benzyltrimethylphosphonium iodide | 36678-77-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyltrimethylphosphonium iodide
• 英文别名: benzyl-trimethyl-phosphonium; iodide；Benzyl-trimethyl-phosphonium; Jodid；Benzyl(trimethyl)phosphanium;iodide
• CAS: 36678-77-0
• 化学式: C₁₀H₁₆P*I
• 分子量: 294.115
• InChiKey: HVJCQQVEQFABIA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-氰基呋喃 、 benzyltrimethylphosphonium iodide 在 双(三甲基硅烷基)氨基钾 作用下， 以 甲苯 为溶剂， 反应 28.0h， 生成 1,1,1-trimethyl-4-phenyl-3-(2-furyl)-2-aza-1,λ⁵-phosphabuta-1,3-diene
  参考文献：
  名称：

  炔酸酯与N-官能化的磷腈的反应。N-乙烯基磷腈的1,2-vs 1,4-加成。

  摘要：

  衍生自氨基膦酸酯的磷腈与炔属酯的反应导致共轭磷酰化。通过磷腈的P = N键（1,2-加成）和炔属酯的三键的[2 + 2]环加成反应，然后再进行氮杂磷中间体的开环，可以解释这些稳定化亚烷基的形成。然而，在N-乙烯基磷腈的情况下，衍生自三苯基膦和三甲基膦的磷腈与二乙炔酸酯反应为烯胺（1,4-加成），而在衍生自三甲基膦的磷腈中，丙酸乙酯1,2-加成产生磷腈的P ＝ N键。

  DOI：

  10.1039/b212693a
• 作为产物：
  描述：

  苄基(二甲基)膦 、 碘甲烷 生成 benzyltrimethylphosphonium iodide
  参考文献：
  名称：

  Jerchel, Chemische Berichte, 1943, vol. 76, p. 600,606

  摘要：

  DOI：

文献信息

• Method for production of 3-cyano-3,5,5-trimethyl cyclohexanone
  申请人：NIPPOH CHEMICALS CO., LTD.

  公开号：EP0502707A1

  公开（公告）日：1992-09-09

  A method for the production of 3-cyano-3,5,5-trimethyl cyclohexanone by the reaction of isophorone with hydrogen cyanide in the presence of a quaternary ammonium salt or quaternary phosphonium salt and a basic compound as a catalyst in a form dissolved or dispersed in water or in the absence of water, which method comprises effecting said reaction by using said quaternary ammonium salt or quaternary phosphonium salt in an amount in the range of from 0.001 to 0.1 mol per mol of isophorone and said basic compound and in an amount in the range of from 0.5 to 3.0 mols per mol of said quaternary ammonium salt or quaternary phosphonium salt and, when water is used, using water in an amount in the range of 0.1 to 25% by weight based on the amount of isophorone, and employing hydrogen cyanidehydrocyanic acid at a ratio in the range of from 0.6 to 1.0 mol per mol of isophorone at a temperature in the range of from 90° to 140°C.

  一种通过异佛尔酮与氰化氢在季铵盐或季鏻盐以及作为催化剂的碱性化合物存在下以溶解或分散于水的形式或在无水的情况下反应生产 3-氰基-3,5,5-三甲基环己酮的方法，该方法包括通过使用所述季铵盐或季鏻盐以每摩尔异佛尔酮 0.001 至 0.1 摩尔的量和所述碱性化合物以每摩尔所述季铵盐或季鏻盐 0.5 至 3.0 摩尔的量进行所述反应。1摩尔/摩尔的异佛尔酮和所述碱性化合物，以及0.5至3.0摩尔/摩尔的所述季铵盐或季鏻盐，当使用水时，使用0.当使用水时，以异佛尔酮的量为基准，水的用量为 0.1 至 25% (重量)，氰化氢氰酸的用量为 0.6 至 1.0 摩尔/摩尔异佛尔酮，温度为 90° 至 140°C。
• Pigment dispersant
  申请人：Ajinomoto Co., Ltd.

  公开号：EP0768321A2

  公开（公告）日：1997-04-16

  Provided is a pigment-dispersible compound (pigment dispersant) which exhibits an excellent compatibility with a wide variety of resins and an excellent pigment dispersibility. Means For Solution A pigment-dispersible polyallylamine derivative represented by formula (I), and a pigment dispersant containing the same as an active ingredient.    wherein R1 represents a residue in which a free amino group or an amino group of a polyallylamine is bound to a polyester, a polyamide or a copolycondensate of an ester and an amide by covalent bond (acid amide bond) formation or by salt (primary ammonium salt) formation through terminal carboxyl groups thereof, and at least one of an n-number of R1's is a residue that has the covalent bond, n represents an integer of from 2 to 1,000, and X and Y, independently from each other, represent hydrogen, a polymerization initiator residue or a chain transfer catalyst residue.

  本发明提供了一种颜料分散性化合物（颜料分散剂），它与多种树脂具有良好的相容性，并具有优异的颜料分散性。 解决方案 一种由式（I）表示的可分散颜料的聚烯丙基胺衍生物，以及一种以其为活性成分的颜料分散剂。 其中 R1 代表一种残基，其中聚烯烃胺的游离氨基或氨基通过共价键（酸酰胺键）形成或通过其末端羧基形成的盐（伯铵盐）与聚酯、聚酰胺或酯和酰胺的共缩聚物结合，且 n 个 R1 中至少有一个是具有共价键的残基、 n 代表 2 到 1000 的整数，以及 X 和 Y 各自代表氢、聚合引发剂残基或链转移催化剂残基。
• Thermoplastic resin composition, agent for improving thermal aging resistance of thermoplastic resin, and resin molded article obtained therefrom
  申请人：Ajinomoto Co., Inc.

