1,2-bis (5,6-dihydro-4H-1,3-oxazin-2-yl)benzene | 1446451-67-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis (5,6-dihydro-4H-1,3-oxazin-2-yl)benzene
• 英文别名: 2-[2-(5,6-dihydro-4H-1,3-oxazin-2-yl)phenyl]-5,6-dihydro-4H-1,3-oxazine
• CAS: 1446451-67-7
• 化学式: C₁₄H₁₆N₂O₂
• 分子量: 244.293
• InChiKey: NGVDCUROJXQOBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-氨基-1-丙醇 、 1,2-二氰基苯 在 sulfur 、 cobalt(II) nitrate 作用下， 以 neat (no solvent) 为溶剂， 反应 0.05h， 以83%的产率得到1,2-bis (5,6-dihydro-4H-1,3-oxazin-2-yl)benzene
  参考文献：
  名称：

  S–Co（II）级联催化：芳族腈与烷胺的环缩合

  摘要：

  在热和微波条件下，已成功开发了无溶剂的S / Co（NO 3）2芳族腈与3-氨基-1-丙醇或2-氨基乙醇的级联催化环缩合反应。通过这种两组分方案，可以以良好至极佳的收率和较短的反应时间选择性地合成单-和双-恶嗪和恶唑啉。该催化系统具有出色的化学选择性，可以重复使用至少7次，而不会在后续反应中显着降低活性。

  DOI：

  10.1016/j.tet.2013.05.132

文献信息

• Process for the preparation of a polymer composition
  申请人：DSM IP Assets B.V.

  公开号：EP1516888A1

  公开（公告）日：2005-03-23

  The invention relates to a process for the preparation of a polymer composition, the process comprising a step of contacting a polymer that comprises carboxyl groups with a cyclic imino ether compound characterized in that the cyclic imino ether compound is a phenylene oxazine according to formula (I) in which formula R = an oxazine group according to formula (II) n = 0, 1, 2, 3, 4 or 5 and that the polymer is contacted with said oxazine in an extruder at a temperature above 100 °C.

  本发明涉及一种制备聚合物组合物的工艺，该工艺包括将含有羧基的聚合物与环状亚氨基醚化合物接触的步骤，其特征在于环状亚氨基醚化合物是符合式（I）的亚苯基恶嗪。 式中 R = 符合式（II）的恶嗪基团 n = 0、1、2、3、4 或 5 聚合物与所述噁嗪在挤压机中接触，温度高于 100 °C。
• COMPOSITION FOR FORMING LASER DIRECT STRUCTURING LAYER, KIT, AND METHOD FOR MANUFACTURING RESIN MOLDED ARTICLE HAVING PLATING LAYER
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP3396019A1

  公开（公告）日：2018-10-31

  To form a plated layer on a surface of the resin molded article without adding the LDS additive to the thermoplastic resin composition. The laser direct structuring layer-forming composition contains a curable compound, an organic solvent, and a laser direct structuring additive.

  在树脂成型品表面形成电镀层，而无需在热塑性树脂组合物中添加激光直接成型添加剂。激光直接成型镀层组合物包含固化化合物、有机溶剂和激光直接成型添加剂。
• RESIN COMPOSITION FOR POWDER LAMINATION SHAPING METHOD, PELLETS, POWDER, METHOD FOR PRODUCING SHAPED ARTICLE, AND SHAPED ARTICLE
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP3919554A1

  公开（公告）日：2021-12-08

  To provide resin composition, a pellet and a powder for use in new powder additive manufacturing, as well as a shaped article using the same, and a method for manufacturing such shaped article. The resin composition comprises a polybutylene terephthalate that contains a terephthalic acid-derived structural unit and a 1,4-butanediol-derived structural unit, for use in powder additive manufacturing, the resin composition having a value (α), defined by mathematical formula [1] below, of 40 or smaller: α=MVR1−MVR0/MVR0×100 where, MVR0 is melt volume flow rate (in cm3/10 min), and MVR1 is melt volume flow rate (in cm3/10 min) .

  提供用于新型粉末增材制造的树脂组合物、颗粒和粉末，以及使用这些组合物和粉末的成型品和制造这些成型品的方法。该树脂组合物包含一种聚对苯二甲酸丁二醇酯，该聚对苯二甲酸丁二醇酯含有对苯二甲酸衍生的结构单元和1,4-丁二醇衍生的结构单元，用于粉末添加剂制造，该树脂组合物的数值（α）由下面的数学公式[1]定义，为40或更小：α=MVR1-MVR0/MVR0×100 其中、 MVR0 为熔体体积流量（单位：立方厘米/10 分钟），MVR1 为熔体体积流量（单位：立方厘米/10 分钟）。
• Composition for forming laser direct structuring layer, kit, and method for manufacturing resin molded article with plated layer
  申请人：MITSUBISHI ENGINEERING-PLASTICS CORPORATION

  公开号：US10472536B2

  公开（公告）日：2019-11-12

  Making formation of a plated layer on a surface of a resin molded article possible, without adding the LDS additive to the thermoplastic resin composition. Provided is a composition for forming a laser direct structuring layer, the composition comprising a water-compatible organic substance, water, and a laser direct structuring additive. Further provided is a kit having the composition for forming a laser direct structuring layer and a method for manufacturing a resin molded article with a plated layer, which uses the composition for forming a laser direct structuring layer.

  无需在热塑性树脂组合物中添加激光直接成型添加剂，即可在树脂成型品表面形成电镀层。本发明提供了一种用于形成激光直接结构层的组合物，该组合物由水相容有机物、水和激光直接结构添加剂组成。此外，还提供了一种试剂盒，该试剂盒具有用于形成激光直接结构层的组合物，还提供了一种制造具有电镀层的树脂模塑品的方法，该方法使用了用于形成激光直接结构层的组合物。
• Flame-retardant resin composition
  申请人：——

  公开号：US20040254270A1

  公开（公告）日：2004-12-16

  A flame-retardant resin composition comprises a thermoplastic resin; a flame retardant comprising a phosphorus-containing compound (A), a aromatic resin (B), and at least one flame-retardant auxiliary (C) selected from a nitrogen-containing compound and a metal salt of an inorganic acid; and at least one stabilizer auxiliary (D) selected from a compound having a functional group reactive to an active hydrogen atom and a water-repellent compound. The phosphorus-containing compound may be a phosphoric ester. The aromatic resin may be a polyphenylene sulfide-series resin or a polyphenylene oxide-series resin. The nitrogen-containing compound is a salt of an amino group-containing triazine compound with an oxygen acid, a salt of an amino group-containing triazine compound with a hydroxyl group-containing triazine compound, a polyphosphoric acid amide, a cyclic urea compound, or others. The present invention provides a flame-retardant resin composition which has been flame-retarded without using a halogen-containing flame retardant.

  阻燃树脂组合物包括热塑性树脂；阻燃剂，包括含磷化合物（A）、芳香族树脂（B）和至少一种阻燃助剂（C），该助剂选自含氮化合物和无机酸的金属盐；以及至少一种稳定助剂（D），该稳定助剂选自具有与活性氢原子反应的官能团的化合物和憎水化合物。含磷化合物可以是磷酸酯。芳香族树脂可以是聚苯硫醚系列树脂或聚苯氧化物系列树脂。含氮化合物为含氨基三嗪化合物与含氧酸的盐、含氨基三嗪化合物与含羟基三嗪化合物的盐、多磷酸酰胺、环状脲化合物或其他。本发明提供了一种不使用含卤素阻燃剂就能阻燃的阻燃树脂组合物。