3,3'-Methylenebis(2-methylphenol) | 91236-07-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-Methylenebis(2-methylphenol)
• 英文别名: 3-[(3-hydroxy-2-methylphenyl)methyl]-2-methylphenol
• CAS: 91236-07-6
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.29
• InChiKey: VEGUCZXWLYWJFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• PHOSPHORUS-CONTAINING COMPOUND AND CURING EPOXY RESIN COMPOSITION CONTAINING SAME
  申请人：ADEKA CORPORATION

  公开号：US20160200747A1

  公开（公告）日：2016-07-14

  Provided is a novel phosphorus-containing compound represented by general formula (I). The compound has reactivity with a glycidyl group and is therefore capable of providing a curing epoxy resin composition that is expected to achieve flame retardation and reduction of dielectric constant. wherein m is a number of 1 to 10; R 1 , R 2 , R 3 , and R 4 are each hydrogen, alkyl, or aryl; R 5 is alkyl, alkanediyl, alkanetriyl, alkanetetrayl, or an aromatic group; X is oxygen or sulfur; Y is oxygen, sulfur, or ═NR′; and R′ is hydrogen, alkyl, or aryl.

  提供的是一种由通式（I）表示的新型含磷化合物。该化合物与环氧乙烯基团具有反应性，因此能够提供一种预期能够实现阻燃和降低介电常数的固化环氧树脂组合物。其中m为1至10的数字；R1、R2、R3和R4分别为氢、烷基或芳基；R5为烷基、烷二基、烷三基、烷四基或芳基；X为氧或硫；Y为氧、硫或═NR′；R′为氢、烷基或芳基。
• PHOSPHORUS-CONTAINING COMPOUND, AND CURABLE EPOXY RESIN COMPOSITION CONTAINING SAME
  申请人：ADEKA CORPORATION

  公开号：US20160152643A1

  公开（公告）日：2016-06-02

  The purpose of the present invention is to provide a phosphorus-containing compound having reactivity with a glycidyl group, specifically a phosphorus-containing compound represented by general formula (I). (In the formula, m represents a numerical value of 1 to 10; R 1 and R 2 independently represent a hydrogen atom, an alkyl group or an aryl group; R 3 represents an alkyl group, an alkanediyl group, an alkanetriyl group, an alkanetetrayl group or an aromatic group; X represents an oxygen atom or a sulfur atom; Y represents an oxygen atom, a sulfur atom or —NR 4 —; and R 4 represents a hydrogen atom, an alkyl group or an aryl group.)

  本发明的目的是提供一种具有与环氧丙烷基反应性的含磷化合物，特别是一种由通式（I）表示的含磷化合物。（其中，m表示1到10的数值；R1和R2独立地表示氢原子、烷基或芳基；R3表示烷基、烷二基基、烷三基基、烷四基基或芳基；X表示氧原子或硫原子；Y表示氧原子、硫原子或—NR4—；而R4表示氢原子、烷基或芳基。）
• Aqueous resin composition
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP1295857A1

  公开（公告）日：2003-03-26

  An aqueous resin composition comprising a polyepoxy compound represented by formula (I): wherein n represents a number of from 0.1 to 20; Z represents a single bond, an alkylidene group having 1 to 4 carbon atoms or a sulfone group; and X represents a hydrogen atom or a glycidyl group, provided that at least 10% of nX's represent a glycidyl group, and water.

  一种含水树脂组合物，包含由式(I)代表的聚环氧化合物： 其中 n 代表 0.1 至 20 的数字；Z 代表单键、具有 1 至 4 个碳原子的亚烷基或砜基团；X 代表氢原子或缩水甘油基团，条件是至少 10%的 nX 代表缩水甘油基团，以及水。
• ACRYLIC SOL COMPOSITION
  申请人：Asahi Denka Co., Ltd.

  公开号：EP1666531A1

  公开（公告）日：2006-06-07

  An acrylic sol composition comprising (a) acrylic polymer fine particles, (b) blocked polyurethane, (c) a polyamine compound containing at least one modification product derived from a polyether polyamine compound represented by formula (I): wherein X represents a residue of a di- to hexahydric polyol with m hydroxyl groups removed therefrom; A represents an alkylene group having 2 to 4 carbon atoms; B represents an alkylene group having 1 to 4 carbon atoms; m represents a number of 2 to 6; and n represents a number of 0 to 50; a plurality of A's, B's, and n's per molecule may be each the same or different, (d) a plasticizer, and (e) a filler. The composition generates neither hydrogen chloride nor dioxin when incinerated, exhibits high storage stability, cures at relatively low temperatures, and provides a coating film excellent in adhesion to a substrate, cold resistance, and strength.

  一种丙烯酸溶胶组合物，由以下物质组成：(a) 丙烯酸聚合物细颗粒；(b) 嵌段聚氨酯；(c) 多胺化合物，其中至少含有一种由式 (I) 所代表的聚醚多胺化合物衍生的改性产物： 其中 X 代表二水至六水多元醇的残余物，其中已除去 m 个羟基；A 代表具有 2 至 4 个碳原子的亚烷基；B 代表具有 1 至 4 个碳原子的亚烷基；m 代表 2 至 6 的数字；n 代表 0 至 50 的数字；每个分子中的多个 A、B 和 n 可以相同或不同、 (d) 增塑剂，和 (e) 填充剂。这种组合物在焚烧时既不会产生氯化氢，也不会产生二恶英，具有很高的储存稳定性，能在相对较低的温度下固化，并能提供与基材粘附性、耐寒性和强度极佳的涂膜。
• HARDENABLE RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP1900774A1

  公开（公告）日：2008-03-19

  A hardenable resin composition containing a urethane-modified epoxy resin (A), a block urethane (B), and a latent hardener (C). The hardenable resin composition of the present invention is excellent in adhesion to various substrates and provides a hardened product that exhibits flexibility over a wide temperature range from low to high temperatures, so that the hardenable resin composition can be used suitably as a structural adhesive, particularly as a structural adhesive for automobiles.

  一种可硬化树脂组合物，含有聚氨酯改性环氧树脂（A）、嵌段聚氨酯（B）和潜在固化剂（C）。本发明的可硬化树脂组合物对各种基材的粘附性极佳，硬化后的产品在从低温到高温的广泛温度范围内均具有柔韧性，因此可硬化树脂组合物可适当用作结构粘合剂，尤其是汽车结构粘合剂。