  公开号：EP0908491A2

  公开（公告）日：1999-04-14

  A thermoplastic resin composition comprising a thermoplastic resin and at least one of a polyglycerin derivative in which at least one hydroxyl group of a polyglycerin molecule is esterified with a fatty acid, an N-acyl basic amino acid and a dibasic acid erythritol ester, and : i) in using said polyglycerin derivative, further comprising an antioxidant, or further comprising an antioxidant and a filler; ii) in using said N-acyl basic amino acid, further comprising a filler and wherein said thermoplastic resin contains at least one type selected from the group consisting of a polyolefin resin, a polystyrene resin, a polyester resin, a polyamide resin and an engineering plastic; and iii) in using said dibasic acid erythritol ester, further comprising a filler, and wherein said thermoplastic resin contains at least one type selected from the group consisting of a polyolefin resin, a polystyrene resin, a polyester resin, a polyamide resin and an engineering plastic, and the amount of said dibasic acid erythritol ester is less than 1 part by weight per 100 parts by weight of the thermoplastic resin, and said ester includes an ester having a degree of esterification of not more than 50% is provided. Thus obtained thermoplastic resin composition is excellent in improving a thermal aging resistance for the resin when a thermoplastic resin is molded, and the additives for the thermoplastic resin composition are also provided.

  一种热塑性树脂组合物，包括热塑性树脂和聚甘油衍生物中的至少一种，其中聚甘油分子的至少一个羟基与脂肪酸、N-酰基碱性氨基酸和二元酸赤藓醇酯酯化，以及： i) 在使用所述聚甘油衍生物时，进一步包含抗氧化剂，或进一步包含抗氧化剂和填充剂； ii) 在使用所述 N-酰基碱性氨基酸时，进一步包含一种填料，其中所述热塑性树脂包含至少一种选自聚烯烃树脂、聚苯乙烯树脂、聚酯树脂、聚酰胺树脂和工程塑料的类型；以及 iii) 在使用所述二盐基酸赤藓糖醇酯时，进一步包括填料，其中所述热塑性树脂包含至少一种选自聚烯烃树脂、聚苯乙烯树脂、聚酯树脂、聚酰胺树脂和工程塑料组成的组的类型，且所述二盐基酸赤藓糖醇酯的用量少于每 100 份热塑性树脂重量的 1 份，且所述酯包括酯化度不超过 50%的酯。 由此获得的热塑性树脂组合物在热塑性树脂模塑时能很好地改善树脂的耐热老化性，同时还提供了热塑性树脂组合物的添加剂。
• NONAQUEOUS INK JET INK, PROCESS FOR PRODUCING NONAQUEOUS INK JET INK, AND INK JET RECORDING METHOD
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2261290A1

  公开（公告）日：2010-12-15

  Disclosed is a nonaqueous ink jet ink that is suitable for printing (scratch resistance and resistance to alcohol wiping) on recording media of plastics such as polyvinyl chloride, is highly safe, can be used without posing any problem of odor, has excellent properties of ink ejection from an ink jet head, and can realize a good printed image quality. Also disclosed are a process for producing a nonaqueous ink jet ink and an ink jet recording method using the nonaqueous ink jet ink. The process for producing a nonaqueous inkjet ink is a process for producing a nonaqueous ink jet ink containing at least an organic solvent, a pigment, and a fixing resin. The process is characterized in that the fixing resin satisfies a b/a value of not more than 0.020 wherein a represents the total of integrated values of areas of all of peaks derived from the fixing resin among all of peaks detected in a proton nuclear magnetic resonance analysis; and b represents the total of integrated values of areas of all of peaks derived from the compounds other than the fixing resin.

  本发明公开了一种非水性喷墨墨水，该墨水适用于在聚氯乙烯等塑料记录介质上进行打印（耐刮擦和耐酒精擦拭），安全性高，使用时不会产生异味，具有从喷墨头喷出墨水的优异性能，可实现良好的打印图像质量。此外，还公开了一种生产非水性喷墨墨水的工艺和一种使用非水性喷墨墨水的喷墨记录方法。生产非水性喷墨墨水的工艺是一种生产非水性喷墨墨水的工艺，该墨水至少含有一种有机溶剂、一种颜料和一种固色树脂。该工艺的特征在于，固色树脂的 b/a 值不大于 0.020，其中 a 代表质子核磁共振分析中检测到的所有峰中由固色树脂产生的所有峰的面积的综合值的总和；b 代表由固色树脂以外的化合物产生的所有峰的面积的综合值的总和。
• DENATURED POLYAMINE
  申请人：Ajinomoto Co., Inc.

  公开号：EP2594599A1

  公开（公告）日：2013-05-22

  Provided is a pigment dispersant which includes a modified polyamine produced by a reaction of a polyamine having two or more primary and/or secondary amino groups per molecule and containing 2 to 1800 nitrogen atoms per molecule, a polyester, and a phosphorus-containing compound, and therefore exhibits excellent pigment dispersion performance, shows little change in color tone by heating, and has excellent heat resistance.

  本发明提供了一种颜料分散剂，其中包括一种改性多胺，该改性多胺是由每分子具有两个或两个以上伯氨基和/或仲氨基且每分子含有 2 至 1800 个氮原子的多胺、聚酯和含磷化合物反应生成的，因此该颜料分散剂具有优异的颜料分散性能，加热后色调几乎不会发生变化，并且具有优异的耐热性。