烯-1（22）、苯乙烯（23）；和氯乙烯（24）的端粒化反应。产品可能含有纯化合物，例如Cl(CH2.CH2)nCCl3类型的化合物，其中n是整数。它们可用作溶剂、传热介质、增塑剂、蜡替代品、涂料材料以及添加到润滑油中。规范471,590、497,643、578,584和581,900被提及。
• METHOD FOR PRODUCING CYCLIC CARBONATE
  申请人：NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：US20160145234A1

  公开（公告）日：2016-05-26

  Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases. A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.

  提供了一种生产环状碳酸酯的方法，该方法通过反应环氧化物和二氧化碳获得，能够高效地以高转化率和高产率生产环状碳酸酯，同时抑制催化剂随时间降解并且催化活性几乎不会下降。在存在从属于具有卤素阴离子作为对离子的季铵盐和具有卤素阴离子作为对离子的季膦盐中选择的季铵盐，或者存在通过将季铵盐固定在载体上而获得的固体催化剂的情况下，通过在反应体系中添加含有至少一个卤素原子的有机卤素化合物来生产环状碳酸酯的方法。
• [EN] FUNGICIDAL COMPOSITIONS<br/>[FR] COMPOSITIONS FONGICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2012146125A1

  公开（公告）日：2012-11-01

  The present invention provides a composition comprising a combination of components A) and B), wherein component A) is a compound of formula (I) and the component (B) is a further fungicide, insecticide or herbicide.

  本发明提供了一种包含组分A)和B)的组合物，其中组分A)是化合物的公式(I)，组分B)是另一种杀真菌剂、杀虫剂或除草剂。
• FUNGICIDAL COMPOSITIONS
  申请人：Haas Ulrich Johannes

  公开号：US20140335201A1

  公开（公告）日：2014-11-13

  The present invention provides a composition comprising a combination of components A) and B), wherein component A) is a compound of formula (I) and the component (B) is a further fungicide, insecticide or herbicide.

  本发明提供了一种组合物，包括组分A)和B)，其中组分A)是化合物的公式(I)，组分B)是另一种杀真菌剂、杀虫剂或除草剂。
• [EN] METHOD FOR PRODUCING N-RETINOYLCYSTEIC ACID ALKYL ESTER<br/>[FR] PROCÉDÉ DE PRODUCTION D'ESTER ALKYLIQUE DE L'ACIDE N-RÉTINOYLCYSTÉIQUE
  申请人：ARDENIA INVESTMENTS LTD

  公开号：WO2017099662A1

  公开（公告）日：2017-06-15

  A method for producing derivatives of N-retinoylaminoalkane sulfonic acid, the method comprising providing retinoic acid, chloroformate, aminoalkanesulfonic acid selected from the group consisting of cysteic acidand alkyl ester thereof, cysteinesulfinic acid and alkyl ester thereof, homocysteic acid and alkyl ester thereof, homocysteinesulfinic acid and alkyl esters thereof, taurine and derivatives thereof, and an organic solvent,and a base, mixing said components under substantial absence of oxidizing compoundsthereby forming a reaction mixture comprising a liquid phase, wherein the liquid phase is one phaseand the derivatives of N-retinoylaminoalkane sulfonic acid are formed in said liquid phase.

  一种生产N-视黄酰氨基烷磺酸衍生物的方法，所述方法包括提供视黄酸、氯甲酸酯、来自半胱氨酸和其烷基酯组成的氨基烷磺酸、半胱氨酸亚磺酸及其烷基酯、同型半胱氨酸及其烷基酯、同型半胱氨酸亚磺酸及其烷基酯、牛磺酸及其衍生物、有机溶剂和一种碱，将所述组分在实质上缺乏氧化物的情况下混合，从而形成包含液相的反应混合物，其中所述液相是一相，且N-视黄酰氨基烷磺酸衍生物在所述液相中形成。

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