9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide | 1259405-60-1

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide
• 英文别名: 6H-dibenzo[1,2] oxaphosphinine-6-sulfide；DOPS；6H-dibenzo[c,e][1,2]oxaphosphinine 6-sulfide；6-sulfido-6H-benzo[c][2,1]benzoxaphosphinin-6-ium
• CAS: 1259405-60-1
• 化学式: C₁₂H₉OPS
• 分子量: 232.243
• InChiKey: DVKXIAKROYARSW-UHFFFAOYSA-N

物化性质

• 沸点：
  403.4±28.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  14.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide 在 氯仿 、 三乙胺 作用下， 以 四氯化碳 为溶剂， 生成 6-chloro-6H-dibenzo[c,e]-[1,2]oxaphosphinine 6-sulfide
  参考文献：
  名称：

  新型硫代磷环分子6H-二苯并[c,e][1,2]氧代膦6-硫化物的合成及反应性

  摘要：

  The new 6H-dibenzo[c,e][1,2]oxaphosphinine 6-sulfide (1) was synthesized and characterized by H-1-, C-13-, P-31-NMR, IR spectroscopy as well as X-ray diffraction and HR-MS. The reactivity of (1) was investigated with a series of test reactions, including Michael-type additions and the Atherton-Todd-reaction and finally compared to that of the parent 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.

  DOI：

  10.3987/com-10-12124
• 作为产物：
  描述：

  10-氯-9,10-二氢-9-氧杂-10-磷杂菲 在 硫化氢 、 sodium hydroxide 作用下， 以 水 、 甲苯 为溶剂， 以89%的产率得到9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide
  参考文献：
  名称：

  新型硫代磷环分子6H-二苯并[c,e][1,2]氧代膦6-硫化物的合成及反应性

  摘要：

  The new 6H-dibenzo[c,e][1,2]oxaphosphinine 6-sulfide (1) was synthesized and characterized by H-1-, C-13-, P-31-NMR, IR spectroscopy as well as X-ray diffraction and HR-MS. The reactivity of (1) was investigated with a series of test reactions, including Michael-type additions and the Atherton-Todd-reaction and finally compared to that of the parent 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.

  DOI：

  10.3987/com-10-12124

文献信息

• 化合物9，10-二氢-9-氧杂-10-磷杂菲-10-硫化物及其制备方法
  申请人：贵州师范大学

  公开号：CN105566395A

  公开（公告）日：2016-05-11

  本发明公开的DOPS其特征在于：其制备方法为：将9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物与五硫化二磷按摩尔比2：1~1.2称量，与有机溶剂一起加入带有冷凝管、搅拌器、温度计和保护气进出口的四口烧瓶中，通入氮气，加入第一份50%五硫化二磷，搅拌升温到55~85℃。反应2~4小时后加入第二份16.8g五硫化二磷，然后温度降到40~55℃反应15~20小时。反应冷却后，真空除去溶剂。在氮气保护下，搅拌下加入100~200ml碳酸氢钠饱和溶液，等二氧化碳释放出来后过滤。收集氯仿层，用无水硫酸纳干燥并过滤。得到的清液浓缩后得到油状物质，干燥后的固体用乙腈重结晶得到产品。产品熔点82℃，产率89~95%。本发明所述阻燃剂制备方法简单，原料价格便宜易得，易于大量生产和制做。产品熔点在81~83℃，常温下易于储存。
• AMMONIUM SALTS OF 9,10-DIHYDRO-10-HYDROXY-9-OXA-10-PHOSPHA-PHENANTHRENE-10-ONE
  申请人：Zich Thomas

  公开号：US20120292582A1

  公开（公告）日：2012-11-22

  The invention relates to ammonium salts of 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-one or -10-oxide (DOPO-OH) of formula I: wherein X is selected from ammonia, melamine, and guanidine, as well as ring-opened hydrolyzates thereof according to the following formula II: wherein X is defined as above.

  该发明涉及公式I的9,10-二氢-10-羟基-9-氧杂-10-磷酸菲-10-酮或-10-氧化物（DOPO-OH）的铵盐，其中X选自氨、三聚氰胺和胍，以及根据以下公式II的开环水解物：其中X定义如上。
• Synthesis of new organophosphorus compounds using the atherton-todd reaction as a versatile tool
  作者：Sebastian Wagner、Muriel Rakotomalala、Yana Bykov、Olaf Walter、Manfred Döring

  DOI：10.1002/hc.21006

  日期：——

  molecules are important and versatile compounds, for a broad field of applications, novel synthetic approaches are of interest to both academia and industry. As an example, the single-step synthesis of the bridged 1,3-phenylene bis(diphenylphosphinate) with potential flame-retardant properties was added to this study. In addition, the reaction is utilized for the synthesis of a novel organophosphorus

  本文讨论了七种有机磷化合物在 Atherton-Todd 条件下的行为。因此，系统研究了不同（苯）氧杂膦、二氧杂膦、二氧杂膦和二苯基氧化膦与三种亲核试剂的反应性和选择性。结果证明了 Atherton-Todd 反应对具有不同磷环境和反应性 PH 键的各种有机磷化合物的多功能性。本文研究的亲核试剂被选为胺类和醇类的模型底物。由于有机磷分子是重要且用途广泛的化合物，因此对于广泛的应用领域，学术界和工业界都对新的合成方法感兴趣。例如，桥接 1 的单步合成，具有潜在阻燃性能的 3-亚苯基双（二苯基次膦酸盐）被添加到该研究中。此外，该反应还用于合成新型有机磷酐。© 2012 Wiley Periodicals, Inc. 杂原子化学 23:216–222, 2012; 在 wileyonlinelibrary.com 上在线查看这篇文章。DOI 10.1002/hc.21006
• 一种磷杂菲衍生物阻燃剂及其制备方法
  申请人：贵州民族大学

  公开号：CN113105506A

  公开（公告）日：2021-07-13

  本发明提供了一种磷杂菲衍生物阻燃剂及其制备方法，所述磷杂菲衍生物阻燃剂的化学结构式为：本发明的磷杂菲衍生物阻燃剂在DOPO结构中引入硫元素，增进了磷的阻燃效果，提高了其凝聚相阻燃能力，MAH‑DOPS阻燃效果好，且不含卤素，有利于环保。
• Flameproof expandable polymerizates
  申请人：Eberstaller Roman

  公开号：US20120184635A1

  公开（公告）日：2012-07-19

  The invention relates to flameproof expandable polymers containing at least one blowing agent, wherein at least one phosphorus compound is contained as a flame retardant. Novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene derivatives, namely 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione ammonium salt, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-ei-hydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione melaminium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione guanidinium salt, bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthrene-10-yl)sulfide, 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-ylthio)-9-oxa-10-phosphaphenanthrene-10-one, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)sulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)disulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)tetrasulfide, di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)ether and/or 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yloxy)-9-oxa-10-phosphaphenanthrene-10-one, or ring-opened hydrolyzates thereof, are provided as flame retardants.

  本发明涉及至少含有一种发泡剂的阻燃膨胀聚合物，其中至少含有一种磷化合物作为阻燃剂。提供了新型的9,10-二氢-9-氧-10-磷杂菲衍生物，包括9,10-二氢-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮铵盐，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三聚氰胺盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮胍盐，双(9,10-二氢-9-氧-10-氧-10-磷杂菲-10-基)硫化物，9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基硫基)-9-氧-10-磷杂菲-10-酮，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)二硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)四硫化物，二(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)醚和/或9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-氧基)-9-氧-10-磷杂菲-10-酮及其开环水解物作为阻燃剂。