(4-chloro-2-methyl-phenyl)-trichloromethyl sulfone | 68961-44-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-chloro-2-methyl-phenyl)-trichloromethyl sulfone
• 英文别名: (4-Chlor-2-methyl-phenyl)-trichlormethyl-sulfon；4-Chloro-2-methyl-1-(trichloromethanesulfonyl)benzene；4-chloro-2-methyl-1-(trichloromethylsulfonyl)benzene
• CAS: 68961-44-4
• 化学式: C₈H₆Cl₄O₂S
• 分子量: 308.012
• InChiKey: SUSQFNPQGIKDBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium hypochlorite 作用下， 生成 (4-chloro-2-methyl-phenyl)-trichloromethyl sulfone
  参考文献：
  名称：

  103.三氯甲基砜及相关化合物

  摘要：

  DOI：

  10.1039/jr9560000508

文献信息

• Photocurable paint composition for road markings
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0915136A1

  公开（公告）日：1999-05-12

  A photocurable paint composition for road markings is disclosed, comprising (A) a compound having an ethylenically unsaturated group, (B) a filler, (C) a cationic dye represented by formula (1):         D+·A1-     (1) (wherein D+ represents a cation having an absorption maximum wavelength in the wavelength region of from 400 to 1,200 nm, and A1- represents an optional anion), (D) a quaternary organic borate-type sensitizer represented by formula (2): (wherein R1, R2, R3 and R4 each independently represents an alkyl group, an aryl group, an aralkyl group, an alkenyl group, an alkynyl group, a silyl group, a heterocyclic group or a halogen atom, and Z+ represents an optional cation) and (E) an ultraviolet radical polymerization initiator capable of generating a radical upon absorption of light at a wavelength of 400 nm or less, or additionally comprising (F) glass beads.

  本发明公开了一种用于道路标线的光固化涂料组合物，它包括 (A) 具有乙烯不饱和基团的化合物；(B) 填料；(C) 由式 (1) 表示的阳离子染料： D+-A1- (1) (其中 D+ 代表一种阳离子，其吸收最大波长在 400 至 1 200 nm 的波长范围内，A1- 代表一种任选阴离子），（D）由式（2）代表的季硼酸有机敏化剂： (其中 R1、R2、R3 和 R4 各自独立地代表烷基、芳基、芳烷基、烯基、炔基、硅基、杂环基或卤素原子，Z+ 代表任选阳离子）和 (E) 紫外自由基聚合引发剂，能够在吸收波长为 400 纳米或以下的光时产生自由基，或另外包括 (F) 玻璃珠。
• Photocurable composition
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP1002817A2

  公开（公告）日：2000-05-24

  A photocurable composition comprising (A) 100 parts by weight of a compound having an ethylenically unsaturated group, (B) from 0.001 to 5 parts by weight of a cationic dye having an absorption maximum wavelength in the wavelength region of from 400 to 1,200 nm represented by formula (1):D+·A1 - wherein D+ represents a cation having an absorption maximum wavelength in the wavelength region of from 400 to 1,200 nm, and A1- represents an anion, and (C) from 0.005 to 10 parts by weight of a quaternary borate-type compound represented by formula (2): wherein R1, R2, R3 and R4 each independently represents an alkyl group, an aryl group, an aralkyl group, an alkenyl group, an alkynyl group, a silyl group, a heterocyclic group or a halogen atom, and Z+ represents a cation, wherein from 5 to 95 wt% of (A) the compound having an ethylenically unsaturated group is a urethane (meth)acrylate oligomer obtained by the reaction of a polyisocyanate having three or more isocyanate groups within one molecule with a hydroxyl group-containing (meth)acrylic acid ester.

