2H,5H-dodecafluoro-hexane | 71040-07-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 2H,5H-dodecafluoro-hexane
• 英文别名: 1,1,1,2,3,3,4,4,5,6,6,6-Dodecafluorohexane
• CAS: 71040-07-8
• 化学式: C₆H₂F₁₂
• 分子量: 302.063
• InChiKey: JAUHXPGMVMGJTB-UHFFFAOYSA-N

物化性质

• 沸点：
  84.5±8.0 °C(Predicted)
• 密度：
  1.557±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  三氟乙烯 、 三氟乙酸 在 水 、 sodium carbonate 、 乙腈 作用下， 生成 2H,5H-dodecafluoro-hexane
  参考文献：
  名称：

  Anode fluoroalkylation of fluoroolefins

  摘要：

  DOI：

  10.1007/bf00963312

文献信息

• DISPERSION OF ION-EXCHANGE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP1535950A1

  公开（公告）日：2005-06-01

  A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25°C at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.

  一种增稠的离子交换聚合物分散体是通过对均匀分散在分散介质中的具有磺酸基团的氟化聚合物作为离子交换聚合物的离子交换聚合物分散体施加超声波振动或剪切力，使其在 25°C、剪切速率为 10 (1/s) 时的粘度在增稠步骤中增加 2-2000 倍而得到的。当形成一层膜时，分散体可以形成一层离子交换膜，该膜厚度均匀，厚度小，强度高，在水和蒸汽中不会开裂并显示出恒定的膨胀性。此外，将含有该分散液和由催化剂金属颗粒组成的催化剂粉末以及装有催化剂金属颗粒的碳载体的涂层溶液涂在基底上形成的层，可用于制备膜电极组件，作为阴极和阳极中至少一个的催化剂层，方法是将该催化剂层提供给离子交换膜。由于催化剂层强度高、缺陷少且非常光滑，因此可获得用于固体聚合物电解质燃料电池的高性能膜电极组件。
• POLYMER FILM, PROCESS FOR PRODUCING THE SAME, AND UNITED MEMBRANE ELECTRODE ASSEMBLY FOR SOLID POLYMER TYPE FUEL CELL
  申请人：Asahi Glass Company, Limited

  公开号：EP1541619A1

  公开（公告）日：2005-06-15

  The present invention provides a polymer membrane mainly made of an ion exchange resin which further comprises melt-spun fluororesin fibers such as fibers made of an ethylene-tetrafluoroethylene copolymer, a polyvinylidene fluoride or the like, having fiber diameters of from 0.01 to 20 µm, fiber lengths of from 1 µm to 10 mm and aspect ratios of at least 5 in an amount of from 1 to 40% based on the total mass. The polymer membrane is excellent in handleability and shows excellent dimensional stability when hydrated, and therefore a polymer electrolyte fuel cell provided with a membrane-electrode assembly having the polymer membrane as an electrolyte membrane has great durability.

  本发明提供了一种主要由离子交换树脂制成的聚合物膜，该膜进一步包含熔融纺丝氟树脂纤维，例如由乙烯-四氟乙烯共聚物、聚偏氟乙烯或类似物制成的纤维，纤维直径为 0.01 至 20 微米，纤维长度为 1 微米至 10 毫米，纵横比至少为 5，含量为总质量的 1 至 40%。这种聚合物膜具有极佳的可操作性，在水合时显示出极佳的尺寸稳定性，因此，使用这种聚合物膜作为电解质膜的膜电极组件的聚合物电解质燃料电池具有极高的耐用性。
• SOLID POLYMER ELECTROLYTE MEMBRANE AND MEMBRANE ELECTRODE ASSEMBLY FOR SOLID POLYMER FUEL CELL
  申请人：Asahi Glass Company, Limited

  公开号：EP2104170A1

  公开（公告）日：2009-09-23

  A membrane/electrode assembly for a polymer electrolyte fuel cell capable of exhibiting high power generation performance constantly for a long period of time in a high temperature and low humidity environment, and a polymer electrolyte membrane whereby such a membrane/electrode assembly is obtainable. A polymer electrode membrane 15, comprising a proton conductive polymer which has an electrical conductivity of at least 0.07 S/cm at a temperature of 80°C at a relative humidity of 40% and which has a water content of less than 15 mass; and a membrane/electrode assembly 10 comprising an anode 13 and a cathode 14 each having a catalyst layer 11, and a polymer electrolyte membrane 15 disposed between the anode 13 and the cathode 14.

