2-Acetoxy-2'-benzyloxy-diethylether | 6794-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Acetoxy-2'-benzyloxy-diethylether
• 英文别名: 2-[2-(Benzyloxy)ethoxy]ethyl acetate；2-(2-phenylmethoxyethoxy)ethyl acetate
• CAS: 6794-04-3
• 化学式: C₁₃H₁₈O₄
• 分子量: 238.284
• InChiKey: GAIAWYSTWUKJRS-UHFFFAOYSA-N

物化性质

• 沸点：
  155-156 °C
• 密度：
  1.078±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙酰溴 、 [2-(2-Benzyloxy-ethoxy)-ethoxy]-tert-butyl-dimethyl-silane 以 二氯甲烷 为溶剂， 反应 0.33h， 以90%的产率得到2-Acetoxy-2'-benzyloxy-diethylether
  参考文献：
  名称：

  A one-step and chemoselective conversion of silyl-protected alcohols into the corresponding acetates

  摘要：

  A reagent system of acetyl bromide combined with a catalytic amount of tin(II) bromide cleaves readily trialkylsilyl ethers to give the corresponding acetates in high yields under very mild conditions.

  DOI：

  10.1016/s0040-4039(00)73040-1

文献信息

• Oriyama Takeshi, Oda Mihoko, Gono Junko, Koga Gen, Tetrahedron Lett, 35 (1994) N 13, S 2027-2030
  作者：Oriyama Takeshi, Oda Mihoko, Gono Junko, Koga Gen

  DOI：——

  日期：——
• RECYCLING PROCESS
  申请人：Worn Again Footwear And Accessories Limited

  公开号：EP3172267A1

  公开（公告）日：2017-05-31
• [EN] RECYCLING PROCESS<br/>[FR] PROCÉDÉ DE RECYCLAGE
  申请人：WORN AGAIN FOOTWEAR AND ACCESSORIES LTD

  公开号：WO2016012755A1

  公开（公告）日：2016-01-28

  The invention relates to a process for extracting polyester from packaging. In particular, the invention relates to packaging comprising one or more dyes such as black packaging. The claim process uses a two stage extraction process to convert waste polyester in clean, reusable polyester. The invention relates to a process for extracting polyester from fabric. In particular, fabric comprising polyester and one or more dyes. The claimed process uses a multistage mechanism to separate dyes from polyester containing garments and reconstitute the polyester.