1-Propyl-1,2-dihydropyridine | 920008-19-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-Propyl-1,2-dihydropyridine
• 英文别名: 1-propyl-2H-pyridine
• CAS: 920008-19-1
• 化学式: C₈H₁₃N
• 分子量: 123.2
• InChiKey: BFEHJRCAUOMQSD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for producing optically active secondary alcohol
  申请人：Kanto Kagaku Kabushiki Kaisha

  公开号：EP2865446A1

  公开（公告）日：2015-04-29

  The object of this invention is to provide a method for producing an optically active secondary alcohol at a high optical purity by hydrogenating a substrate carbonyl compound at a high efficiency using as a catalyst a ruthenium complex bearing as a ligand certain optically active diphosphine compound and a readily synthesized amine compound. The method of producing an optically active secondary alcohol according to the present invention is characterized in that a substrate carbonyl compound (provided that 3-quinuclidinone, 3-quinuclidinone derivative having a substituent, and a ketone having an aromatic hydrocarbon group and a heterocycle are excluded) is reacted with hydrogen and/or a hydrogen donating compound in the presence of a ruthenium complex selected from the compounds expressed by following general formula (1) RuXYAB (1) [in the general formula (1), X and Y are the same or different from each other and denote a hydrogen atom or an anionic group, A denotes an optically active diphosphine expressed by the general formula (2), B denotes an amine compound expressed by following general formula (3)].

  本发明的目的是提供一种高光学纯度的光学活性仲醇的制取方法，该方法是以某种光学活性二膦化合物和易于合成的胺化合物为配体的钌络合物为催化剂，通过高效率地氢化底物羰基化合物来制取光学活性仲醇。 根据本发明的生产光学活性仲醇的方法，其特征在于底物羰基化合物(但不包括3-奎宁环酮、具有取代基的3-奎宁环酮衍生物和具有芳香烃基和杂环的酮)在选自通式(1)RuXYAB(1)的化合物的钌络合物存在下与氢和/或氢捐赠化合物反应[在通式(1)中、X 和 Y 彼此相同或不同，表示氢原子或阴离子基团，A 表示通式 (2) 所表示的光学活性二膦，B 表示通式 (3) 所表示的胺化合物]。
• FLOORING SYSTEM INCLUDING A DRY GLUE
  申请人：Pergo (Europe) AB

  公开号：EP1917317A2

  公开（公告）日：2008-05-07
• ATOM TRANSFER RADICAL POLYMERIZATION UNDER BIOLOGICALLY COMPATIBLE CONDITIONS
  申请人：Carnegie Mellon University

  公开号：EP2747753A1

  公开（公告）日：2014-07-02
• PROCESS FOR PRODUCING OPTICALLY ACTIVE SECONDARY ALCOHOL
  申请人：Kanto Kagaku Kabushiki Kaisha

  公开号：EP2865446B1

  公开（公告）日：2021-09-22
• Encapsulated structural adhesive
  申请人：Yan Nianxi

  公开号：US20070021533A1

  公开（公告）日：2007-01-25

  The invention teaches an encapsulated curable adhesive composition especially adapted for use as a structural adhesive. The adhesive composition enables formation of a thin layer reactive composition of microcapsules and a two-part curative. The adhesive composition comprises a first population of microcapsules encasing a monomer and a first-part curative comprising an initiator. The adhesive composition further comprises a second-part curative. The second-part curative comprises an activator and a catalyst. At least the activator of the second-part curative is preferably encapsulated in a second population of microcapsules. The catalyst and the second population of microcapsules can be dispersed in a binder material, along with the first population of microcapsules. The first population of microcapsules contain encapsulated within the core a monomer having a Tg 35° C. or less and the first-part curative. The first population microcapsules contain encapsulated within the core a monomer having a Tg 35° C. or less along with the first-part curative. The encapsulated monomer and first-part curative constitute a blend which is a free flowing liquid having a viscosity of less than 500 Cp (milliPascal-second), and more preferably less than 10 Cp (milliPascal-second). The first population of microcapsules with first-part curative, and a second-part curative and second population of microcapsules are dispersed in a binder material. Reactive contact of the monomer and first-part curative with the second-part curative is affected by exuding the respective capsule contents into reactive contact through breakage of the microcapsules such as an interference fit of the substrate or substrates to which the composition is applied.