N,N'-bis-(2,4-dinitro-phenyl)-propanediyldiamine | 54897-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis-(2,4-dinitro-phenyl)-propanediyldiamine
• 英文别名: N,N'-Bis-(2,4-dinitro-phenyl)-propandiyldiamin；N,N'-bis-(2,4-dinitrophenyl)-1,3-diaminopropane；N~1~,N~3~-bis(2,4-dinitrophenyl)-1,3-propanediamine；N,N'-bis(2,4-dinitrophenyl)propane-1,3-diamine
• CAS: 54897-72-2
• 化学式: C₁₅H₁₄N₆O₈
• 分子量: 406.312
• InChiKey: VIPOXTBARJIBOH-UHFFFAOYSA-N

物化性质

• 沸点：
  665.4±55.0 °C(Predicted)
• 密度：
  1.605±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  207
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  N,N'-bis-(2,4-dinitro-phenyl)-propanediyldiamine 在 硝酸 作用下， 生成 N,N'-dinitro-N,N'-dipicryl-propanediyldiamine
  参考文献：
  名称：

  Veer, Recueil des Travaux Chimiques des Pays-Bas, 1938, vol. 57, p. 989,995

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3-丙二胺 、 1-氯-2,4-二硝基苯 生成 N,N'-bis-(2,4-dinitro-phenyl)-propanediyldiamine
  参考文献：
  名称：

  Diaminoalkane and oxidation colorants

  摘要：

  通式（I）中的二氨基烷，其中R.sub.1到R.sub.10分别代表氢、（C.sub.1 -C.sub.4）-烷基、羟基-(C.sub.2 -C.sub.3)-烷基、（C.sub.1 -C.sub.4）-烷氧基-(C.sub.2 -C.sub.3)烷基、氨基-(C.sub.2 -C.sub.3)烷基或2,3-二羟基丙基基团，n为1到6之间的数字，但要求--NR.sub.1 R.sub.2和--NR.sub.7 R.sub.8基团要么在位置4和4'，要么在位置5和5'。这些二氨基烷的盐与无机和有机酸在生理上兼容。染色角蛋白纤维的方法。

  公开号：

  US06024768A1

文献信息

• Chromatographic approach to the measurement of the interstrand distance for some chiral bonded phases
  作者：William H. Pirkle、Robin S. Readnour

  DOI：10.1021/ac00001a003

  日期：1991.1.1

  A series of homologus N,N'-bis(d,2-dinitrophenyl)-alpha,omega-diaminoalkanes (bis-DNP's) was chromatographed at various temperatures on pi-basic chiral stationary phases derived from N-(2-napthyl)alanine in order to determine the enthalpy and entropy of adsorption. The number of methylene groups in the bis-DNP's influences the ability of the terminal pi-acidic groups to interact simultaneously with neighboring strands of stationary phase, a process termed "bridging". When the number of methylene groups is optimal for bridging, the enthalpy of adsorption is most exothermic. The length of the bis-derivative required for optimal bridging is related to the interstrand distance. Optimal bridging occurs for the bis-DNP's having five methylene groups regardless of the extent of surface coverage of the silica for the surface coverage range investigated. This suggests that the strands are not randomly spaced on the silica, with interstrand distance being influenced only by surface coverage, but are instead clustered, the clusters having similar distributions of interstrand distances. Adsorption is more exothermic for phases of high surface coverages than for low. If interstrand spacing is independent of surface coverage but surface coverage affects the enthalpy of adsorption, t hen surface coverage must influence the cluster size, which then influences the average extent of solvation of a strand of bonded phase.
• US6024768A
  申请人：——

  公开号：US6024768A

  公开（公告）日：2000-02-15
• Veer, Recueil des Travaux Chimiques des Pays-Bas, 1938, vol. 57, p. 989,995
  作者：Veer

  DOI：——

  日期：——
• Diaminoalkane and oxidation colorants
  申请人：Hans Schwarzkopf GmbH & Co. KG

  公开号：US06024768A1

  公开（公告）日：2000-02-15

  A diaminoalkane of general formula (I) in which R.sub.1 to R.sub.10 stand independently of each other for hydrogen, a (C.sub.1 -C.sub.4)-alkyl group, a hydroxy-(C.sub.2 -C.sub.3)-alkyl group, a (C.sub.1 -C.sub.4)-alkoxy-(C.sub.2 -C.sub.3) alkyl group, an amino- (C.sub.2 -C.sub.3) alkyl group or a 2,3-dihydroxypropyl group and n is a number from 1 to 6 with the proviso that the --NR.sub.1 R.sub.2 and --NR.sub.7 R.sub.8 groups are either in positions 4 and 4' or in positions 5 and 5'. Salts of the diaminoalkane which are physiologically compatible with inorganic and organic acids. Method of coloring keratin fiber.

  通式（I）中的二氨基烷，其中R.sub.1到R.sub.10分别代表氢、（C.sub.1 -C.sub.4）-烷基、羟基-(C.sub.2 -C.sub.3)-烷基、（C.sub.1 -C.sub.4）-烷氧基-(C.sub.2 -C.sub.3)烷基、氨基-(C.sub.2 -C.sub.3)烷基或2,3-二羟基丙基基团，n为1到6之间的数字，但要求--NR.sub.1 R.sub.2和--NR.sub.7 R.sub.8基团要么在位置4和4'，要么在位置5和5'。这些二氨基烷的盐与无机和有机酸在生理上兼容。染色角蛋白纤维的方法。