dimethyl-propyl-sulfonium; iodide | 52238-40-1

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: dimethyl-propyl-sulfonium; iodide
• 英文别名: Dimethyl-propyl-sulfonium; Jodid；Dimethylpropyl-sulfonium-iodid；Dimethyl(propyl)sulfanium iodide；dimethyl(propyl)sulfanium;iodide
• CAS: 52238-40-1
• 化学式: C₅H₁₃S*I
• 分子量: 232.129
• InChiKey: NUSXMKGPZWJZSY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.72
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙醇 、 sodium ethanolate 、 dimethyl-propyl-sulfonium; iodide 生成 三聚丙烯
  参考文献：
  名称：

  422.消除反应的机理。第十二部分。在碱性醇介质中从乙基，正丙基，正丁基，异丁基和2-苯基乙基二甲基磺酸盐中消除烯烃的动力学

  摘要：

  DOI：

  10.1039/jr9480002072
• 作为产物：
  描述：

  正辛基丙基硫醚 、 碘甲烷 生成 dimethyl-propyl-sulfonium; iodide
  参考文献：
  名称：

  Ingold et al., Journal of the Chemical Society, 1933, p. 535

  摘要：

  DOI：

文献信息

• Banthorpe,D.V. et al., Journal of the Chemical Society, 1960, p. 4054 - 4087
  作者：Banthorpe,D.V. et al.

  DOI：——

  日期：——
• Molten and Solid Trialkylsulfonium Iodides and Their Polyiodides as Electrolytes in Dye-Sensitized Nanocrystalline Solar Cells
  作者：Heléne Paulsson、Anders Hagfeldt、Lars Kloo

  DOI：10.1021/jp036859v

  日期：2003.12.1

  Potential new electrolytes for dye-sensitized nanocrystalline solar cells (DNSCs) of Gratzel type based on trialkylsulfonium iodides have been investigated. Room temperature molten salts of (Et2MeS)I, (Bu2MeS)I, and (Bu2EtS)I, with iodine in low concentrations, revealed good conducting abilities. DNSCs using iodine-doped (Bu2MeS)l as electrolyte achieved an overall light-to-electricity conversion efficiency of 3.7% in simulated AM 1.5 solar light at a light intensity of 0.1 Sun. The effects from varying the temperature during the IN measurements were studied, as well as the effects of 4-tert-butylpyridine treatment of the electrodes.
• Ingold et al., Journal of the Chemical Society, 1933, p. 535
  作者：Ingold et al.

  DOI：——

  日期：——
• 422. Mechanism of elimination reactions. Part XII. Kinetics of olefin eliminations from ethyl-, n-propyl-, n-butyl, isobutyl-, and 2-phenyl-ethyl-dimethylsulphonium salts in alkaline alcoholic media
  作者：E. D. Hughes、C. K. Ingold、G. A. Maw

  DOI：10.1039/jr9480002072

  日期：——