N-vinyldi(p-tolyl)amine | 1227189-28-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-vinyldi(p-tolyl)amine
• 英文别名: N-ethenyl-4-methyl-N-(4-methylphenyl)aniline
• CAS: 1227189-28-7
• 化学式: C₁₆H₁₇N
• 分子量: 223.318
• InChiKey: GJIIWLDFQCFEAK-UHFFFAOYSA-N

物化性质

• 沸点：
  346.9±35.0 °C(Predicted)
• 密度：
  1.023±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴乙烯 、 4,4'-二甲基二苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 16.0h， 生成 N-vinyldi(p-tolyl)amine
  参考文献：
  名称：

  Hanley, Patrick S.; Markovic, Dean; Hartwig, John F., Journal of the American Chemical Society, 2010, vol. 132, p. 6302 - 6303

  摘要：

  DOI：

文献信息

• Process for disproportionating silanes
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0206621A1

  公开（公告）日：1986-12-30

  A process for disproportionating silanes, which comprises contacting a silane having at least one Si-H bond represented by the general formula wherein R represents an alkyl or aryl group, X represents a halogen atom or an alkoxy group, ℓis 0, 1 or 2, and m is 1, 2 or 3 and ℓ+m is 1, 2 or 3, and when fis 2, R's may be identical or different, and when ℓ+m is 1 or 2, X's may be identical or different, with a reaction product of a strong acid-type cation exchange resin with an amine.

  一种歧化硅烷的工艺，其包括与具有至少一个 Si-H 键的硅烷接触，该硅烷由通式表示 其中 R 代表烷基或芳基，X 代表卤素原子或烷氧基，ℓ 为 0、1 或 2，m 为 1、2 或 3，ℓ+m 为 1、2 或 3，当 f 为 2 时，R 可以相同或不同，当 ℓ+m 为 1 或 2 时，X 可以相同或不同。
• Resin composition for laser engraving, relief printing starting plate for laser engraving and process for producing the same
  申请人：Fujifilm Corporation

  公开号：EP2301750A1

  公开（公告）日：2011-03-30

  A resin composition for laser engraving is provided that includes (a) a binder polymer having a reactive group, (b) a compound having a hydrophilic group and a bonding group that can react with the reactive group, and (c) a crosslinking agent.

  提供了一种用于激光雕刻的树脂组合物，其中包括 (a) 具有活性基团的粘合剂聚合物，(b) 具有亲水性基团和可与活性基团反应的键合基团的化合物，以及 (c) 交联剂。
• Resin composition for laser engraving, relief printing plate precursor for laser engraving and process for producing same, process for making relief printing plate, and relief printing plate
  申请人：Fujifilm Corporation

  公开号：EP2565046A2

  公开（公告）日：2013-03-06

  Disclosed are a resin composition for laser engraving, a relief printing plate precursor for laser engraving and process for producing the same, a process for making relief printing plate, and a relief printing. The resin composition for laser engraving comprising: (Component A) a compound represented by following Formula (1), and (Component B) a binder polymer having a functional group that is capable of reacting with a hydrolyzable silyl group and/or a silanol group and thereby forming a crosslinked structure: wherein in Formula (1), W, X and Y each independently represent a hydrolyzable group selected from the group consisting of an alkoxy group, an aryloxy group, a mercapto group, a halogen atom, an amide group, an acetoxy group, an amino group and an isopropenoxy group, or a hydroxy group; L represents a divalent linking group or a single bond; Z1 represents a divalent group having 4 to 45 carbon atoms in total and containing at least two of a unit selected from an ethylene oxide unit and a propylene oxide unit; Z2 represents an alkyl group having 7 or less carbon atoms, or a benzyl group; and the sum of the numbers of carbon atoms of L, Z1 and Z2 is 10 to 50.

  本发明公开了一种用于激光雕刻的树脂组合物、一种用于激光雕刻的浮雕印版前体及其生产工艺、一种浮雕印版的生产工艺以及一种浮雕印刷。 激光雕刻用树脂组合物包括：（A 组分）由下式（1）表示的化合物；和（B 组分）具有能与可水解硅基和/或硅醇基反应从而形成交联结构的官能团的粘合剂聚合物： 式（1）中，W、X 和 Y 各自独立地代表可水解基团，该基团选自由烷氧基、芳氧基、巯基、卤素原子、酰胺基、乙酰氧基、氨基和异丙烯氧基或羟基组成的组；L 代表二价连接基团或单键；Z1 代表总共具有 4 至 45 个碳原子的二价基团，至少含有两个选自环氧乙烷单元和环氧丙烷单元的单元；Z2 代表具有 7 个或更少碳原子的烷基或苄基；L、Z1 和 Z2 的碳原子数之和为 10 至 50。
• RELIEF PRINTING PLATE
  申请人：FUJIFILM Corporation

  公开号：EP2393666B1

  公开（公告）日：2014-01-15
• RESIN COMPOSITION FOR LASER ENGRAVING, RELIEF PRINTING PLATE PRECURSOR FOR LASER ENGRAVING AND PROCESS FOR PRODUCING THE SAME, AND RELIEF PRINTING PLATE AND PROCESS FOR MAKING THE SAME
  申请人：KANCHIKU Shigefumi

  公开号：US20120024224A1

  公开（公告）日：2012-02-02

  A resin composition for laser engraving, comprising (Component A) a compound having two or more ring structures selected from the group consisting of an epoxy ring, an oxetane ring and a five-membered carbonate ring, (Component B) a curing agent capable of reacting with Component A to thus form a crosslinked structure, and (Component C) a compound having at least one of a hydrolyzable silyl group and a silanol group.