(E)-3-phenyl-N-propylprop-2-en-1-amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-3-phenyl-N-propylprop-2-en-1-amine
• 英文别名: (3-Phenyl-2-propen-1-YL)propylamine
• 化学式: C₁₂H₁₇N
• 分子量: 175.274
• InChiKey: XVODXZBINOXIOP-RMKNXTFCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正丙胺 、 烯丙苯 在 三氟甲磺酸酐 、 二苯基亚砜 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以86%的产率得到
  参考文献：
  名称：

  硫介导的烯烃烯丙基CH胺化反应中的反马尔科夫尼科夫重排

  摘要：

  迄今尚未发现涉及从次级碳正离子向初级碳正离子或初级三氟甲磺酸酯的反马尔科夫尼科夫重排的未知化学。

  DOI：

  10.1039/c6cc05128f

文献信息

• PROCESS FOR PRODUCING POLYMER WITH FUNCTIONAL END
  申请人：KURARAY CO., LTD.

  公开号：EP1721912A1

  公开（公告）日：2006-11-15

  An organolithium compound represented by the following general formula (i): (i) [wherein A represents a heteroatom selected among oxygen, nitrogen, sulfur, and phosphorus; Ar represents optionally substituted aryl; R1 represents C1-10 alkyl; R2 represents C1-10 alkylene; R3 represents C1-10 alkyl or a protective group for the functional group -A-H (A is a heteroatom); and when the heteroatom A is oxygen or sulfur, then m and n each is 0 or 1, provided that the sum of m and n is 1, and when the heteroatom A is nitrogen or phosphorus, then m and n each is 0, 1, or 2, provided that the sum of m and n is 2], which has not hitherto been used in anionic polymerization, is used as an anionic polymerization initiator to easily and smoothly produce a polymer having a functional group at an end.

  由以下通式(i)代表的有机锂化合物：(i) [其中 A 代表选自氧、氮、硫和磷的杂原子；Ar 代表任选取代的芳基；R1 代表 C1-10 烷基；R2 代表 C1-10 亚烷基；R3 代表 C1-10 烷基或官能团 -A-H 的保护基（A 为杂原子）；当杂原子 A 为氧或硫时，则 m 和 n 各为 0 或 1，条件是 m 和 n 之和为 1；当杂原子 A 为氮或磷时，则 m 和 n 各为 0、1 或 2，条件是 m 和 n 之和为 2]，迄今尚未用于阴离子聚合，用作阴离子聚合引发剂，可轻松顺利地生成末端具有官能团的聚合物。
• BLOCKED ISOCYANATE SILICONE RESINS
  申请人：Dow Corning Corporation

  公开号：EP2102286A1

  公开（公告）日：2009-09-23
• Process for producing polymer with functional end
  申请人：Satoh Kotaro

  公开号：US20070167587A1

  公开（公告）日：2007-07-19

  An organolithium compound represented by the following general formula (i): (i) [wherein A represents a heteroatom selected among oxygen, nitrogen, sulfur, and phosphorus; Ar represents optionally substituted aryl; R 1 represents C 1-10 alkyl; R 2 represents C 1-10 alkylene; R 3 represents C 1-10 alkyl or a protective group for the functional group -A-H (A is the heteroatom); and when the heteroatom A is oxygen or sulfur, then m and n each is 0 or 1, provided that the sum of m and n is 1, and when the heteroatom A is nitrogen or phosphorus, then m and n each is 0, 1, or 2, provided that the sum of m and n is 2], which has not hitherto been used in anionic polymerization, is used as an anionic polymerization initiator to easily and smoothly produce a polymer having a functional group at an end.
• Blocked-Isocyanate Silicone Resins
  申请人：Horstman John Bernard

  公开号：US20100093902A1

  公开（公告）日：2010-04-15

  This invention relates to new blocked isocyanate silicone resins which can be used to make shelf stable one part curable coating compositions. These coatings do not cure until heated. The coatings provide weather resistant protection for numerous substrates including automobile exteriors, leather fabric, electronic components, wood floors and surfaces.
• US4473630A
  申请人：——

  公开号：US4473630A

  公开（公告）日：1984-09-25