2,6-Ditert-butyl-4-(4-methoxyphenyl)aniline | 86385-58-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-Ditert-butyl-4-(4-methoxyphenyl)aniline
• CAS: 86385-58-2
• 化学式: C₂₁H₂₉NO
• 分子量: 311.467
• InChiKey: GSZJAIGOSCJGPY-UHFFFAOYSA-N

物化性质

• 沸点：
  411.1±45.0 °C(Predicted)
• 密度：
  0.990±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-Ditert-butyl-4-(4-methoxyphenyl)aniline 在 2,6-二甲基吡啶 、 水 作用下， 以 乙腈 为溶剂， 生成 2,6-di-tert-butyl-4-hydroxy-4-(4-methoxyphenyl)-2,5-cyclohexadien-1-imine
  参考文献：
  名称：

  Electrochemistry of anilines. 6. Reactions of electrogenerated biphenylylnitrenium ions

  摘要：

  3,5-Di-tert-butyl-substituted biphenyl-4-ylnitrenium ions are generated by anodic oxidation of the corresponding biphenylylamines in acetonitrile in the presence of a base. The reactions of these species with several nucleophiles are studied. The principal reaction sites are identified as the positions ortho and para to the = NH moiety. No reactions at the iminium nitrogen and in the second ring of the biphenyl system are observed. Products are characterized by spectroscopic techniques. Some common spectroscopic features of the iminoquinolide reaction products are discussed.

  DOI：

  10.1021/jo00015a019

文献信息

• Co(salen) catalyzed oxidation of 2,4,6-trisubstituted anilines with tert-butylhydroperoxide
  作者：Akira Nishinaga、Stefan Fo¨rster、Emerich Eichhorn、Bernd Speiser、Anton Rieker

  DOI：10.1016/s0040-4039(00)60100-4

  日期：1992.7

  Co(salen) catalyzed oxidation of 2,4,6-trisubstituted (preferentially 2,6-di-tert-butylated) anilines with tert-butylhydroperoxide gives 4-tert-butylperoxy-2,5-cyclohexadien-1-imine and nitrobenzene derivatives. The relative ratio of the products depends on the nature of the substituents in the substrate.