(1-phenyl-prop-2-yl)phosphine | 1256544-07-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1-phenyl-prop-2-yl)phosphine
• 英文别名: 1-Phenylpropan-2-ylphosphane
• CAS: 1256544-07-6
• 化学式: C₉H₁₃P
• 分子量: 152.176
• InChiKey: CVDYUGPRUHCBKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  烯丙苯 在 phosphan 、 potassium hydroxide 作用下， 以 水 、 二甲基亚砜 为溶剂， 90.0 ℃ 、101.33 kPa 条件下， 反应 2.0h， 以53%的产率得到(1-phenyl-prop-2-yl)phosphine
  参考文献：
  名称：

  Reaction of phosphine with allylbenzene in the KOH–DMSO system: regioselective synthesis of (1-phenylprop-2-yl)phosphine and bis(1-phenylprop-2-yl)phosphine

  摘要：

  Phosphine reacts with allylbenzene in the KOH-DMSO system (90-110 degrees C, 2-2.5 h, atmospheric pressure) to afford Markovnikov adducts, (1-phenylprop-2-yl)phosphine and/or bis(1-phenylprop-2-yl)phosphine in 53-80% yields.

  DOI：

  10.1016/j.mencom.2010.09.012

文献信息

• SILVER-(CONJUGATED COMPOUND) COMPLEX
  申请人：Sumitomo Chemical Co., Ltd

  公开号：EP2478981A1

  公开（公告）日：2012-07-25

  A silver-(conjugated compound) composite comprising silver particles having a number-average Feret diameter of not more than 1,000 nm, and a conjugated compound having a weight-average molecular weight of not less than 3.0×102 adsorbed to the silver particles. The composite exhibits excellent conductivity and charge injection properties, and excellent dispersibility within non-polar solvents

  一种银-（共轭化合物）复合材料，由平均费里特直径不大于 1,000 纳米的银颗粒和吸附在银颗粒上的平均分子量不小于 3.0×102 的共轭化合物组成。这种复合材料具有优异的导电性和电荷注入特性，在非极性溶剂中具有优异的分散性。
• EP2478981B1
  申请人：——

  公开号：EP2478981B1

  公开（公告）日：2020-12-23
• SILVER-(CONJUGATED COMPOUND) COMPOSITE
  申请人：Iijima Takayuki

  公开号：US20120168693A1

  公开（公告）日：2012-07-05

  A silver-(conjugated compound) composite comprising silver particles having a number-average Feret diameter of not more than 1,000 nm, and a conjugated compound having a weight-average molecular weight of not less than 3.0×10 2 adsorbed to the silver particles. The composite exhibits excellent conductivity and charge injection properties, and excellent dispersibility within non-polar solvents.
• COMPOSITION OF SILVER-CONJUGATED COMPOUND COMPOSITE
  申请人：Iijima Takayuki

  公开号：US20140001422A1

  公开（公告）日：2014-01-02

  A composition of a silver-conjugated compound composite containing (1) a silver-conjugated compound composite containing a silver particle with a Feret diameter of 1,000 nm or less and a conjugated compound having a weight average molecular weight of 3.0×10 2 or more being adsorbed to the silver particles and (2) an ionic compound. The ionic compound may be a compound having a structure represented by the following Formula (hh-1): [Chem. 1] M m′ + a X′ n′− b (hh-1) wherein M m′+ represents a metal cation, X′ n′− represents an anion, a and b each independently represent an integer of 1 or more, and when M m′+ and X′ n′− are each plurally present, they may be the same as or different from each other.
• US9412487B2
  申请人：——

  公开号：US9412487B2

  公开（公告）日：2016-08-09