  一种用于聚合物电解质燃料电池的膜/电极组件，该组件能够在高温低湿环境中长期持续显示高发电性能，以及一种聚合物电解质膜，通过该膜/电极组件可获得这种膜。 一种聚合物电极膜 15，由质子导电聚合物组成，该聚合物在相对湿度为 40% 的 80°C 温度条件下，导电率至少为 0.07 S/cm，且含水量小于 15 质量；以及一种膜/电极组件 10，包括阳极 13 和阴极 14，每个阳极 13 和阴极 14 均具有催化剂层 11，以及设置在阳极 13 和阴极 14 之间的聚合物电解质膜 15。
• FLUORINE-CONTAINING ION EXCHANGE RESIN DISPERSED COMPOSITION
  申请人：Asahi Kasei E-materials Corporation

  公开号：EP2264085A1

  公开（公告）日：2010-12-22

  Problems to be Solved There is provided a dispersion composition of fluorine-containing ion exchange resin, which has an extremely low solution viscosity even in a case in which the concentration of a fluorine-containing ion exchange resin is increased by a concentration operation in a liquid composition in which the fluorine-containing ion exchange resin is dispersed. Solution A dispersion composition of fluorine-containing ion exchange resin, which comprises a fluorine-containing ion exchange resin having a repeating unit represented by the following formulae (1) and (2) and having an equivalent weight of 400 to 1000 g/eq, and a solvent containing water,         -(CFZCFZ)-     (1) wherein Z represents H, Cl, F, or a perfluoroalkyl group containing 1 to 3 carbon atoms; m represents an integer of 0 to 12; and n represents an integer of 0 to 2, and wherein an abundance ratio of a resin having a particle size of 10 µm or more in the fluorine-containing ion exchange resin is 0.1% to 80% by volume.

  有待解决的问题 本发明提供了一种含氟离子交换树脂的分散组合物，即使在含氟离子交换树脂分散于其中的液体组合物中通过浓缩操作提高含氟离子交换树脂浓度的情况下，该组合物的溶液粘度也极低。 解决方案 一种含氟离子交换树脂的分散组合物，它由具有下式（1）和（2）所代表的重复单元且当量重量为 400 至 1000 克/当量的含氟离子交换树脂和含水的溶剂组成、 -(CFZCFZ)- (1) 其中 Z 代表 H、Cl、F 或含有 1 至 3 个碳原子的全氟烷基；m 代表 0 至 12 的整数；n 代表 0 至 2 的整数，以及 含氟离子交换树脂中粒径大于或等于 10 微米的树脂的丰度比为 0.1%至 80%（体积比）。
• METHOD FOR PRODUCING LIQUID COMPOSITION, METHOD FOR PRODUCING COATING LIQUID FOR FORMING CATALYST LAYER, AND METHOD FOR PRODUCING MEMBRANE ELECTRODE ASSEMBLY
  申请人：Asahi Glass Company, Limited

  公开号：EP3339369A1

  公开（公告）日：2018-06-27

  To provide a method for producing a liquid composition or a coating liquid for forming a catalyst layer, which can make cracking less likely to occur at the time of forming a solid polymer electrolyte membrane or a catalyst layer; and a method for producing a membrane electrode assembly, which can make cracking less likely to occur at the time of forming the catalyst layer or the solid polymer electrolyte membrane. This liquid composition is prepared by dispersing in a medium containing water and a hydrocarbon-type alcohol a polymer (x) having a structural unit having a ring structure and a structural unit having an ion exchange group, or a polymer (y) having either one or both of a structural unit having two ion-exchange groups in a pendant group and a structural unit having one ion exchange group in a short-chain pendant group, to prepare a dispersion in which the concentration of the polymer (x) or the polymer (y) is from 10 to 26 mass%, and mixing the dispersion and a fluorinated solvent so that the sum of the concentration of the polymer (x) or the polymer (y) and the concentration of the fluorinated solvent becomes to be from 12 to 35 mass%.

  提供一种生产用于形成催化剂层的液体组合物或涂覆液的方法，该方法可在形成固体聚合物电解质膜或催化剂层时减少裂纹的发生；以及一种生产膜电极组件的方法，该方法可在形成催化剂层或固体聚合物电解质膜时减少裂纹的发生。这种液体组合物的制备方法是：将具有环状结构的结构单元和具有离子交换基团的结构单元的聚合物 (x) 或具有在一个悬垂基团中具有两个离子交换基团的结构单元和在一个短链悬垂基团中具有一个离子交换基团的结构单元中的一个或两个的聚合物 (y) 分散在含有水和烃类醇的介质中、制备聚合物 (x) 或聚合物 (y) 浓度为 10 至 26 质量％的分散液，并将分散液与含氟溶剂混合，使聚合物 (x) 或聚合物 (y) 浓度与含氟溶剂浓度之和达到 12 至 35 质量％。