  一种光固化组合物，包括(A)100 重量份具有乙烯不饱和基团的化合物，(B)0.001至5份(重量)的阳离子染料，其吸收最大波长为400至1,200纳米，由式(1)表示：D+-A1- 其中D+代表阳离子，其吸收最大波长为400至1,200纳米，A1-代表阴离子，和(C)0.005至10份(重量)的季硼酸酯类化合物，由式(2)表示： 其中 R1、R2、R3 和 R4 各自独立地代表烷基、芳基、芳烷基、烯基、炔基、硅 基、杂环基或卤素原子，Z+ 代表阳离子、其中(A)具有乙烯基不饱和基团的化合物的 5 至 95 wt%为聚氨酯（甲基）丙烯酸酯低聚物，该低聚物是由在一个分子内具有三个或更多异氰酸酯基团的多异氰酸酯与含羟基的（甲基）丙烯酸酯反应而得。
• Ultraviolet-sensing sheet, ultraviolet-sensing set, and ultraviolet-sensing method
  申请人：FUJIFILM Corporation

  公开号：US10113907B2

  公开（公告）日：2018-10-30

  Provided are an ultraviolet-sensing sheet, an ultraviolet-sensing set, and an ultraviolet-sensing method, in which color gradation properties which are suitable for detecting an ultraviolet dose are obtained and in which the coloring of an ultraviolet-sensing layer caused by the effect of light other than ultraviolet light is prevented. An ultraviolet-sensing sheet 1 includes: a filter layer 10 that selectively allows transmission of light having a specific wavelength; and an ultraviolet-sensing layer 20 that includes a capsule including a color-forming dye and a photooxidant. It is preferable that the filter layer 10 has a maximum value of the transmittance in a wavelength range of 300 nm or longer and shorter than 380 nm.

  本发明提供了一种紫外线传感片材、紫外线传感装置和紫外线传感方法，其中可获得适合检测紫外线剂量的色阶特性，并可防止紫外线传感层因紫外线以外的光的影响而着色。 紫外线传感片 1 包括：过滤层 10，可选择性地允许特定波长的光透过；紫外线传感层 20，包括一个胶囊，内含成色染料和光氧化剂。滤光层 10 最好在 300 纳米或更长且短于 380 纳米的波长范围内具有最大透射率值。
• Ultraviolet-sensitive sheet, method for manufacturing ultraviolet-sensing sheet, and method for sensing ultraviolet
  申请人：FUJIFILM Corporation

  公开号：US10203245B2

  公开（公告）日：2019-02-12

  Provided an ultraviolet-sensing sheet that facilitates measurement of ultraviolet irradiance over a wide area, that is suitable in ultraviolet irradiance in a range from 1 to 1,000 mJ/cm2, a method for manufacturing such an ultraviolet-sensing sheet, and a method for sensing ultraviolet. The ultraviolet-sensing sheet has a change in reflection density ΔD1 of 0.2 or more over a range of cumulative illuminance 1 mJ/cm2 or more and less than 10 mJ/cm2, a change in reflection density ΔD2 of 0.2 or more over a range of cumulative illuminance 10 mJ/cm2 or more and less than 100 mJ/cm2, and a change in reflection density ΔD3 of 0.2 or more over a range of cumulative illuminance 100 mJ/cm2 or more and 1,000 mJ/cm2 or less, as measured at a wavelength of 365 nm when the ultraviolet-sensing sheet is irradiated with a high-pressure mercury lamp.

  提供了一种便于测量大面积紫外线辐照度的紫外线传感片，该传感片适用于紫外线辐照度在1至1,000 mJ/cm2范围内的情况，还提供了制造这种紫外线传感片的方法以及传感紫外线的方法。紫外线传感片在累积照度为 1 mJ/cm2 或以上、10 mJ/cm2 以下的范围内，反射密度 ΔD1 的变化为 0.2 或以上、 在累积照度为 10 mJ/cm2 或以上且小于 100 mJ/cm2 的范围内，反射密度 ΔD2 的变化为 0.2 或以上；以及 在累积照度为 100 mJ/cm2 或以上且小于 1,000 mJ/cm2 的范围内，反射密度 ΔD3 的变化为 0.2 或以上、 用高压汞灯照射紫外线传感片时，在 365 纳米波长处测得。
• STRAHLUNGSHÄRTBARE BESCHICHTUNGSMASSEN
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP1820064A2

  公开（公告）日：2007-08-22